Synthesis of an efficient MOF catalyst for the degradation of OPDs using TPA derived from PET waste bottles.

In this study, a method for degrading PET-waste plastic bottles using ZnCl2:Urea as a catalyst was developed, resulting in high conversion (87%). The terephthalic acid obtained from the degradation of Waste PET Bottles (WPTs) was combined with copper and zinc salts to synthesize bimetallic metal-organic frameworks (MOF). The effectiveness of a bimetallic Cu-Zn(BDC)-MOF in catalyzing the reduction reaction of organic pollutant dyes (OPDs) was investigated, and the degradation efficiency of individual dyes was optimized, achieving over 95% degradation within 6-12 min under optimal conditions. Various techniques, including FT-IR, XRD, FE-SEM, EDS, and TEM were used to characterize the synthesized MOF. Results showed that the catalytic activity of Cu-Zn-MOF in reduction reaction of OPDs was enhanced by increasing the copper content. The reaction kinetics were investigated following pseudo-first-order kinetics with rate constants of 0.581, 0.43, 0.37, and 0.30 min-1 for Methylene Blue (MB), Methyl Orange (MO), 4-Nitrophenol (4-NP), and 4-Nitroaniline (4-NA), respectively. The investigations revealed that the produced catalyst exhibited excellent stability and recoverability, while its activity remained well-preserved even after undergoing three reuse cycles.

Simulation of temperature swing adsorption process to purify hydrogen for fuel cell uses by SAPO34 as adsorbent.

To purify hydrogen gas from synthesis gas using a adsorption process, SAPO 34 adsorbent was used. Due to the strong adsorption of carbon dioxide in this adsorbent, it is not possible to recover the adsorbent by reducing the pressure alone, and it is necessary to use thermal operations for recovery. For this purpose, a temperature swing adsorption (TSA) process is used to increase the purity of hydrogen for use in fuel cells. To investigate the optimum operational conditions, various temperatures and different pressures of input gas were investigated to compare the purity and recovery of adsorption process. The TSA process was simulated for pressures of 11, 22 and 33 bars and the recovery percentage of each process was calculated. According to the results obtained, the recovery value at 33 bars is better than the other two pressures, but due to the fact that operational and initial costs increase at high pressures; 22 bar pressure was chosen to present the remaining results. In this work, the total amount of material and the molar rate are also reported. The average purity of the components in the product and waste outlet streams has also been presented. Accordingly, the average molar fraction of hydrogen in the product outlet stream is 99.96% in the temperature increase stage, 99.94% and in the stream used for temperature reduction is 99.96%.

Thermal design and zeotropic working fluids mixture selection optimization for a solar waste heat driven combined cooling and power system.

Considering the limitation of fossil fuel resources and their environmental effects, the use of renewable energies is increasing. In the current research, a combined cooling and power production (CCPP) system is investigated, the energy source of which is solar energy. Solar energy absorbs by solar flat plate collectors (SFPC). The system produces power with the help of an organic Rankine cycle (ORC). An ejector refrigeration cycle (ERC) system is considered to provide cooling capacity. The motive flow is supplied from the expander extraction in the ERC system. Various working fluids have been applied so far for the ORC-ERC cogeneration system. This research investigates the effect of using two working fluids R-11 and R-2545fa, and the zeotropic mixtures obtained by mixing these two fluids. A multiobjective optimization process is considered to select the appropriate working fluid. In the optimization design process, the goal is to minimize the total cost rate (TCR) and maximize the exergy efficiency of the system. The design variables are the quantity of SFPC, heat recovery vapor generator (HRVG) pressure, ejector motive flow pressure, evaporator pressure, condenser pressure, and entertainment ratio. Finally, it is observed that using zeotropic mixtures obtained from these two refrigerants has a better result than using pure refrigerants. Finally, it is observed that the best performance is achieved when R-11 and R245fa are mixed with a ratio of 80 to 20%, respectively and led to 8.5% improvement in exergy efficiency, while the increase in TCR is only 1.5%.

Artificial Lightweight Aggregates Made from Pozzolanic Material: A Review on the Method, Physical and Mechanical Properties, Thermal and Microstructure.

As the demand for nonrenewable natural resources, such as aggregate, is increasing worldwide, new production of artificial aggregate should be developed. Artificial lightweight aggregate can bring advantages to the construction field due to its lower density, thus reducing the dead load applied to the structural elements. In addition, application of artificial lightweight aggregate in lightweight concrete will produce lower thermal conductivity. However, the production of artificial lightweight aggregate is still limited. Production of artificial lightweight aggregate incorporating waste materials or pozzolanic materials is advantageous and beneficial in terms of being environmentally friendly, as well as lowering carbon dioxide emissions. Moreover, additives, such as geopolymer, have been introduced as one of the alternative construction materials that have been proven to have excellent properties. Thus, this paper will review the production of artificial lightweight aggregate through various methods, including sintering, cold bonding, and autoclaving. The significant properties of artificial lightweight aggregate, including physical and mechanical properties, such as water absorption, crushing strength, and impact value, are reviewed. The properties of concrete, including thermal properties, that utilized artificial lightweight aggregate were also briefly reviewed to highlight the advantages of artificial lightweight aggregate.

Waste Material via Geopolymerization for Heavy-Duty Application: A Review.

Due to the extraordinary properties for heavy-duty applications, there has been a great deal of interest in the utilization of waste material via geopolymerization technology. There are various advantages offered by this geopolymer-based material, such as excellent stability, exceptional impermeability, self-refluxing ability, resistant thermal energy from explosive detonation, and excellent mechanical performance. An overview of the work with the details of key factors affecting the heavy-duty performance of geopolymer-based material such as type of binder, alkali agent dosage, mixing design, and curing condition are reviewed in this paper. Interestingly, the review exhibited that different types of waste material containing a large number of chemical elements had an impact on mechanical performance in military, civil engineering, and road application. Finally, this work suggests some future research directions for the the remarkable of waste material through geopolymerization to be employed in heavy-duty application.

Contribution of Interfacial Bonding towards Geopolymers Properties in Geopolymers Reinforced Fibers: A Review.

There is a burgeoning interest in the development of geopolymers as sustainable construction materials and incombustible inorganic polymers. However, geopolymers show quasi-brittle behavior. To overcome this weakness, hundreds of researchers have focused on the development, characterization, and implementation of geopolymer-reinforced fibers for a wide range of applications for light geopolymers concrete. This paper discusses the rapidly developing geopolymer-reinforced fibers, focusing on material and geometrical properties, numerical simulation, and the effect of fibers on the geopolymers. In the section on the effect of fibers on the geopolymers, a comparison between single and hybrid fibers will show the compressive strength and toughness of each type of fiber. It is proposed that interfacial bonding between matrix and fibers is important to obtain better results, and interfacial bonding between matrix and fiber depends on the type of material surface contact area, such as being hydrophobic or hydrophilic, as well as the softness or roughness of the surface.