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1.
Phys Rev Lett ; 120(9): 097201, 2018 Mar 02.
Article in English | MEDLINE | ID: mdl-29547324

ABSTRACT

We report the discovery of a field driven transition from a single-q to multi-q spin density wave (SDW) in the tetragonal heavy fermion compound CeAuSb_{2}. Polarized along c, the sinusoidal SDW amplitude is 1.8(2)µ_{B}/Ce for T≪T_{N}=6.25(10) K with a wave vector q_{1}=(η,η,1/2) [η=0.136(2)]. For H∥c, harmonics appearing at 2q_{1} evidence a striped magnetic texture below µ_{∘}H_{1}=2.78(1) T. Above H_{1}, these are replaced by coupled harmonics at q_{1}+q_{2}=(2η,0,0)+c^{*} until µ_{∘}H_{2}=5.42(5) T, where satellites vanish and magnetization nonlinearly approaches saturation at 1.64(2)µ_{B}/Ce for µ_{∘}H≈7 T.

2.
Arch Oral Biol ; 84: 133-138, 2017 Dec.
Article in English | MEDLINE | ID: mdl-28987726

ABSTRACT

OBJECTIVE: The antimicrobial efficacy of zinc- (ZnCl2) and cetylpyridinium-chloride (CPC) and their inhibition capacity on volatile sulfur compound (VSC) production by oral bacterial strains were investigated. DESIGN: Minimum inhibitory concentrations (MIC) and growth curves were determined for ZnCl2, CPC, and CPC with ZnCl2 solutions against eight oral microorganisms (Aggregatibacter actinomycetemcomitans, Fusobacterium nucleatum, Porphyromonas gingivalis, Prevotella intermedia, Treponema denticola, Tannerella forsythia, Staphylococcus aureus and Streptococcus mutans) known to be involved in the pathophysiology of both halitosis and periodontal disease. Gas chromatography was applied to measure VSCs (H2S, CH3SH, (CH3)2S) production levels of each strains following exposure to the solutions. RESULTS: ZnCl2 and CPC effectively inhibited growth of all eight strains. ZnCl2 was generally more effective than CPC in suppressing bacterial growth excluding A. actinomycetemcomitans, P. intermedia, and T. forsythia. Synergism between CPC and ZnCl2 was shown in A. actinomycetemcomitans. The MIC for CPC was significantly lower than ZnCl2. VSC production was detected in five bacterial strains (A. actinomycetemcomitans, F. nucleatum, P. gingivalis, T. denticola, and T. forsythia). Each bacterial strain showed unique VSCs production profiles. H2S was produced by F. nucleatum, P. gingivalis, and T. denticola, CH3SH by all five strains and (CH3)2S by A. actinomycetemcomitans, F. nucleatum, P. gingivalis, and T. denticola. Production of CH3SH, the most malodorous component among the three major VSCs from mouth air was evident in F. nucleatum and T. forsythia. CONCLUSION: Both ZnCl2 and CPC effectively inhibit bacterial growth causative of halitosis and periodontal disease, resulting in a direct decrease of bacterial VSCs production.


Subject(s)
Anti-Infective Agents, Local/pharmacology , Cetylpyridinium/pharmacology , Chlorides/pharmacology , Gases/metabolism , Halitosis/microbiology , Sulfur Compounds/metabolism , Zinc Compounds/pharmacology , Aggregatibacter actinomycetemcomitans/drug effects , Chromatography, Gas , Fusobacterium nucleatum/drug effects , In Vitro Techniques , Porphyromonas gingivalis/drug effects , Prevotella intermedia/drug effects , Staphylococcus aureus/drug effects , Streptococcus mutans/drug effects , Tannerella forsythia/drug effects , Treponema denticola/drug effects
3.
Proc Natl Acad Sci U S A ; 113(24): 6599-604, 2016 06 14.
Article in English | MEDLINE | ID: mdl-27233936

ABSTRACT

Samarium hexaboride (SmB6), a well-known Kondo insulator in which the insulating bulk arises from strong electron correlations, has recently attracted great attention owing to increasing evidence for its topological nature, thereby harboring protected surface states. However, corroborative spectroscopic evidence is still lacking, unlike in the weakly correlated counterparts, including Bi2Se3 Here, we report results from planar tunneling that unveil the detailed spectroscopic properties of SmB6 The tunneling conductance obtained on the (001) and (011) single crystal surfaces reveals linear density of states as expected for two and one Dirac cone(s), respectively. Quite remarkably, it is found that these topological states are not protected completely within the bulk hybridization gap. A phenomenological model of the tunneling process invoking interaction of the surface states with bulk excitations (spin excitons), as predicted by a recent theory, provides a consistent explanation for all of the observed features. Our spectroscopic study supports and explains the proposed picture of the incompletely protected surface states in this topological Kondo insulator SmB6.


