ABSTRACT
To monitor airborne nano-sized particles (NPs), a single-chip differential mobility particle sizer (DMPS) based on resonant micro cantilevers in defined micro-fluidic channels (µFCs) is introduced. A size bin of the positive-charged fraction of particles herein is separated from the air stream by aligning their trajectories onto the cantilever under the action of a perpendicular electrostatic field of variable strength. We use previously described µFCs and piezoresistive micro cantilevers (PMCs) of 16 ng mass fabricated using micro electro mechanical system (MEMS) technology, which offer a limit of detection of captured particle mass of 0.26 pg and a minimum detectable particulate mass concentration in air of 0.75 µg/m3. Mobility sizing in 4 bins of a nebulized carbon aerosol NPs is demonstrated based on finite element modelling (FEM) combined with a-priori knowledge of particle charge state. Good agreement of better than 14% of mass concentration is observed in a chamber test for the novel MEMS-DMPS vs. a simultaneously operated standard fast mobility particle sizer (FMPS) as reference instrument. Refreshing of polluted cantilevers is feasible without de-mounting the sensor chip from its package by multiply purging them alternately in acetone steam and clean air.
ABSTRACT
In this study, we investigate the performance of two piezoresistive micro-electro-mechanical system (MEMS)-based silicon cantilever sensors for measuring target analytes (i.e., ultrafine particulate matters). We use two different types of cantilevers with geometric dimensions of 1000 × 170 × 19.5 µm3 and 300 × 100 × 4 µm3, which refer to the 1st and 2nd types of cantilevers, respectively. For the first case, the cantilever is configured to detect the fundamental in-plane bending mode and is actuated using a resistive heater. Similarly, the second type of cantilever sensor is actuated using a meandering resistive heater (bimorph) and is designed for out-of-plane operation. We have successfully employed these two cantilevers to measure and monitor the changes of mass concentration of carbon nanoparticles in air, provided by atomizing suspensions of these nanoparticles into a sealed chamber, ranging from 0 to several tens of µg/m3 and oversize distributions from ~10 nm to ~350 nm. Here, we deploy both types of cantilever sensors and operate them simultaneously with a standard laboratory system (Fast Mobility Particle Sizer, FMPS, TSI 3091) as a reference.
ABSTRACT
The release of ultra-fine particles from equipment of daily use is currently a topic of high public concern. The present study reports on the measurement of 12 household appliances such as toasters, grills, and hair dryers in an emission test chamber regarding the release of particles between 5.6 and 560 nm. The devices were new at the time experiments started and had never been used for their original purpose. For instance, toasters and sandwich-makers were tested without the presence of food or residues from prior usage. During the experiments the devices released aerosols with count mean diameters mainly below 100 nm. Within the operating phase high quantities of 10 nm particles are released which form larger particles by agglomeration. The origin of the particles can be attributed to the heated surfaces but cleaning these surfaces only had a minor influence on the emission strength. The released particles are evaporated in a thermodenuder between 150 °C and 200 °C. These findings indicate the particles to be formed from semi-volatile organic compounds. However, the compounds are not located on the heated surfaces and are not released as supersaturated vapor because emission is continuous over the operating phase of the device. Furthermore, the contribution of oxygen to the formation process can be neglected because the emission can also be detected in a nitrogen atmosphere. However, the presence of additional organic compounds in the surrounding air was found to be influencing the growth of the particles within the operating phase. All in all the tested household appliances were strong particle emission sources even when there was no contact with food or clothing.
