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J Am Chem Soc ; 124(12): 2868-9, 2002 Mar 27.
Article in English | MEDLINE | ID: mdl-11902866

ABSTRACT

The Mo-catalyzed asymmetric ring-closing metathesis (ARCM) of various achiral trienes leads to the formation of medium-ring unsaturated heterocycles in high yield and with excellent enantioselectivity. Reactions may be carried out on gram scale and in the absence of solvent. The unsaturated siloxanes obtained enantioselectively can be readily functionalized to obtain synthetically useful and difficult-to-access tertiary alcohols.


Subject(s)
Alcohols/chemical synthesis , Ethers, Cyclic/chemical synthesis , Heterocyclic Compounds/chemical synthesis , Hydrocarbons, Cyclic/chemical synthesis , Molybdenum/chemistry , Organometallic Compounds/chemistry , Catalysis , Stereoisomerism
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