ABSTRACT
Reusing or recycling waste into new useful materials is essential for environmental protection. Herein, we used discarded polystyrene (PS) and fly-ash (FA) particles and a fabricated fly-ash incorporated polystyrene fiber (FA/PS fiber) composite. The electrospinning process produced continuous PS fibers with a good distribution of FA particles. The prepared nanofibers were characterized by state-of-the-art techniques. The performances of the composite nanofibers were tested for fire-retardant applications. We observed that the incorporation of FA particles into the PS fibers led to an improvement in the performance of the composite as compared to the pristine PS fibers. This study showed an important strategy in using waste materials to produce functional nanofibers through an economical procedure. We believe that the strategy presented in this paper can be extended to other waste materials for obtaining nanofiber membranes for various environmental applications.
ABSTRACT
The rigorous fabrication of electrode materials using upper-ranked porous precursor especially metal organic frameworks (MOFs) are challenging but appealing task to procure electrochemical energy storage and conversion system with altitudinous performance. Herein, we replenish the rational construction of atypical electrode of hollow Zn-Ni-Co-oxide (ZNCO) nanosheet arrays onto rGO garnished Ni foam (rGO/NF) via two step solution based method. Firstly, 2D Zn-Co-MOFs derived nanoleave arrays are prepared by co-precipitation method. Next, hollow and porous ZNCO nanostructure from 2D solid nanoleave arrays are achieved by ion-exchange and etching process conjoined with post annealing treatment. The as-fabricated hierarchical ZNCO nanosheet arrays offer large numbers of electroactive sites with short ion-diffusion pathways, reflecting the outstanding electrochemical performance in-terms of excellent specific capacity (267 mAh g-1) ultra-high rate capability (83.82% at 50 A/g) and long-term cycling life (~90.16%) in three electrode configuration for supercapacitor (SCs). Moreover, the hollow and porous ZNCO nanostructure responds as immensely active and substantial electrocatalyst for methanol oxidation with lowest onset potential of 0.27 V. To demonstrate the practicability, hybrid supercapacitor (HSC) device is constructed using ZNCO@rGO-NF nanostructure as positive and rGO decorated MOF derived porous carbon (rGO-MDPC) as negative electrode. The as-assembled ZNCO//rGO-MDPC ASC device delivers higher energy density of 61.25 Wh kg-1 at the power density of 750 W kg-1 with long-term cyclic stability (<6% to its initial specific capacity value) after 6000 cycles.
ABSTRACT
The most efficient method for obtaining high concentration, monodispersed quantum dots is the sol gel method. This manuscript reports room temperature photoluminescence (PL) of lead sulfide (PbS) quantum dots with the effect of a capping agent. Lead sulfide quantum dots were prepared from a waveguide sol gel material with an organic-inorganic capping agent. The quantum dots were made using silica, a photoreactive methylmethacrylate group and a zirconia sol gel solution to give various concentrations of PbS quantum dots. UV-visible absorption spectra linearly increased with increasing PbS quantum dot concentration up to 10 649 ppm, after which increase was nonlinear. At room temperature, strong photoluminescence was achieved with a weak excitation light source, and the intensity increased almost linearly. This indicated that the quantum dots were distributed uniformly in the sol gel matrix. The thermal process slightly reduced the luminescence intensity. A red shift due to band gap energy was observed from 1.55 eV to 1.49 eV.
Subject(s)
Lead/chemistry , Quantum Dots/chemistry , Sulfides/chemistry , Luminescence , Particle Size , TemperatureABSTRACT
BACKGROUND: This study is focused on a rapid and safe transfer when there are many people who need rescuing in unapproachable location. Generally, a stretcher, a basket or a mesh drawing is used to transfer injured people or survivors in the emergency rescue, however, it turned out that it takes long time to transfer a number of people with a stretcher and it is difficult to transfer injured people safely with a basket or a mesh drawing. It would expect to transfer many people who need rescuing promptly and harmlessly. METHODS: In this article, Targeted Acceptable Responses to Generated Events of Tasks (TARGETS), an event-based team performance measurement methodology was used to investigate the effects of Mission Oriented Protective Posture (MOPP) on the behavioral processes underlying team performance during simulated rescue tasks while wearing chemical protective equipment. In addition, this study determined which team processes were related to team performance outcomes. Results of six primary analyses indicated that team process performance was not degraded by MOPP 4 on any rescue task and that the team processes critical for successful task performance are task-dependent. RESULTS: As a result, authors have developed a new life-saving equipment. Numerous people who need rescuing can be quickly and safely rescued and transferred to the hospital with it. From a medical point of view, it reduces the risk of secondary damage from transport and helps avoid missing the golden time for first aid caused by delay in transferring emergency patients as numerous people can be transferred safely and quickly. CONCLUSION: The article is due to introduce the equipment which can transfer people who need rescuing promptly and effectively in a situation such as when numerous people need rescuing in the mountain. In a rescue situation such as mountain rescue, rope connected life-saving equipment is dropped to the rescue site with a rope from a rescue helicopter and laying down the injured on the life-saving equipment body and equip life-saving equipment to the rope consecutively. In this way, it is expected to transfer the injured rapidly and safely.
