Silicon-tapered waveguide for mode conversion in metal-insulator-metal waveguide-based plasmonic sensor for refractive index sensing.

In this study, we have undertaken a comprehensive numerical investigation of a refractive index sensor designed around a metal-insulator-metal (MIM) plasmonic waveguide. Our approach utilizes the finite element method to thoroughly analyze the sensor's performance. The sensor's configuration utilizes a ring resonator design, which has been slightly modified at the coupling segment. This modification enhances the efficiency of light coupling between a bus waveguide and the ring resonator, particularly at the resonance wavelength. This strategic adjustment significantly improves the device's extinction ratio, a critical factor in its functionality. Remarkably, the sensitivity of this sensor is determined to be approximately 1155.71 nm/RIU, while it possesses a figure of merit of 25.9. Furthermore, our study delves into the intricate mechanism governing the injection of light into the nanoscale MIM waveguide. We achieve this through the incorporation of silicon-tapered waveguides, which play a pivotal role in facilitating the transformation of a dielectric mode into a plasmonic mode, and vice versa. Ultimately, the findings of this research hold significant promise for advancing the field of plasmonic sensing systems based on MIM waveguide technology. The insights gained here pave the way for the practical realization and optimization of highly efficient and precise plasmonic sensors.

Laser-Induced Periodic Surface Structures on Layered GaSe Crystals: Structural Coloring and Infrared Antireflection.

We study structural and morphological transformations caused by multipulse femtosecond-laser exposure of Bridgman-grown ϵ-phase GaSe crystals, a van der Waals semiconductor promising for nonlinear optics and optoelectronics. We unveil, for the first time, the laser-driven self-organization regimes in GaSe allowing the formation of regular laser-induced periodic surface structures (LIPSSs) that originate from interference of the incident radiation and interface surface plasmon waves. LIPSSs formation causes transformation of the near-surface layer to amorphous Ga2Se3 at negligible oxidation levels, evidenced from comprehensive structural characterization. LIPSSs imprinted on both output crystal facets provide a 1.2-fold increase of the near-IR transmittance, while the ability to control local periodicity by processing parameters enables multilevel structural color marking of the crystal surface. Our studies highlight direct fs-laser patterning as a multipurpose application-ready technology for precise nanostructuring of promising van der Waals semiconductors, whose layered structure restricts application of common nanofabrication approaches.

Polarization-sensitive direct laser patterning of azopolymer thin films with vortex beams.

Laser patterning of thin films of materials is widely used for the fabrication of one-, two- and three-dimensional functional nanomaterials. Using structured laser beams with a complex structure of amplitude, phase, and polarization distributions allows one to significantly simplify and speed up the procedure of manufacturing nano- and microstructures with a complex shape, such as a spiral structure. Here, we demonstrate the use of vortex laser beams with a helical wavefront for the realization of spiral mass transfer in azopolymer films. The polarization sensitivity of this material allows us to demonstrate the formation of different three-dimensional structures in the case of linearly or circularly polarized vortex beams of different orders. The presented theoretical analysis shows that the profile of the fabricated structures is defined by the structure of the longitudinal component of the incident radiation, and thus can be easily controlled with the polarization state of the radiation without the need to change the amplitude-phase structure of the beam.

Robust multifilament arrays in air by Dammann grating.

We compare transverse structure evolution and energy deposition into the medium within focused multifilament arrays created using two different types of diffraction optical elements (DOEs): TEM11 phase plate and a Dammann grating. We show that the employment of the Dammann grating provides a robust way to create regular multifilament arrays, which is far less dependent on laser beam quality than one using the phase plate.

Plasmonic sensor based on metal-insulator-metal waveguide square ring cavity filled with functional material for the detection of CO2 gas.

In this work, a straightforward and highly sensitive design of a CO2 gas sensor is numerically investigated using the finite element method. The sensor is based on a plasmonic metal-insulator-metal (MIM) waveguide side coupled to a square ring cavity filled with polyhexamethylene biguanide (PHMB) functional material. The refractive index of the functional material changes when exposed to the CO2 and that change is linearly proportional to the concentration of the gas. The sensors based on surface plasmon polariton (SPP) waves are highly sensitive due to the strong interaction of the electromagnetic wave with the matter. By utilizing PHMB polymer in the MIM waveguide plasmonic sensor provides a platform that offers the highest sensitivity of 135.95 pm/ppm which cannot be obtained via optical sensors based on silicon photonics. The sensitivity reported in this work is ∼7 times higher than reported in the previous works. Therefore, we believe that the results presented in this paper are exceedingly beneficial for the realization of the sensors for the detection of toxic gases by employing different functional materials.

