Optical characterization of stratified-premixed natural gas direct-injection combustion regimes.

Gaseous fuels for heavy-duty internal combustion engines provide inherent advantages for reducing CO2, particulate matter (PM), and NOX emissions. Pilot-ignited direct-injected NG (PIDING) combustion uses a small pilot injection of diesel to ignite a late-cycle main direct injection of NG, resulting in significant reduction of unburned CH4 emissions relative to port-injected NG. Previous works have identified NG premixing as a critical parameter establishing indicated efficiency and emissions performance. To this end, a recent experimental investigation using a metal engine identified six general regimes of PIDING heat release and emissions behavior arising from variation of NG stratification through control of relative injection timing (RIT) of the NG with respect to the pilot diesel. The objective of the current work is to provide comprehensive description of in-cylinder fuel mixing of direct injected gaseous fuel and its impacts on combustion and pollutant formation processes for stratified PIDING combustion. In-cylinder imaging of OH*-chemiluminescence (OH*-CL) and PM (700 nm), and measurement of local concentration of fuel is considered for 11 different RIT , representing 5 regimes of stratified PIDING combustion (performed with P inj = 22 . 0 MPa and ϕ = 0 . 63 ). The magnitude and cyclic variability of premixed fuel concentration near the bowl wall provides direct experimental validation of thermodynamic metrics ( RI T premix , SO I NG , trans , RI T * ) that describe the fuel-air mixture state of all 5 regimes of PIDING combustion. The local fuel concentration develops non-monotonically and is a function of RIT. High indicated efficiency and low CH4 emissions previously observed for stratified-premixed PIDING combustion in previous (non-optical) investigations are due to: (i) very rapid reaction zone growth ( > 45 m/s) and (ii) more distributed early reaction zones when overlapping pilot and NG injections cause partial pilot quenching. These results connect and extend the findings of previous investigations and guide the future strategic implementation of NG stratification for improved combustion and emissions performance.

Heat release rate and emissions regimes of stratified pilot-ignited direct-injection natural gas combustion.

Natural gas (NG) is an attractive fuel for heavy-duty internal combustion engines because of its potential for reduced CO2, particulate, and NOX emissions and lower cost of ownership. Pilot-ignited direct-injected NG (PIDING) combustion uses a small pilot injection of diesel to ignite a main direct injection of NG. Recent studies have demonstrated that increased NG premixing is a viable strategy to increase PIDING indicated efficiency and further reduce particulate and CO emissions while maintaining low CH4 emissions. However, it is unclear how the combustion strategies relate to one another, or where they fit within the continuum of NG stratification. The objective of this work is to present a systematic evaluation of pilot combustion, NG combustion, and emissions behavior of stratified-premixed PIDING combustion modes that span from fully-premixed to non-premixed conditions. A sweep of the relative injection timing, RIT , of NG and pilot diesel was performed in a heavy-duty PIDING engine with P inj = 140-220 bar, ϕ g = 0.47-0.71, and a constant NG energy fraction of 94%. Apparent heat release rate and emissions analyses identified interactions between the pilot fuel and NG, and qualitatively characterized the impact of NG stratification on combustion and emissions. Changes in the RIT resulted in six distinct PIDING combustion regimes, for all considered injection pressures and equivalence ratios: (i) RIT-insensitive premixed, (ii) stratified-premixed (early-cycle injection), (iii) NG jet impingement transition, (iv) stratified-premixed (late-cycle injection), (v) variable premixed fraction, and (vi) minimally-premixed. Parametric definitions for the bounds of each regime of combustion were valid for the wide range of P inj and ϕ g investigated, and are expected to be relevant for other PIDING engines, as previously identified regimes agree with those identified here. This conceptual framework encompasses and validates the findings of previous stratified PIDING investigations, including optimal ranges of operation that provide significantly increased efficiency and lower emissions of incomplete combustion products.

Comprehensive analysis of the air quality impacts of switching a marine vessel from diesel fuel to natural gas.

