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Stainless-Steel Ball-Milling Method for Hydro-/Deutero-genation using H2O/D2O as a Hydrogen/Deuterium Source.
Sawama, Yoshinari; Kawajiri, Takahiro; Niikawa, Miki; Goto, Ryota; Yabe, Yuki; Takahashi, Tohru; Marumoto, Takahisa; Itoh, Miki; Kimura, Yuuichi; Monguchi, Yasunari; Kondo, Shin-ichi; Sajiki, Hironao.
ChemSusChem ; 8(22): 3773-6, 2015 Nov.
Article in English | MEDLINE | ID: mdl-26493945

ABSTRACT

A one-pot continuous-flow method for hydrogen (deuterium) generation and subsequent hydrogenation (deuterogenation) was developed using a stainless-steel (SUS304)-mediated ball-milling approach. SUS304, especially zero-valent Cr and Ni as constituents of the SUS304, and mechanochemical processing played crucial roles in the development of the reactions.


Subject(s)
Deuterium Oxide/chemistry , Deuterium/chemistry , Stainless Steel/chemistry , Hydrogenation
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