Kinetics and Mechanisms of ZnO to ZIF-8 Transformations in Supercritical CO2 Revealed by In†Situ X-ray Diffraction.

ZIF-8 was synthesized in supercritical carbon dioxide (scCO2 ). In situ powder X-ray diffraction, ex situ microscopy, and simulations provide an encompassing view of the formation of ZIF-8 and intermediary ZnO@ZIF-8 composites in this nontraditional solvent. Time-resolved imaging exposed divergent physicochemical reaction pathways from previous studies of the growth of anisotropic ZIF-8 core@shell structures in traditional solvents. Synthetically relevant physiochemical properties of scCO2 were integrated into classical nucleation theory, relating interfacial forces, calculated through DFTB+ based molecular dynamics (MD), with 3D nucleation outcomes. The kinetics of crystallization were examined and displayed a characteristic signature of time- and temperature-dependent mechanisms over the extent of the reaction. Lastly, it is shown that subtle factors, such as the extent of reaction and the size/shape of sacrificial templates can tailor ZIF-8 composition and size, eliciting control over hierarchical porosity in a nonconventional green solvent.

Flexible metal-organic supramolecular isomers for gas separation.

Three interpenetrated metal-organic supramolecular isomers were synthesised using a flexible tetrahedral organic linker and Zn(2) clusters that sorb CO(2) preferably over N(2), H(2) and methane at room temperature.