Soil erosion and degradation assessment integrating multi-parametric methods of RUSLE model, RS, and GIS in the Shaqlawa agricultural area, Kurdistan Region, Iraq.

This study evaluated soil erosion rates in the Shaqlawa district using the Geographical Information System (GIS)-based Revised Universal Soil Loss Equation (RUSLE) model. The primary objective was to identify areas within the district that are prone to significant erosion and develop appropriate soil conservation schemes accordingly. A combination of primary and secondary data from diverse sources was utilized to achieve this objective. The GIS-based RUSLE model used variables like soil erodibility (K), soil coverage (C), topographic effect (LS), rainfall runoff (R), and erosion control practices (P) to estimate the amount of soil that had been washed away in the study area. The study provided valuable information that can be used to plan and administer soil protection in the Shaqlawa district. The average yearly soil loss in the study region is estimated to be 65.66 t ha-1 year-1. The district is experiencing significant soil erosion rates, which may have detrimental effects on agricultural productivity, water quality, and environmental health. The analysis revealed that Balisan, Hiran, Shaqlawa center, and part of the Salahaddin subdistrict are the most affected areas, with high values of LS and R factors contributing to significant soil erosion rates. These results underscore the importance of soil protection and management efforts in the Shaqlawa district. The combination of the RUSLE with GIS and remote sensing techniques has been recognized as an essential, cost-effective, and highly accurate approach for estimating soil erosion.

A case study of environmental pollution by pathogenic bacteria and metal(oid)s at Soran Landfill Site, Erbil, Iraqi Kurdistan Region.

Environmental pollution is a serious issue all around the world, especially when it is caused by metal(oid)s and pathogenic microorganisms. This study reports here for the first time on the contamination of soil and water with metal(oid)s and pathogenic bacteria directly resulting from the Soran Landfill Site. Soran landfill is a level 2 solid waste disposal site that lacks leachate collection infrastructure. The site is potentially an environmental and public hazard caused by metal(oid)s content and significantly dangerous pathogenic microorganisms through leachate release into the soil and nearby river. This study reports on the levels of the metal(oid)s content of As, Cd, Co, Cr, Cu, Mn, Mo, Pb, Zn, and Ni obtained by inductively coupled plasma mass spectrometer in soil, leachate stream mud, and leachate samples. Five pollution indices are used to assess potential environmental risks. According to the indices, Cd and Pb contamination is significant, whereas As, Cu, Mn, Mo, and Zn pollution is moderate. A total of 32 isolates of bacteria were defined from soil, leachate stream mud, and liquid leachate samples: 18, 9, and 5, respectively. Moreover, 16 s rRNA analysis suggested that the isolates belong to three enteric bacterial phyla of Proteobacteria, Actinobacteria, and Firmicutes. The closest GenBank matches of 16S rDNA sequences indicated the presence of the genera: Pseudomonas, Bacillus, Lysinibacillus, Exiguobacterium, Trichococcus, Providencia, Enterococcus, Macrococcus, Serratia, Salinicoccus, Proteus, Rhodococcus, Brevibacterium, Shigella, Micrococcus, Morganella, Corynebacterium, Escherichia, and Acinetobacter. The identity percentage was mostly between 95%-100%. The results of this study show the levels of microbiological and geochemical contamination of soils, surface and potentially ground water with harmful microorganisms and toxic metal(oid)s originating specifically from Soran landfill leachate which subsequently incorporated into the surrounding environment, creating thus a considerable health and environmental risk.

Time Series Modelling and Simulating the Lockdown Scenarios of COVID-19 in Kurdistan Region of Iraq.

INTRODUCTION: Since the first published cases of the Coronavirus disease known as COVID-19 in the city of Wuhan Hubei Province in China, up until to the time of preparation of this report in mid-September 2020, more than 30 million people have been infected all over the world. In March 2020, more than 300,000 cases have been reported all over Iraq. This study aims to represent data analysis, modelling and forecasting approaches to the presented data in the Kurdistan Region of Iraq. METHODOLOGY: The project involves mathematical models for forecasting and artificial simulations using particles. In the study, time series models including Simple Exponential Model, Holt's Method and Brown's Models have been used for the forecasting of the future potential rates in the area. A series of simulations have been conducted to observe the possibilities of virus spread rates in a virtual world which represents a quarter of Erbil. RESULTS: The outcome of the study shows how the disease have spread in Kurdistan, and what are the current rates to compare with neighbour regions. The modelling clearly shows that with cases still sporadically appearing, the risk of second and third waves of infections is high. CONCLUSIONS: Therefore, the regional government must reduce unnecessary gatherings to the lowest possible level. A scientific registry system of disease statistics must be put in place and rigorously updated all the times. We recommend the officials use a nationwide database provided to the public to monitor movement of every infected individual, to prevent further spread.