New environmental regulations are mandating cleaner fuels and lower emissions from all maritime operations. Natural gas (NG) is a fuel that enables mariners to meet regulations; however, emissions data from maritime operations with natural gas is limited. We measured emissions of criteria, toxic and greenhouse pollutants from a dual-fuel marine engine running either on diesel fuel or NG as well as engine activity and analyzed the impacts on pollutants, health, and climate change. Results showed that particulate matter (PM), black carbon (BC), nitric oxides (NOx), and carbon dioxide (CO2) were reduced by about 93%, 97%, 92%, and 18%, respectively when switching from diesel to NG. Reductions of this magnitude provide a valuable tool for the many port communities struggling with meeting air quality standards. While these pollutants were reduced, formaldehyde (HCHO), carbon monoxide (CO) and methane (CH4) increased several-fold. A health risk assessment of exhaust plume focused on when the vessel was stationary, and at-berth showed the diesel plume increased long-term health risk and the NG plume increased short-term health risk. An analysis of greenhouse gases (GHGs) and BC was performed and revealed that, on a hundred year basis, the whole fuel cycle global warming potential (GWP) per kWh including well-to-tank and exhaust was 50% to few times higher than that of diesel at lower engine loads, but that it was similar at 75% load and lower at higher loads. Mitigation strategies for further reducing pollutants from NG exhaust are discussed and showed potential for reducing short-term health risks and climate impacts.

Characterization and Reduction of In-Use CH4 Emissions from a Dual Fuel Marine Engine Using Wavelength Modulation Spectroscopy.

In-use exhaust stream CH4 emissions from two dual fuel marine engines were characterized and strategies for CH4 reduction were identified and evaluated. For this, a low-cost, portable, wavelength modulation spectroscopy (WMS) system was developed. The performance of the developed WMS sensor was assessed using gas standards and demonstrated on a heavy-duty, diesel pilot ignited, direct-injection natural gas research engine through comparison to a flame ionization detector. The WMS sensor was subsequently used to measure the exhaust-stream CH4 concentration from two diesel pilot-ignited, port-injected natural gas engines on a coastal vessel while under normal operation. Using cylinder deactivation to reduce the excess air ratio, λ, and vessel operation changes to minimize operation at lower loads, the total CH4 emission were reduced by up to 33%. The measured, load specific CH4 emissions were subsequently used to identify an improved vessel operation strategy, with an estimated 56-60% reduction in CH4 emissions. These results demonstrate the importance of considering the real-world engine operation profile for accurate estimates of the global warming potential, as well as the utility of a WMS sensor for characterizing and mitigating in-use CH4 emissions.

Toward enhanced hydrogen generation from water using oxygen permeating LCF membranes.

Hydrogen production from water thermolysis can be enhanced by the use of perovskite-type mixed ionic and electronic conducting (MIEC) membranes, through which oxygen permeation is driven by a chemical potential gradient. In this work, water thermolysis experiments were performed using 0.9 mm thick La0.9Ca0.1FeO3-δ (LCF-91) perovskite membranes at 990 °C in a lab-scale button-cell reactor. We examined the effects of the operating conditions such as the gas species concentrations and flow rates on the feed and sweep sides on the water thermolysis rate and oxygen flux. A single step reaction mechanism is proposed for surface reactions, and three-resistance permeation models are derived. Results show that water thermolysis is facilitated by the LCF-91 membrane especially when a fuel is added to the sweep gas. Increasing the gas flow rate and water concentration on the feed side or the hydrogen concentration on the sweep side enhances the hydrogen production rate. In this work, hydrogen is used as the fuel by construction, so that a single-step surface reaction mechanism can be developed and water thermolysis rate parameters can be derived. Both surface reaction rate parameters for oxygen incorporation/dissociation and hydrogen-oxygen reactions are fitted at 990 °C. We compare the oxygen fluxes in water thermolysis and air separation experiments, and identify different limiting steps in the processes involving various oxygen sources and sweep gases for this 0.9 mm thick LCF-91 membrane. In the air feed-inert sweep case, the bulk diffusion and sweep side surface reaction are the two limiting steps. In the water feed-inert sweep case, surface reaction on the feed side dominates the oxygen permeation process. Yet in the water feed-fuel sweep case, surface reactions on both the feed and sweep sides are rate determining when hydrogen concentration in the sweep side is in the range of 1-5 vol%. Furthermore, long term studies show that the surface morphology changes and silica impurities have little impact on the oxygen flux for either water thermolysis or air separation.