Subject(s)
Boron Compounds/chemistry , Samarium/chemistry , Spectrum Analysis/methods
4.
Int J Oral Maxillofac Implants ; 30(6): 1341-7, 2015.
Article in English | MEDLINE | ID: mdl-26478974

ABSTRACT

PURPOSE: To clarify the antimicrobial efficacy of zinc chloride (ZnCl2) and cetylpyridinium chloride (CPC) by testing their impact on the growth of seven bacterial strains known to be involved in the pathophysiology of both peri-implant disease and halitosis-Staphylococcus aureus, Streptococcus mutans, Porphyromonas gingivalis, Prevotella intermedia, Fusobacterium nucleatum, Treponema denticola, and Tannerella forsythia. MATERIALS AND METHODS: A time-response growth curve was obtained. Commercial mouthrinses with CPC, ZnCl2, or both were added to the media in a final concentration of 0.25% CPC, 2.5% ZnCl2, and 2.5% ZnCl2 with 0.25% CPC. RESULTS: Both CPC and ZnCl2 effectively inhibited the growth of almost all bacterial strains tested except T denticola. ZnCl2 was generally more effective in suppressing bacterial growth than CPC. ZnCl2 with CPC showed the greatest inhibitory activities on almost all strains of bacterial growth except for P gingivalis and T denticola, followed by ZnCl2, then CPC, thus suggesting the possibility of a synergistic effect of the two agents. P gingivalis exhibited a different pattern because ZnCl2 showed the most significant inhibitory effect. CPC did not show growth inhibitory effects on T denticola, but ZnCl2 did. CONCLUSION: Zinc and CPC effectively inhibit bacterial growth that causes both halitosis and peri-implant disease. The effect is even more powerful when applied in combination.


Subject(s)
Anti-Bacterial Agents/pharmacology , Cetylpyridinium/pharmacology , Chlorides/pharmacology , Dental Implants/microbiology , Halitosis/microbiology , Mouthwashes/pharmacology , Peri-Implantitis/microbiology , Stomatitis/microbiology , Zinc Compounds/pharmacology , Anti-Bacterial Agents/administration & dosage , Bacteroides/drug effects , Cetylpyridinium/administration & dosage , Chlorides/administration & dosage , Drug Combinations , Fusobacterium nucleatum/drug effects , Humans , Materials Testing , Mouthwashes/administration & dosage , Porphyromonas gingivalis/drug effects , Prevotella intermedia/drug effects , Staphylococcus aureus/drug effects , Streptococcus mutans/drug effects , Treponema denticola/drug effects , Zinc Compounds/administration & dosage
5.
Science ; 346(6214): 1208-12, 2014 Dec 05.
Article in English | MEDLINE | ID: mdl-25477456

ABSTRACT

In the Kondo insulator samarium hexaboride (SmB6), strong correlation and band hybridization lead to an insulating gap and a diverging resistance at low temperature. The resistance divergence ends at about 3 kelvin, a behavior that may arise from surface conductance. We used torque magnetometry to resolve the Fermi surface topology in this material. The observed oscillation patterns reveal two Fermi surfaces on the (100) surface plane and one Fermi surface on the (101) surface plane. The measured Fermi surface cross sections scale as the inverse cosine function of the magnetic field tilt angles, which demonstrates the two-dimensional nature of the conducting electronic states of SmB6.

6.
Proc Natl Acad Sci U S A ; 111(13): 4798-802, 2014 Apr 01.
Article in English | MEDLINE | ID: mdl-24639519

ABSTRACT

Hybridization between conduction electrons and the strongly interacting f-electrons in rare earth or actinide compounds may result in new states of matter. Depending on the exact location of the concomitant hybridization gap with respect to the Fermi energy, a heavy fermion or an insulating ground state ensues. To study this entanglement locally, we conducted scanning tunneling microscopy and spectroscopy (STS) measurements on the "Kondo insulator" SmB6. The vast majority of surface areas investigated were reconstructed, but infrequently, patches of varying sizes of nonreconstructed Sm- or B-terminated surfaces also were found. On the smallest patches, clear indications for the hybridization gap with logarithmic temperature dependence (as expected for a Kondo system) and for intermultiplet transitions were observed. On nonreconstructed surface areas large enough for coherent cotunneling, we were able to observe clear-cut Fano resonances. Our locally resolved STS indicated considerable finite conductance on all surfaces independent of their structure, not proving but leaving open the possibility of the existence of a topologically protected surface state.

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