Influence of Chemical Composition on Structure and Mechanical Properties of Vacuum-Carburized Low-Alloy Steels.

This study presents research results concerning the vacuum carburizing of four steel grades, specifically conforming to European standards 1.7243, 1.6587, 1.5920, and 1.3532. The experimental specimens exhibited variations primarily in nickel content, ranging from 0 to approximately 3.8 wt. %. As a comparative reference, gas carburizing was also conducted on the 1.3532 grade, which had the highest nickel content. Comprehensive structural analysis was carried out on the resultant carburized layers using a variety of techniques, such as optical and electron scanning, transmission microscopy, and X-ray diffraction. Additionally, mechanical properties such as hardness and fatigue strength were assessed. Fatigue strength evaluation was performed on un-notched samples having a circular cross-section with a diameter of 12 mm. Testing was executed via a three-point bending setup subjected to sinusoidally varying stresses ranging from 0 to maximum stress levels. The carburized layers produced had effective thicknesses from approximately 0.8 to 1.4 mm, surface hardness levels in the range of 600 to 700 HV, and estimated retained austenite contents from 10 to 20 vol%. The observed fatigue strength values for the layers varied within the range from 1000 to 1350 MPa. It was found that changing the processing method from gas carburizing, which induced internal oxidation phenomena, to vacuum carburizing improved the fatigue properties to a greater extent than increasing the nickel content of the steel.

New Gd3+ and Mn2+-Co-Doped Scheelite-Type Ceramics-Their Structural, Optical and Magnetic Properties.

New Gd3+- and Mn2+-co-doped calcium molybdato-tungstates with the chemical formula of Ca1−3x−yMny▯xGd2x(MoO4)1−3x(WO4)3x (labeled later as CaMnGdMoWO), where ▯ denotes vacant sites in the crystal lattice, 0 < x ≤ 0.2500 and y = 0.0200 as well as 0 < y ≤ 0.0667 and x = 0.1667 were successfully synthesized by high-temperature solid-state reaction method and combustion route. Obtained ceramic materials crystallize in scheelite-type structure with space group I41/a. Morphological features and grain sizes of powders under study were investigated by SEM technique. Spectroscopic studies within the UV-vis spectral range were carried out to estimate the direct band gap (Eg) and Urbach energy (EU) of obtained powders. EPR studies confirmed the existence of two types of magnetic objects, i.e., Mn2+ and Gd3+ ions, and significant antiferromagnetic (AFM) interactions among them.

First step towards understanding the specific identity of fish muscle parasites of the genus Sarcotaces (Copepoda: Philichthyidae)-New species and first molecular ID in the genus.

Parasitic copepods of the genus Sarcotaces are remarkable. They occur in galls inside skeletal muscles of fishes and it is virtually impossible to overlook them, especially during fish handling and processing. The galls contain an intensively black ink-like substance that may stain fish tissue during filleting. They have a global distribution and until recently, seven nominal species had been described, each from a host representing a different fish family. Females of valid species are quite similar in their morphology, therefore the males are essential for species determination. Even though such a task may be difficult, because of the existing inadequate descriptions that additionally hinder correct identification. The aim of this study was to provide a detailed morphological and molecular characterization of the Sarcotaces specimens found in muscles of the common mora, Mora moro (Risso, 1810), most probably originating from southern Australia. The additional aim was to indicate possible mode and strategy of infection for the parasitic copepods of the genus Sarcotaces. The present paper not only describes and illustrates Sarcotaces izawai sp. nov. but also provides its molecular ID based on the COI gene. In addition to traditional light microscopy studies, Scanning Electron Microscopy (SEM) was also used. Males of Sarcotaces izawai sp. nov. differ from those of its congeners: in the host fish family, in the relative proportions of the caudal rami, and in the setal formula of the antennulae. For the first time in this genus, we described the maxillulae. We also discussed the possible mode and strategy of infection and redefined mesoparasitism.

Structure and Properties of Gas-Nitrided, Precipitation-Hardened Martensitic Stainless Steel.

Nanoflex stainless steel is a promising material for medical applications. However, improvement of its mechanical properties without compromising its corrosion resistance is still a challenge. In order to investigate the effect of the nitriding process on the corrosion and wear resistance of Sandvik NanoflexTM steel, a number of processes were carried out in a gas atmosphere with differing ammonia contents in the temperature range of 425-475 °C for 4 h. The mechanical properties and wear resistance of the layers were tested using the nanoindentation and pin-on-disc methods, respectively. In order to assess corrosion resistance, potentiodynamic tests were carried out in Ringer's artificial body fluid and in a 3% aqueous solution of sodium chloride. The results are discussed herein with respect to the microstructural characteristics of the layers studied using light and scanning electron microscopy, X-ray diffraction phase analysis and wavelength dispersive X-ray microanalysis. The structure of nitrided layers included three zones: the subsurface zone composed of nitrides and the zones composed of metastable phases, i.e., the S phase (γN) and expanded martensite (αN) with possible precipitates of nitrides. The third zone adjacent to the steel core was enriched with carbon. The nitrided samples showed significant improvement in the wear rate while maintaining good corrosion resistance in comparison to the non-treated steel. We concluded that nitriding should be carried out at a temperature below 450 °C and in an atmosphere containing no more than approximately 50% ammonia in order to avoid nitrides precipitation.

