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1.
Chem Commun (Camb) ; 49(70): 7708-10, 2013 Sep 11.
Article in English | MEDLINE | ID: mdl-23877656

ABSTRACT

The thermal stability of α''-Fe16N2, which attracts much interest because of its superior magnetic properties featuring a large magnetocrystalline anisotropy (Ku ~ 1 × 10(7) erg cm(-3)) and a large saturation magnetization (Ms ~ 234 emu g(-1)), though unfortunately thermally unstable, has been quantitatively studied.

2.
Chem Commun (Camb) ; 49(25): 2563-5, 2013 Mar 28.
Article in English | MEDLINE | ID: mdl-23423558

ABSTRACT

Carboxylated SiO2-coated α-Fe nanoparticles have been successfully prepared via CaH2-mediated reduction of SiO2-coated Fe3O4 nanoparticles followed by surface carboxylation. These α-Fe-based nanoparticles, which are characterized by ease of coating with additional functional groups, a large magnetization of 154 emu per g-Fe, enhanced corrosion resistivity, excellent aqueous dispersibility, and low cytotoxicity, have potential to be a versatile platform in biomedical applications.


Subject(s)
Carboxylic Acids/chemistry , Ferrosoferric Oxide/chemistry , Magnetite Nanoparticles/chemistry , Silicon Dioxide/chemistry , Animals , CHO Cells , Cell Line, Tumor , Cell Survival/drug effects , Cricetinae , Cricetulus , Humans , Magnetic Resonance Imaging , Magnetite Nanoparticles/toxicity , Neoplasms/diagnostic imaging , Radiography
3.
J Agric Food Chem ; 58(20): 11014-7, 2010 Oct 27.
Article in English | MEDLINE | ID: mdl-20923150

ABSTRACT

The leaves of coriander ( Coriandrum sativum L.) exhibited a strong deodorizing effect against porcine internal organs (large intestine). The effective deodorizing compounds of coriander were identified by separating the volatile component of coriander, testing the effectiveness of each fraction against the offensive odor of porcine large intestine, and then identifying the compounds by GC-MS. The volatile component of coriander was first separated into six fractions (A-F) by preparative gas chromatography, and the deodorizing activity of each of these fractions against the offensive odor was measured. Fraction D, which showed the strongest deodorizing effect, was then separated into 12 subfractions by preparative GC. The deodorant activity of each subfraction was evaluated, and the deodorant compounds were identified by GC-MS. It was discovered that (E,E)-2,4-undecadienal was the most effective deodorizing compound. The deodorizing activity of (E,E)-2,4-undecadienal on the porcine large intestine increased as with concentration, reaching almost complete deodorizing ability at 10 ppb.


Subject(s)
Aldehydes/chemistry , Aldehydes/pharmacology , Coriandrum/chemistry , Intestine, Large/drug effects , Odorants/analysis , Plant Extracts/chemistry , Plant Extracts/pharmacology , Aldehydes/isolation & purification , Animals , Food Handling , Gas Chromatography-Mass Spectrometry , Plant Extracts/isolation & purification , Plant Leaves/chemistry , Swine
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