Topsoil's magnetic and electrical properties in a volcanic and tropical region.

Environmental monitoring by measuring topsoil's magnetic and electrical properties is one practical, quick, and low-cost approach. This method has been used worldwide as a proxy for the presence of potentially toxic elements. However, additional research must be conducted on diverse soil types, geology, and climates. We determined the magnetic and electrical properties of urban and agricultural topsoils in a volcanic region and analyzed them as possible proxies of potentially toxic elements for environmental monitoring. To identify topsoil characteristics, we employed the measurements of magnetic susceptibility and hysteresis, electrical conductivity, total dissolved solids, power of hydrogen (pH), particle morphology, and element contents that were statistically analyzed to identify relevant properties. The result was able to differentiate volcanic soils from urban, industrial, and agricultural areas as well. The value of low-frequency magnetic susceptibility (χLF) in soils from urban areas is higher than 866.0±249.9 ×10-8 m3 kg-1, while the value of χLF in agricultural areas is 208.0±67.8 ×10-8 m3 kg-1. This is reinforced by the relationship between low-frequency and frequency-dependent magnetic susceptibility (χLF-χFD%) in samples from urban areas that fall within the same cluster dominated by coarse-grained magnetic minerals originating from anthropogenic processes. In contrast, the agricultural area forms a separate cluster primarily influenced by pedogenic processes from acid igneous rock minerals. Caution is required for interpreting the magnetic signal due to the high contents of lithogenic magnetic particles inherited from the parent materials of Andisols.

Magnetic susceptibilities of surface sediments from estuary rivers in volcanic regions.

Estuaries have very complex mechanisms because they are influenced by seawater intrusion, which causes enrichment of contaminants in the maximum turbidity area. Magnetic susceptibility measurements have been used for monitoring a wide variety of environments. However, there have been few studies of the magnetic properties of surface sediments from estuaries in volcanic environments in the tropics. This study investigates the magnetic properties and their correlations with the geochemistry of surface sediments in estuaries in volcanic areas and was conducted in the Krueng Aceh River, Indonesia. Measurements consist of magnetic susceptibility measurements, chemical analysis, and mineralogical analysis. Measurements of magnetic susceptibilities were performed using a Bartington MS2 instrument with an MS2B sensor using frequencies of 460 and 46 kHz. X-ray fluorescence (XRF) and energy-dispersive spectroscopy (EDS) were used to identify elements in the sediments. Scanning electron microscopy (SEM) analysis was used to analyze sediment grains. X-ray diffraction (XRD) analysis was used to determine mineral contents. For the first time, χLF/χFD ratios were found to be an obvious parameter for identifying areas of sediment traps and metal enrichment in the estuary turbidity maxima (ETM) zone. The magnetic properties carried by volcanic rock minerals consist of pigeonite and enstatite. These two minerals have not been previously considered as carriers of sediments with magnetic properties when monitoring heavy metal enrichment in urban rivers. These results provide an extension of the use of magnetic susceptibility measurements in environmental studies, particularly in estuary river environments in volcanic areas such as the Krueng Aceh River, Indonesia.

Magnetic characterizations of nickel hyperaccumulating plants (Planchonella oxyhedra and Rinorea bengalensis) from Halmahera, Indonesia.

Magnetic minerals, such as magnetite and hematite, have been reported to be present, in particular, leaves as biogenic particles. The magnetic minerals and properties of Ni hyperaccumulators have not previously been reported in the literature. This study aimed to characterize the magnetic properties of two Ni hyperaccumulating plant species, R. bengalensis and P. oxyhedra, which grow in an ultramafic region on Halmahera Island, Indonesia. For comparison, similar characterization was carried out on two non-hyperaccumulating plant species which grow in the same region. Concentrations of Ni, Fe, and Mn in the leaves of the hyperaccumulating plants were measured using atomic absorption spectroscopy (AAS) and their magnetic properties were characterized using measurements of magnetic susceptibility, low temperature magnetic susceptibility, and hysteresis curves. The results show that, compared to the non-hyperaccumulating plants, the Ni hyperaccumulating plants have higher concentrations of Ni and similar concentration of Fe. The magnetic susceptibilities of hyperaccumulating plants are positive, and those of non-hyperaccumulating plants are negative. This suggests that the abundance of Ni, rather than Fe, may control the magnetic properties of Ni hyperaccumulating plants. This probable connection between Ni concentration and plant magnetic properties could be advantageous for identifying hyperaccumulators, and should, therefore, be explored further.