Microstructure and Mechanical Properties of Welded Joints of 1.4462 Duplex Steel Made by the K-TIG Method.

K-TIG (Keyhole Tungsten Inert Gas) method is a new, emerging welding technology that offers a significant acceleration of the joining process, even for very thick plates. However, its potential for welding of certain materials is still unknown. Particularly challenging are duplex steels as this technology does not allow the use of a filler material, which is crucial for these steels and for weld joint microstructure adjustment. In order to demonstrate the suitability of this technology for single-pass welding of 1.4462 duplex steel detailed studies of the microstructure of the weld joints obtained for different linear energies were carried out and discussed with respect to their mechanical properties. According to the results obtained, the heat-affected zone (HAZ) shows a microstructure similar to the HAZ of duplex steel welded with the traditional TIG multi-pass methods. However, the weld, due to the lack of filler material, had a microstructure different to that typical for duplex steel welded joints and was also characterized by an increased content of ferrite. However, all joints, both in terms of microstructure and mechanical properties, met the requirements of the relevant standards. Moreover, the K-TIG process can be carried out in the linear energy range typical of duplex steel welding, although further optimization is needed.

The Influence of Different Length Aluminum Foam Filling on Mechanical Behavior of a Square Thin-Walled Column.

The demand for lightweight, strong structural profiles is currently high in the transport industry, mechanical engineering, and construction. Therefore, it is important to evaluate their properties, especially mechanical properties. The main objective of this paper is to determine energy absorption coefficients and evaluate the crush resistance of thin-walled aluminum profiles using numerical simulation and empirical verification. This paper presents the compression results of testing of thin-walled aluminum profiles filled with a porous material (cast aluminum foam). The numerical analysis was conducted using the software Abaqus/CAE. Aluminum material data were obtained from a static tensile test performed on a Shimadzu machine. The experiment was performed on an Instron CEAST 9450HES dynamic hammer. Profiles with three shapes of crush initiators filled with aluminum foam measuring 40 mm-200 mm in 20 mm increments were numerically tested. A sample with a concave initiator filled with foams of 40 mm, 60 mm, 80 mm, and 120 mm in length was used to verify the numerical analyses. Energy absorption coefficients were determined from the analyses. The results of both analyses were tabulated to show the percentage differences. The study showed an increase in the Crush Load Efficiency (CLE) index by up to 33% for samples with the same crush initiator. In addition, it was noted that the use of porous fill does not increase the value of initiating Peak Crushing Force (PCF), which indicates the generation of much smaller overloads dangerous for vehicle passengers.

Identification of Grain Oriented SiFe Steels Based on Imaging the Instantaneous Dynamics of Magnetic Barkhausen Noise Using Short-Time Fourier Transform and Deep Convolutional Neural Network.

This paper presents a new approach to the extraction and analysis of information contained in magnetic Barkhausen noise (MBN) for evaluation of grain oriented (GO) electrical steels. The proposed methodology for MBN analysis is based on the combination of the Short-Time Fourier Transform for the observation of the instantaneous dynamics of the phenomenon and deep convolutional neural networks (DCNN) for the extraction of hidden information and building the knowledge. The use of DCNN makes it possible to find even complex and convoluted rules of the Barkhausen phenomenon course, difficult to determine based solely on the selected features of MBN signals. During the tests, several samples made of conventional and high permeability GO steels were tested at different angles between the rolling and transverse directions. The influences of the angular resolution and the proposed additional prediction update algorithm on the DCNN accuracy were investigated, obtaining the highest gain for the angle of 3.6°, for which the overall accuracy exceeded 80%. The obtained results indicate that the proposed new solution combining time-frequency analysis and DCNN for the quantification of information from MBN having stochastic nature may be a very effective tool in the characterization of the magnetic materials.

Resistance of Aluminide Coatings on Austenitic Stainless Steel in a Nitriding Atmosphere.

A new slurry cementation method was used to produce silicide-aluminide protective coatings on austenitic stainless steel 1.4541. The slurry cementation processes were carried out at temperatures of 800 and 1000 °C for 2 h with and without an additional oxidation process at a temperature of 1000 °C for 5 min. The microstructure and thickness of the coatings were studied by scanning electron microscopy (SEM). The intention was to produce coatings that would increase the heat resistance of the steel in a nitriding atmosphere. For this reason, the produced coatings were subjected to gas nitriding at a temperature of 550-570 °C in an atmosphere containing from 40 to 60% of ammonia. The nitriding was carried out using four time steps: 16, 51, 124, and 200 h, and microstructural observations using SEM were performed after each step. Analysis of the chemical composition of the aluminide coatings and reference sample was performed using wavelength (WDS) and energy (EDS) dispersive X-ray microanalysis, and phase analysis was carried out using X-ray diffraction (XRD). The resistance of the aluminide coatings in the nitriding atmosphere was found to depend strongly on the phase composition of the coating. The greatest increase in resistance to gas corrosion under nitriding atmosphere conditions was achieved using a manufacturing temperature of 1000 °C.