Greener pathway toward the synthesis of lichen-based ZnO@TiO2@SiO2 and Fe3O4@SiO2 nanocomposites and investigation of their biological activities.

A green way is introduced to biosynthesis of ZnO@TiO2@SiO2 and Fe3O4@SiO2 nanocomposites using the bioactive potential of Lecanora muralis (LM) lichen. UV-Vis spectroscopy and GC-Mass analysis of the lichen show the presence of various bioactive constituents inside the lichen aqueous extract. The XRD, SEM, EDS, and elemental mapping techniques revealed the well fabrication of biosynthesized nanostructures. Also, investigation of antibacterial and antifungal activities of nanostructures demonstrated that green synthesized nanostructures have a very good antibacterial ability against Staphylococcus aureus, Escherichia coli, Pseudomonas spp. and Candida spp. pathogenic bacteria, and fungi but no antifungal activity toward the Aspergillus flavus, Aspergillus niger, and Aspergillus terrus fungi species.

Modification of rheological and filtration characteristics of water-based mud for drilling oil and gas wells using green SiO2@ZnO@Xanthan nanocomposite.

In this study, a green, simple and economical approach was used to synthesise the SiO2@ZnO@Xanthan nanocomposite (NC) to modify the rheological and filtration characteristics of the water-based drilling mud. The green synthesised NCs were identified using scanning electron microscopy, energy dispersive X-ray spectroscopy, elemental mapping, X-ray diffraction and UV-Vis analytical techniques. Additionally, the effect of SiO2@ZnO@Xanthan NCs on the filtration and rheological properties of mud including apparent viscosity, plastic viscosity, yield point, gel strength, mud cake and fluid loss was investigated. The obtained results confirmed that the synthesised NCs effectively improved the rheological properties of drilling mud, and considerably decreased its fluid loss and filter cake by about 54 and 92.5%, respectively. The results highly recommend the SiO2@ZnO@Xanthan NC as an excellent additive to improve the rheological properties, and reduce the fluid loss and the filter cake of the drilling mud.

Biosynthesis of reusable and recyclable CuO@Magnetite@Hen Bone NCs and its antioxidant and antibacterial activities: a highly stable magnetically nanocatalyst for excellent reduction of organic dyes and adsorption of polycyclic aromatic hydrocarbons.

For the first time, through a fast, eco-friendly and economic method, the aqueous extract of the leaf of Euphorbia corollate was used to the green synthesis of the highly stable CuO@Magnetite@Hen Bone nanocomposites (NCs) as a potent antioxidant and antibacterial agent against Pseudomonas aureus, Staphylococcus aureus, Escherichia coli and Klebsiella pneumoniae pathogenic bacteria. The biosynthesised NCs were identified using the scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy, elemental mapping, X-ray diffraction (XRD), Fourier transforms infrared spectroscopy and UV-vis analytical techniques. Also, the radical scavenging activity using (2,2-diphenyl-1-picrylhydrazyl) method was used to evaluate the antioxidant activity of the NCs. The stability of nanocatalyst was monitored using the XRD and SEM analyses after 30 days from its synthesis. Furthermore, its excellent catalytic activity, recycling stability, and high substrate applicability were demonstrated to the adsorption of the polycyclic aromatic hydrocarbons of the light crude oil from Shiwashok oil fields and destruction of methylene blue and methyl orange as harmful organic dyes at ambient temperature using UV-vis spectroscopy. Moreover, the green CuO@Magnetite@Hen Bone NCs were recovered and reused several times without considerable loss of its catalytic activity.

Assessment of heavy metal release into the soil after mine clearing in Halgurd-Sakran National Park, Kurdistan, Iraq.

