Thermal treatment of petroleum-contaminated marine sediment according to oxygen availability and temperature: Product quality as a potential plant-growth medium.

The sustainable management of dredged sediment from contaminated sites needs to consider the end-use of the treated sediment. In this regard, modifying conventional sediment treatment techniques to generate a product that is suitable for a range of terrestrial uses is necessary. In the present study, we evaluated the product quality of treated sediment as a potential plant-growth medium following the thermal treatment of marine sediment contaminated by petroleum. The contaminated sediment was subject to thermal treatment at temperatures of 300, 400, or 500 °C, and no, low, or moderate oxygen availability, and the resulting treated sediment was analyzed in terms of its bulk properties, spectroscopic properties, organic contaminants, water-soluble salts and organic matter, and the leachability and extractability of heavy metals. All operational combinations for the treatment process reduced the total petroleum hydrocarbon content of the sediment from 4922 mg kg-1 to lower than 50 mg kg-1. The thermal treatment process stabilized the heavy metals in the sediment, reducing the zinc and copper concentration by up to 58.9% and 89.6%, respectively, in the leachate from the toxicity characteristic leaching procedure. The hydrophilic organic and/or sulfate salt byproducts of the treatment were phytotoxic, but these can easily be removed by washing the sediment with water. By combining the sediment analysis results with experimental data from barley germination and early-growth tests, the end product was found to be of higher quality when higher temperatures and lower oxygen availability were employed in the treatment process. These findings demonstrate that it is possible to retain the natural organic resources of the original sediment by optimizing the thermal treatment, thus ensuring a suitably high product quality for use as a plant-growth medium.

Coupled effect of porous network and water content on the natural attenuation of diesel in unsaturated soils.

The natural attenuation potential of a vadose zone against diesel is critical for optimizing remedial actions and determining groundwater vulnerability to contamination. Here, diesel attenuation in unsaturated soils was systematically examined to develop a qualitative relationship between physical soil properties and the natural attenuation capacity of a vadose zone against diesel. The uniformity coefficient (Cu) and water saturation (Sw, %) were considered as the proxies reflecting the degree of effects by porous network and water content in different soils, respectively. These, in turn, are related to the primary diesel attenuation mechanisms of volatilization and biodegradation. The volatilization of diesel was inversely proportional to Cu and Sw, which could be attributed to effective pore channels facilitating gas transport. Conversely, biodegradation was highly proportional to Cu under unsaturated conditions (Sw = 35-71%), owing to nutrients typically associated with fine soil particles. The microbial community in unsaturated soils was affected by Sw rather than Cu. The overall diesel attenuation including volatilization and biodegradation was optimized at Sw = 35% for all tested soils.

Effects of treatment agents during acid washing and pH neutralization on the fertility of heavy metal-impacted dredged marine sediment as plant-growing soil.

The present study was aimed at investigating the effects of different acids and pH neutralizers applied to dredged marine sediment for the treatment of heavy metals, and the resulting influence on the sediment quality as a plant growth medium. The inspection of barley germination in the dredged marine sediment revealed that residual salts are critical plant stressors whose adverse effects exceed those exhibited by high-level heavy metals and petroleum hydrocarbons present in the sediment. Acid washing and pH neutralization reduced not only the heavy metal contents but also the sediment salinity (by factors of 6.1-9.5), resulting in 100% germination of barley. For acid-washed and calcium-oxide-neutralized sediment, the barley growth was comparable to that observed in untreated and water washed sediment despite factors of 5.2-8.0 greater sediment salinity in the former. This result represents the protective effect of residual calcium against sodium and chloride toxicity. Water washing of acid-washed and pH-neutralized sediments further enhanced barley growth owing to the reduction in osmotic pressure. This study showed the effect of different sediment-washing reagents on the product quality. It also indicated the significance of balancing the enhancement of product quality and economic cost of further treatment requirements.

Prediction of long-term heavy metal leaching from dredged marine sediment applied inland as a construction material.

Column leaching studies have been suggested as a reference for site-specific prediction of the long-term leaching characteristics of trace constituents in granular materials used as construction materials. In this study, the concept of the long-term leaching prediction using column studies is applied for dredged marine sediment impacted by heavy metals. The column studies show tailing of the liquid to solid ratio-dependent heavy metal leaching for sediment after heavy metal treatment by acid washing. A dual-mode first-order decay model, applied for the first time in this study for column leaching studies, is able to reproduce the leaching characteristics observed. A procedure for long-term leaching prediction using the dual-mode model is developed and applied to a virtual field scenario for which the sediment is beneficially used as a construction material. The prediction results show that by more accurately reproducing the column study results, the dual-mode model generally predicts greater long-term heavy metal loading to the underlying soil layer and longer duration of leaching than the single-mode model. The heavy metal leaching observed in the columns does not show any correlation with the sequential extraction procedure and toxicity characteristic leaching procedure (TCLP) results, suggesting that the column leaching test should be considered to be independent of such batch test procedures.

Assessment of hydrophobic organic contaminant availability in sediments after sorbent amendment and its complete removal.

Sorbents amended to sediments in situ for sequestration of hydrophobic organic contaminants (HOCs) may be swept away from the treated sites due to hydrodynamic forces applied to the sediment surface. The purpose of this study is to examine the possibility of recovery of HOC availability in sorbent-amended sediment after complete removal of the sorbent. Sediment contact with an easily separable model sorbent Tenax beads for 28 days in a slurry phase resulted in 74-98% reduction in polycyclic aromatic hydrocarbon and polychlorinated biphenyl availability compared to the untreated controls. HOC availability in the sorbent-treated sediment slightly increased by sorbent removal and after one month of mixing in a slurry phase because the slowly-desorbing HOC fraction was released and repartitioned back to the sediment, partially replenishing the rapidly-desorbing HOC fraction. However, HOC availability did not further increase during an extended mixing period of 12 months suggesting that the repartitioning process was not an infinite source. HOC availability after the 12-month post-treatment mixing for the sorbent-treated sediment was 53-97% lower than that of the untreated sediment because of the combined effect of HOC mass removal from sediment (with the sorbent) and incomplete recovery of available HOC fraction in the sorbent-treated sediment.