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1.
Materials (Basel) ; 15(23)2022 Dec 02.
Article in English | MEDLINE | ID: mdl-36500107

ABSTRACT

Nitrogen ions were implanted into the coated Nb layer by plasma immersion ion implantation to improve resistance to corrosion of a metal bipolar plate. Due to nitrogen implantation, the corrosion behavior of the Nb layer was enhanced. The electron microscope observation reveals that the microstructure of the Nb layer became denser and had fewer defects with increasing implantation energy. As a result, the densified structure effectively prevented direct contact with the corrosive electrolyte. In addition, at a higher implantation rate (6.40 × 1017 N2/cm2), a thin amorphous layer was formed on the surface, and the implanted nitrogen ions reacted at neighboring Nb sites, resulting in the localized formation of nitrides. Such phase and structural changes contributed to further improve corrosion resistance. In particular, the implanted Nb layer at bias voltage of 10 kV exhibited a current density more than one order of magnitude smaller with a two times faster stabilization than the as-deposited Nb layer under the PEMFC operating conditions.

2.
RSC Adv ; 12(54): 35320-35327, 2022 Dec 06.
Article in English | MEDLINE | ID: mdl-36540241

ABSTRACT

Electrochromic technologies have recently attracted attention due to their energy-saving performance for reducing green gas emissions. The materials design and preparation of electrochromic materials with sufficient microstructure and crystallographic features for suitable ion intercalation/deintercalation are essential for high performance and efficiency. In the present work, nanostructured amorphous tungsten trioxide (WO3) films are electrodeposited to enhance electrochromic properties by controlling the pH of electrolytes. Electron microscopy and spectroelectrochemical analysis demonstrate that smaller grain sizes result in larger electrochemical reactive surface areas and shorter ion diffusion lengths. Consequently, the ions efficiently intercalated and deintercalated during the coloring and bleaching states, respectively. In particular, prepared WO3 films at electrolyte pH 1.4 demonstrate high optical modulation (74.83%) and good transmittance switching speeds (1.56 and 2.06 s during coloring and bleaching, respectively) at 650 nm, as well as comparable coloration efficiency (61.92 cm2 C-1 at 650 nm).

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