Ultrashort inverted tapered silicon ridge-to-slot waveguide coupler at 1.55 µm and 3.392 µm wavelength.

Herein, a compact and efficient inverted tapered ridge-to-slot waveguide coupler design based on the silicon-on-insulator platform is presented. The proposed device consists of three segments such as ridge waveguide, inverted taper segment, and slot waveguide. The coupling segment resembles a V shape, which provides good mode-matching between the ridge and slot waveguide. Two significant aspects of the proposed coupler design are discussed. In the first part of the paper, the coupler design optimized at 1.55 µm is suggested for optical interconnect. The propagation loss and coupling efficiency of 1.69 dB/µm and 91% are obtained for the 100 nm long tapered segment introduced between the ridge waveguide and slot waveguide, respectively. This propagation loss of the device includes the loss suffered by the ridge waveguide, tapered segment, and slot waveguide. Our proposed device design can be used in integrated optical platforms, where the efficient coupling of light to slot waveguides is required. Whereas, in the second part, the coupler design is optimized at the mid-infrared of 3.392 µm for an evanescent field absorption methane gas sensor. Slot waveguide offers excessive light-matter interaction due to its strong mode confinement in the low index material. The evanescent field ratio of ∼0.73 is obtained for the optimized waveguide geometry. As a result, 3 dB decay in the transmitted power can be obtained at 60% of gas concentration present in the ambient medium.

Silicon microprotrusions with tailored chirality enabled by direct femtosecond laser ablation.

Here, we report on formation of nanoprotrusions on the surface of a bulk crystalline silicon wafer under femtosecond-laser ablation with a donut-shaped laser beam. By breaking circular symmetry of the irradiating donut-shaped fs-pulse beam, a switch in geometry of the formed surface nanoprotrusions from regular to chiral was demonstrated. The chirality of the obtained Si nanostructures was promoted with an asymmetry degree of the laser beam. An uneven helical flow of laser-melted Si caused by asymmetry of the initial intensity and temperature pattern on the laser-irradiated Si surface explains this phenomenon. Chirality of the formed protrusions was confirmed by visualizing cross-sectional cuts produced by focused ion beam milling as well as Raman activity of these structures probed by circularly polarized light with opposite handedness. Our results open a pathway towards easy-to-implement inexpensive fabrication of chiral all-dielectric nanostructures for advanced nanophotonic applications and sensing of chiral molecules.

Refractive twisted microaxicons.

Complex-shaped light fields with specially designed intensity, phase, and polarization distributions are highly demanded for various applications including optical tweezers, laser material processing, and lithography. Here, we propose a novel (to the best of our knowledge) optical element formed by the twisting of a conic surface, a twisted microaxicon, allowing us to controllably generate high-quality spiral-shaped intensity patterns. Performance of the proposed element was analyzed both analytically and numerically using ray approximation and the rigorous finite difference time domain (FDTD) solution of Maxwell's equation. The main geometric parameters, an apex cone angle and a degree of twisting, were considered to control and optimize the generated spiral-shaped intensity patterns. The three-dimensional structure of such a microaxicon cannot be described by an unambiguous height function; therefore, it has no diffraction analogue in the form of a thin optical element. Such an element can be produced via direct laser ablation of transparent targets with structured laser beams or direct laser writing via two-photon photopolymerization and can be used in various micro- and nano-optical applications.

Plasmonic Nanolenses Produced by Cylindrical Vector Beam Printing for Sensing Applications.

Interaction of complex-shaped light fields with specially designed plasmonic nanostructures gives rise to various intriguing optical phenomena like nanofocusing of surface waves, enhanced nonlinear optical response and appearance of specific low-loss modes, which can not be excited with ordinary Gaussian-shaped beams. Related complex-shaped nanostructures are commonly fabricated using rather expensive and time-consuming electron- and ion-beam lithography techniques limiting real-life applicability of such an approach. In this respect, plasmonic nanostructures designed to benefit from their excitation with complex-shaped light fields, as well as high-performing techniques allowing inexpensive and flexible fabrication of such structures, are of great demand for various applications. Here, we demonstrate a simple direct maskless laser-based approach for fabrication of back-reflector-coupled plasmonic nanorings arrays. The approach is based on delicate ablation of an upper metal film of a metal-insulator-metal (MIM) sandwich with donut-shaped laser pulses followed by argon ion-beam polishing. After being excited with a radially polarized beam, the MIM configuration of the nanorings permitted to realize efficient nanofocusing of constructively interfering plasmonic waves excited in the gap area between the nanoring and back-reflector mirror. For optimized MIM geometry excited by radially polarized CVB, substantial enhancement of the electromagnetic near-fields at the center of the ring within a single focal spot with the size of 0.37λ2 can be achieved, which is confirmed by Finite Difference Time Domain calculations, as well as by detection of 100-fold enhanced photoluminescent signal from adsorbed organic dye molecules. Simple large-scale and cost-efficient fabrication procedure offering also a freedom in the choice of materials to design MIM structures, along with remarkable optical and plasmonic characteristics of the produced structures make them promising for realization of various nanophotonic and biosensing platforms that utilize cylindrical vector beam as a pump source.

