ABSTRACT
Polyurethanes (PUs) are an important class of polymers due to their low density and thermal conductivity combined with their interesting mechanical properties-they are extensively used as thermal and sound insulators, as well as structural and comfort materials. Despite the broad range of applications, the production of PUs is still highly petroleum-dependent. The use of carbohydrates in PU synthesis has not yet been studied extensively, even though, as multihydroxyl compounds, they can easily serve as crosslinkers in PU synthesis. Partially or potentially biobased di-, tri- or poly-isocyanates can further be used to increase the renewable content of PUs. In our research, PU films could be easily produced using two bio-based isocyanates-ethyl ester L-lysine diisocyanate (LLDI] and ethyl ester l-lysine triisocyanate (LLTI)-, one commercial isocyanate-isophorone diisocyanate (IPDI), and a bio-based white dextrin (AVEDEX W80) as a crosslinker. The thermal and mechanical properties are evaluated and compared as well as the stability against solvents.
ABSTRACT
The polyurethane industry is strongly dependent on fossil-based polyols and polyisocyanates. Developing novel sustainable polyols from valuable biobased building blocks is a first step toward strong and durable development. The synthesis and properties of PU films based on pristine and acylated white dextrins (AVEDEX W80) as polyol and an aliphatic, low-viscosity, solvent-free triisocyanate based on hexamethylene diisocyanate (trimer-Desmodur N3300) as crosslinker is reported. After optimizing several conditions, such as the reaction time, reaction temperature, amount of solvent, isocyanate index, and amount per surface area, it is possible to obtain smooth PU films with good thermal properties.
