Dynamics of active liquid interfaces.

Controlling interfaces of phase-separating fluid mixtures is key to the creation of diverse functional soft materials. Traditionally, this is accomplished with surface-modifying chemical agents. Using experiment and theory, we studied how mechanical activity shapes soft interfaces that separate an active and a passive fluid. Chaotic flows in the active fluid give rise to giant interfacial fluctuations and noninertial propagating active waves. At high activities, stresses disrupt interface continuity and drive droplet generation, producing an emulsion-like active state composed of finite-sized droplets. When in contact with a solid boundary, active interfaces exhibit nonequilibrium wetting transitions, in which the fluid climbs the wall against gravity. These results demonstrate the promise of mechanically driven interfaces for creating a new class of soft active matter.

Topological structure and dynamics of three-dimensional active nematics.

Topological structures are effective descriptors of the nonequilibrium dynamics of diverse many-body systems. For example, motile, point-like topological defects capture the salient features of two-dimensional active liquid crystals composed of energy-consuming anisotropic units. We dispersed force-generating microtubule bundles in a passive colloidal liquid crystal to form a three-dimensional active nematic. Light-sheet microscopy revealed the temporal evolution of the millimeter-scale structure of these active nematics with single-bundle resolution. The primary topological excitations are extended, charge-neutral disclination loops that undergo complex dynamics and recombination events. Our work suggests a framework for analyzing the nonequilibrium dynamics of bulk anisotropic systems as diverse as driven complex fluids, active metamaterials, biological tissues, and collections of robots or organisms.

How Supertough Gels Break.

Fracture of highly stretched materials challenges our view of how things break. We directly visualize rupture of tough double-network gels at >50% strain. During fracture, crack tip shapes obey a x∼y^{1.6} power law, in contrast to the parabolic profile observed in low-strain cracks. A new length scale ℓ emerges from the power law; we show that ℓ scales directly with the stored elastic energy and diverges when the crack velocity approaches the shear wave speed. Our results show that double-network gels undergo brittle fracture and provide a testing ground for large-strain fracture mechanics.

Topological defects govern crack front motion and facet formation on broken surfaces.

Cracks develop intricate patterns on the surfaces that they create. As faceted fracture surfaces are commonly formed by slow tensile cracks in both crystalline and amorphous materials, facet formation and structure cannot reflect microscopic order. Although fracture mechanics predict that slow crack fronts should be straight and form mirror-like surfaces, facet-forming fronts propagate simultaneously within different planes separated by steps. Here we show that these steps are topological defects of crack fronts and that crack front separation into disconnected overlapping segments provides the condition for step stability. Real-time imaging of propagating crack fronts combined with surface measurements shows that crack dynamics are governed by localized steps that drift at a constant angle to the local front propagation direction while their increased dissipation couples to long-ranged elasticity to determine front shapes. We study how three-dimensional topology couples to two-dimensional fracture dynamics to provide a fundamental picture of how patterned surfaces are generated.

Nonlinear Focusing in Dynamic Crack Fronts and the Microbranching Transition.

Cracks in brittle materials produce two types of generic surface structures: facets at low velocities and microbranches at higher ones. Here we observe a transition from faceting to microbranching in polyacrylamide gels that is characterized by nonlinear dynamic localization of crack fronts. To better understand this process we derive a first-principles nonlinear equation of motion for crack fronts in the context of scalar elasticity. Its solution shows that nonlinear focusing coupled to rate dependence of dissipation governs the transition to microbranching.

Crack front dynamics: the interplay of singular geometry and crack instabilities.

When fast cracks become unstable to microscopic branching (microbranching), fracture no longer occurs in an effective 2D medium. We follow in-plane crack front dynamics via real-time measurements in brittle gels as microbranching unfolds and progresses. We first show that spatially local energy balance quantitatively describes crack dynamics, even when translational invariance is badly broken. Furthermore, our results explain microbranch dynamics; why microbranches form along spatially localized chains and how finite-time formation of cusps along the crack front leads to their death.

Simple nonlinear equation for structural relaxation in glasses.

A wide range of glassy and disordered materials exhibit complex, nonexponential, structural relaxation (aging). We propose a simple nonlinear rate equation δ = a[1-exp(b δ)], where δ is the normalized deviation of a macroscopic variable from its equilibrium value, to describe glassy relaxation. Analysis of extensive experimental data shows that this equation quantitatively captures structural relaxation, where a and b are both temperature- and, more importantly, history-dependent parameters. This analysis explicitly demonstrates that structural relaxation cannot be accurately described by a single nonequilibrium variable. Relaxation rates extracted from the data imply the existence of cooperative rearrangements on a supermolecular scale.

Navier-Stokes hydrodynamics of thermal collapse in a freely cooling granular gas.

We show that, in dimension higher than one, heat diffusion and viscosity cannot arrest thermal collapse in a freely evolving dilute granular gas, even in the absence of gravity. Thermal collapse involves a finite-time blowup of the gas density. It was predicted earlier in ideal, Euler hydrodynamics of dilute granular gases in the absence of gravity, and in nonideal, Navier-Stokes granular hydrodynamics in the presence of gravity. We determine, analytically and numerically, the dynamic scaling laws that characterize the gas flow close to collapse. We also investigate bifurcations of a freely evolving dilute granular gas in circular and wedge-shaped containers. Our results imply that, in general, thermal collapse can only be arrested when the gas density becomes comparable with the close-packing density of grains. This provides a natural explanation to the formation of densely packed clusters of particles in a variety of initially dilute granular flows.

Energy transfer by inertial waves during the buildup of turbulence in a rotating system.

We study the transition from fluid at rest to turbulence in a rotating tank. The energy is transported by inertial wave packets through the fluid volume. These high amplitude waves propagate at velocities consistent with those calculated from linearized theory [H. P. Greenspan, (Cambridge University Press, Cambridge, England, 1968)]. A "front" in the temporal evolution of the energy power spectrum indicates a time scale for energy transport at the linear wave speed. Nonlinear energy transfer between modes is governed by a different, longer, time scale. The observed mechanisms can lead to significant differences between rotating and two-dimensional turbulent flows.