Recognition of polarization and phase states of light based on the interaction of non-uniformly polarized laser beams with singular phase structures.

We propose to analyze the polarization and phase states of laser beams using a fixed set of non-polarizing phase elements. The experimental implementation of the proposed method is based on the use of multi-order phase-diffractive optical elements (DOEs). The presence or absence of intensity maxima (information bits) corresponding to the numbers of diffraction orders allows an identification code (a codeword) to be obtained. The resulting codeword makes it possible to uniquely determine the order of the vortex singularity and the order of the cylindrical polarization of the laser beam in various combinations based on simple relations.

Symmetry-wise nanopatterning and plasmonic excitation of ring-like gold nanoholes by structured femtosecond laser pulses with different polarizations.

Low- and ultralow-energy tightly focused 200 fs, 515 nm donut-shaped laser pulses at 0.25 and 0.65 NA focusing were used for single-shot ablative pulse-energy scalable nanopatterning of 50 nm thick gold film and the following plasmonic excitation of dye monolayer photoluminescence (PL) in the fabricated nanostructures, respectively. The same pulses at much lower, non-ablative nanojoule energies, and the same focusing and linear, azimuthal, or radial polarizations provided efficient spectrally and symmetry-matched excitation of both localized and delocalized surface electromagnetic modes in the separate, ring-like through holes and their arrays in the film envisioned by our modeling, thus resulting in a polarization-sensitive yield of rhodamine 6G dye PL. The demonstrated consistency between the symmetries of the donut-shaped low-energy photo-exciting laser beam, its polarization state, and the donut-shaped gold nanostructures, produced by the same beam at high, ablative pulse energies, paves the way to smart, self-consistent nanofabrication and plasmonic sensing, when the structured light interacts with the consistently structured matter.

10-million-elements-per-second printing of infrared-resonant plasmonic arrays by multiplexed laser pulses.

We report on high-quality infrared (IR)-resonant plasmonic nanoantenna arrays fabricated on a thin gold film by tightly focused femtosecond (fs) laser pulses coming at submegahertz repetition rates at a printing rate of 10 million elements per second. To achieve this, the laser pulses were spatially multiplexed by fused silica diffractive optical elements into 51 identical submicrometer-sized laser spots arranged into a linear array at periodicity down to 1 µm. The demonstrated high-throughput nanopatterning modality indicates fs laser maskless microablation as an emerging robust, flexible, and competitive lithographic tool for advanced fabrication of IR-range plasmonic sensors for environmental sensing, chemosensing, and biosensing.

Zero-orbital-angular-momentum laser printing of chiral nanoneedles.

Laser irradiation of various materials including metals, polymers, and semiconductors with vortex beams was previously shown to "twist" transiently molten matter providing the direct easy-to-implement way to obtain chiral surface relief. Specifically for metals, this effect was attributed to transfer of an orbital angular momentum (OAM) carried by a vortex beam. In this Letter, we report the formation of twisted metallic nanoneedles on surfaces of silver and gold films under their irradiation by a zero-OAM laser beam with a spiral-shaped intensity distribution. Our comparative experiments clearly demonstrate, for the first time to the best of our knowledge, that the formation of the chiral nanoneedles on the noble-metal films is mainly governed by the temperature-gradient-induced chiral thermocapillary mass transfer, rather than by OAM-driven rotation of the molten matter.

Fractional Airy beams.

Airy beams possess a number of properties that ensure their multifunction and high relevance in many applications. This fact stimulates scientists to search for new modifications and generalizations of classical Airy beams. Several generalizations of the Airy functions are known, on the basis of both the modification of the differential equation and the variations in the integral representation. In this paper we propose and investigate a new type of Airy beams-fractional Airy beams (FrAiB). They are based on the generalization of the integral representation and are close to the Olver functions, but we are considering a wider range of the power-law dependence of the argument, including non-integer (fractional) values of the power. A theoretical and numerical analysis of the FrAiBs, as well as their symmetrized variants, was performed. The properties of FrAiBs, such as being non-diffracting and autofocusing, were numerically investigated by means of the fractional Fourier transform, describing the beam transformations by paraxial optical systems. We believe that new beams can be useful for laser manipulation techniques and lensless laser patterning.