The aim of this study was to assess the heavy metal pollution in soils after mine clearance and disposal through controlled explosions in dugout pits during demining operations at two hotspot areas, in the Halgurd-Sakran National Park (HSNP). This investigation was undertaken in order to reveal the concentration level, migration and enrichment in various heavy metals present in polluted soils. Eighteen samples, nine sampling positions at each site, were collected. The current study used inductively coupled plasma-emission spectroscopy (ICP-ES) methodology to determine the concentration levels of Cu, Pb, Zn, Ni, Co, Mn, As and Cr in the soil samples as important toxic contaminants resulting from the demining process. The results show concentration levels of 63.33, 16.22, 116.44, 328, 32.66, 1594.33, 7 and 291.55 ppm in site 1 for Cu, Pb, Zn, Ni, Co, Mn, As and Cr, respectively, while site 2 gave 72.55, 17, 102.55, 296.55, 32, 1851.88, 9.11 and 308.77 ppm. Soil enrichment factor (EF) in sites 1 and 2 of the heavy metals Ni, Cr, Mn, Co and Cu ranged from extremely high enrichment to moderate-high enrichment, respectively. The geo-accumulation (I-geo) index indicated contamination levels that ranged from very strongly to moderately contaminated soil for Ni, Cr, Mn, Co and Cu, respectively. On the other hand, the pollution load index (PLI) showed all values from all samples in both sites were above 1 indicating totally contaminated areas. However, the most polluting heavy metals in the soil at both sites are Ni and Cr with high contamination levels attributed to the controlled mines' detonations. In conclusion, these mines' detonations are producing residual heavy metals in the soil that are potentially harmful to the vegetation cover, animals and ultimately humans.

Natural iron ore as a novel substrate for the biosynthesis of bioactive-stable ZnO@CuO@iron ore NCs: a magnetically recyclable and reusable superior nanocatalyst for the degradation of organic dyes, reduction of Cr(vi) and adsorption of crude oil aromatic compounds, including PAHs.

For the first time, stable ZnO@CuO@iron ore nanocomposites (NCs) were green synthesized using magnetic iron ore as a natural substrate through an eco-friendly, simple and cost-effective method. The biosynthesized nanocatalyst was characterized using the SEM, EDS, elemental mapping, point analysis, XRD, FT-IR, polarized microscopy and UV-vis analytical techniques. The XRD and SEM methods confirmed the excellent stability of the nanocatalyst, even for 6 months. Also, the antioxidant ability of the green-synthesized NCs using a DPPH method was assessed per gallic acid and in contrast with ascorbic acid. Furthermore, their antibacterial activities against the common pathogenic bacteria of Pseudomonas aureus, Staphylococcus aureus and Escherichia coli were evaluated at different concentrations compared to chloramphenicol as a positive control. Moreover, the superior catalytic activity of the ZnO@CuO@iron ore NCs was investigated during a series of reactions, including the adsorption of polycyclic aromatic hydrocarbons (PAHs) of heavy crude oil (HCO) obtained from the Shaikhan oil field, the destruction of some organic dyes at room temperature, including methylene blue (MB) and methyl orange (MO), thymol blue (TB), bromothymol blue (BTB), phenol red (Ph.R), methyl red (MR), solochrome black T (SBT) and eriochrome black T (EBT) and finally the reduction of Cr(vi) at ambient temperature using UV-vis spectroscopy. Finally, the magnetic NCs could be simply recovered and reused several times without considerable loss of catalytic activity.

Microbial dissolution of hematite and associated cellular fossilization by reduced iron phases: a study of ancient microbe-mineral surface interactions.

We report here on magnetite- and wustite-encrusted and geometrically oriented microbial-like structures (MLS) attached to the surfaces of hematite (alpha-Fe(2)O(3)) crystals in a banded iron formation. Field emission scanning electron microscope (FE-SEM) and scanning electron microscope (SEM) imaging showed a 3-D network of MLS arranged in 1 microm x approximately 20 microm coccoidal-like chains (CLC) of various geometrical shapes: dichotomous and budding-like protrusions, parallel, intersecting, triangular, or sinusoidal. Individual spheroidal forms ( approximately 1 mum in diameter), some displaying what appears to be division, were also abundant. In addition to their size, morphology, and preferred orientations, a microbial origin of these chains and single spheroidal forms is inferred by the presence of material that resembles extracellular polymeric substances (EPS) extending from the base of the chains along the mineral surface: the attachment sites show circular dissolution pits of about 100 nm diameter. Other thin structures protruding from the CLC are reminiscent of bacterial "nanowires." We were, however, unable to find any extant cells, organic carbon, or even recover DNA from the MLS, which suggests that they, if microbial, are possibly mineralogically replaced casts or mineral encrustations of cells. It is further speculated that, given the nature of the substrate upon which the forms are attached and their preferential orientations, it seems plausible that the "original cells" may have been Fe(III)-reducing bacteria that exploited structural imperfections in the crystal lattice. Importantly, the preservation of the ancient microbial shapes in mineral casts of magnetite, wustite, or both may be an overlooked means by which cellular features in the rock record are retained.