ABSTRACT
Carbon black and titanium dioxide have been widely used as pigment particles for electrophoretic displays. However, the effect of external water vapor on these pigment particles has not yet been presented. Therefore, in this work, we report the clumping phenomenon between pigment particles as a result of water vapor absorption. To verify clumping between pigment particles, various analysis techniques were used, including scanning electron microscopy, atomic force microscopy, zeta potential measurement, and Raman spectroscopy. We examined the Raman spectrum of carbon black to demonstrate the effect of water vapor absorption on particles. According to the Raman spectrum analysis, the 2D and 2D' peak intensities were significantly increased; moreover, the full widths at half maximum were modified. Thus, we concluded that water vapor absorption on pigment particles can induce the clumping phenomenon on pigments. To protect an electrophoretic display device from external gas transmission, we applied a nanocomposites gas barrier film to the device. The device lifetime was consequently improved by 336%.
ABSTRACT
Nanocomposites are potential substitutes for inorganic materials in fabricating flexible gas-barrier thin films. In this study, two nanocomposites are used to form a flexible gas-barrier film that shows improved flexibility and a decreased water vapor transmission rate (WVTR), thereby extending the diffusion path length for gas molecules. The nanoclay materials used for the flexible gas-barrier thin film are Na+-montmorillonite (MMT) and graphene oxide (GO). A flexible gas-barrier thin film was fabricated using a layer-by-layer (LBL) deposition method, exploiting electronic bonding under non-vacuum conditions. The WVTR of the film, in which each layer was laminated by LBL assembly, was analyzed by Ca-test and the oxygen transmission rate (OTR) was analyzed by MOCON. When GO and MMT are used together, they fill each other's vacancies and form a gas-barrier film with high optical transmittance and the improved WVTR of 3.1 × 10-3 g per m2 per day without a large increase in thickness compared to barrier films produced with GO or MMT alone. Thus, this film has potential applicability as a barrier film in flexible electronic devices.
ABSTRACT
A flexible thin gas barrier film formed by layer-by-layer (LBL) assembly has been studied. We propose for the first time that hexagonal boron nitride (h-BN) can be used in LBL assembly. When dispersed in water through sonication-assisted hydrolysis, h-BN develops hydroxyl groups that electrostatically couple with the cationic polymer polydiallyldimethylammonium chloride (PDDA). This process produces hydroxyl-functional h-BN/PDDA nanocomposites. The nanocomposites exhibit well exfoliated and highly ordered h-BN nanosheets, which results in an extremely high visual clarity, with an average transmittance of 99% in the visible spectrum. Moreover, well aligned nanocomposites extend gas diffusion path that reduce water vapor transmission rate to 1.3 × 10-2 g m-2 d-1. The simple and fast LBL process demonstrated here can be applied in many gas barrier applications.
ABSTRACT
Resistive switching memory (ReRAM) has attracted much attention in recent times owing to its fast switching, simple structure, and non-volatility. Flexible and transparent electronic devices have also attracted considerable attention. We therefore fabricated an Al2O3-based ReRAM with transparent indium-zinc-oxide (IZO) electrodes on a flexible substrate. The device transmittance was found to be higher than 80% in the visible region (400-800 nm). Bended states (radius = 10 mm) of the device also did not affect the memory performance because of the flexibility of the two transparent IZO electrodes and the thin Al2O3 layer. The conduction mechanism of the resistive switching of our device was explained by ohmic conduction and a Poole-Frenkel emission model. The conduction mechanism was proved by oxygen vacancies in the Al2O3 layer, as analyzed by x-ray photoelectron spectroscopy analysis. These results encourage the application of ReRAM in flexible and transparent electronic devices.
ABSTRACT
Layer-by-layer (LBL) assembly, which uses electronic and ionic intermolecular bonding under nonvacuum conditions, is a promising technology for fabricating gas barrier films owing to its simple processing and easy formation of a multilayer structure. In this research, nanoclay-polymer multilayers of Na(+)-montmorillonite (Na-MMT) were fabricated. Particularly, the addition of AuCl3 on fabricated MMT layers caused a reaction with the surface silanol functional groups (Si-O-H) of the MMT platelets, resulting in the formation of Au2O3 on the MMT-polymer multilayers. The Au2O3 filled the vacancies between the MMT platelets and linked the MMT platelets together, thus forming a gas barrier film that reduced the water vapor transmission rate (WVTR) to 3.2 × 10(-3) g m(-2) day(-1). AuCl3-treated MMT-polymer multilayers thus have the potential to be utilized for manufacturing gas barrier films for flexible electronics on a large scale.