Multi-beam pulsed-laser patterning of plasmonic films using broadband diffractive optical elements.

Multi-sector broadband diffractive optical elements (DOEs) were designed and fabricated from fused silica for high-efficiency multiplexing of femtosecond and nanosecond Gaussian laser beams into multiple (up to one 100) optically tunable microbeams with increased high-numerical aperture (NA) focal depths. Various DOE-related issues, such as high-NA laser focusing, laser pulsewidth, and DOE symmetry-dependent heat conduction effects, as well as the corresponding spatial resolution, were discussed in the context of high-throughput laser patterning. The increased focal depths provided by such DOEs, their high multiplexing efficiency and damage threshold, as well as easy-to-implement optical shaping of output microbeams provide advanced opportunities for direct, mask-free, and vacuum-free high-throughput subtractive (ablative) and displacive pulsed-laser patterning of various nanoplasmonic films for surface-enhanced spectroscopy, sensing, and light control.

Direct laser printing of chiral plasmonic nanojets by vortex beams.

Donut-shaped laser radiation, carrying orbital angular momentum, namely optical vortex, was recently shown to provide vectorial mass transfer, twisting transiently molten material and producing chiral micro-scale structures on surfaces of different bulk materials upon their resolidification. In this paper, we show that at high-NA focusing nanosecond laser vortices can produce chiral nanoneedles (nanojets) of variable size on thin films of such plasmonic materials, as silver and gold films, covering thermally insulating substrates. Main geometric parameters of the produced chiral nanojets, such as height and aspect ratio, were shown to be tunable in a wide range by varying metal film thickness, supporting substrates, and the optical size of the vortex beam. Donut-shaped vortex nanosecond laser pulses, carrying two vortices with opposite handedness, were demonstrated to produce two chiral nanojets twisted in opposite directions. These results suggest optical interference of the incident and reflected laser beams as a source of complex surface intensity distributions in metal films, possessing spiral components and driving both center-symmetric and spiral thermocapillary melt flows to yield in frozen nanoneedles with their pre-determined spiral nanocarving.

Study of polarization properties of fiber-optics probes with use of a binary phase plate.

We conduct a theoretical and experimental study of the distribution of the electric field components in the sharp focal domain when rotating a zone plate with a π-phase jump placed in the focused beam. Comparing the theoretical and experimental results for several kinds of near-field probes, an analysis of the polarization sensitivity of different types of metal-coated aperture probes is conducted. It is demonstrated that with increasing diameter of the non-metal-coated tip part there occurs an essential redistribution of sensitivity in favor of the transverse electric field components and an increase of the probe's energy throughput.

Strengthening the longitudinal component of the sharply focused electric field by means of higher-order laser beams.

We study the sharp focusing of differently polarized low-order and high-order beams, including Bessel and Laguerre-Gaussian (LG) modes, to compare them using several criteria: the size of a light spot, the intensity ratio of the central peak and sidelobes, and the intensity of the longitudinal electric field component. The experiments performed using the near-field microscopy techniques are in general agreement with the results of the numerical simulation. We have validated the growth of the longitudinal component in the focus for high-order modes at moderate NA=0.6-0.8, and essential lower sidelobes of Bessel modes, in comparison with LG modes.

Generating hypergeometric laser beams with a diffractive optical element.

We derive explicit analytical relations to describe paraxial light beams that represent a particular case of the hypergeometric (HyG) laser beams [J. Opt. Soc. Am. A25, 262-270 (2008)JOAOD60740-323210.1364/JOSAA.25.000262]. Among these are modified quadratic Bessel-Gaussian beams, hollow Gaussian optical vortices, modified elegant Laguerre-Gaussian beams, and gamma-HyG beams. Using e-beam microlithography, a binary diffractive optical element capable of producing near-HyG beams is synthesized. Theory and experiment are in sufficient agreement. We experimentally demonstrate the ability to rotate dielectric microparticles using the bright diffraction ring of a HyG beam.

Design and investigation of color separation diffraction gratings.

Color separation gratings (CSGs) are designed within the framework of the rigorous electromagnetic theory using a gradient method. The optimality of the scalar-theory-based solutions is estimated. The results of the experimental study of a CSG to separate three wavelengths are presented.