Regularities of 137Cs distribution in the soil and vegetation cover of elementary landscape-geochemistry system within the forest test plot in the Chernobyl NPP exclusion zone.

The main goal of the investigation was to reveal the lateral and vertical regularities of element distribution in the elementary landscape-geochemical system (ELGS) type: summit-slope-closing depression. We used an isotope 137Cs as a tracer of migration of chemical elements in soil and vegetation cover. The study was performed in a test site characterizing undisturbed forest landscapes in the Russian zone of the Chernobyl accident. Investigated ELGS was 16-m long with a relative height difference of 1.5 m. Field measurements of 137Cs activity was performed with a 1-meter step by the modified portable gamma-spectrometer Violinist-III (USA). Cs-137 content in moss and soil cores sampled with the same lateral step was determined in the laboratory using Canberra (USA, HPGe detector). The upper soil layer 8-cm thick contained from 70 to 96% of 137Cs, and 89-99% of the total inventory was fixed in the top 20-cm layer. Cs-137 activity in both the soil and moss cover demonstrated a cyclic type of variability, which was described and modeled using Fourier analysis. Correlation between the actual and modeled activity values (r0.01 = 0.868) showed that three main harmonics are sufficient for representative modeling of the observed cycles. We infer that the revealed patterns are characteristic for most of the chemical elements and may be useful for practical purposes.

Experimental study of the sorption properties of natural zeolite-containing tripolite and their ability to purify aqueous solutions contaminated with Ni and Zn.

Sorption properties of natural zeolite-containing tripolite from the Khotynetsky deposit (Russia, Oryol region) were studied to evaluate their possibility to purify ground waters contaminated by technogenic Ni2+ and Zn2+. According to experimental data the total ion-exchange capacity of the natural tripolite sample equaled to 1.79 mg-eq/g. The kinetic experiments showed that equilibrium in the studied rock-solution system took place after 500 h of interaction. In the range of the used Ni2+ and Zn2+ concentrations (2-10 mg/L) after 21 days of interaction with natural tropolite suspension, the sorption of the studied ions can be approximated by a linear isotherm, zinc being sorbed much better than nickel: the average values of distribution coefficients (Kd) obtained for 0.003 N CaCl2 aquatic solution equaled to 2.7 × 103 ml/g for Ni2+ and 6.7 × 103 ml/g for Zn2+. Therefore, natural zeolite-containing tripolite of the Khotinetsky deposit can be used for extraction of technogenic Ni2+ and Zn2+ from natural surface and ground waters contaminated by these ions and can be considered as an effective natural sorbent for solving environmental problems.

Spatial geochemical differentiation of the iodine-induced health risk and distribution of thyroid cancer among urban and rural population of the Central Russian plain affected by the Chernobyl NPP accident.

The main goal was to study the spatial distribution of thyroid cancer (THYC) among the population of urban and rural settlements of four regions of Russia, which were characterized by different contents of stable iodine in soils and exposed to radioactive fallout of 131I from the Chernobyl NPP. Using GIS technologies, zoning of territories for the deficiency of 127I and pollution with 131I was performed. The resulting risk maps were compared with the THYC distribution. The association between the spatial distribution of the total (natural and man-made) risk assessment and the incidence of THYC at the district level tended to have a higher positive correlation (r = 0.505, p < 0.001, n = 94) compared with the correlation of the latter parameter with a fallout density of 131I (r = 0.468, p < 0.001). After latent period, the incidence of THYC among residents of urban settlements of the Bryansk region was considerably higher than in rural, the difference increasing with time. The correlation between the assessed total risk and THYC distribution in risk zones was significant and higher in the rural areas than in the urban ones. A tendency for a negative significant correlation (r = - 0.55, p = 0.01) between daily iodine intake (based on the main components of the diet) and THYC cases among the rural population was found. A definite difference in the influence of geochemical environmental factors on the distribution of THYC among urban and rural populations deserves more detailed study to prevent this disease.

Vertical distribution of anthropogenic radionuclides in cores from contaminated floodplains of the Yenisey River.

The Mining and Chemical Industrial Combine, Zheleznogorsk (MCIC, previously known as Krasnoyarsk-26) on the River Yenisey has contaminated the surrounding environment with anthropogenic radionuclides as a result of discharges of radioactive wastes. The purpose of this study was to investigate the vertical distribution of anthropogenic contamination ((137)Cs and plutonium) within floodplain areas at different distances from the discharge point. Sites were chosen that display different characteristics with respect to periodic inundation with river water. Cs-137 activity concentrations were in the range 23-3770 Bq/kg (dry weight, d.w.); Pu-239,240 activity concentrations were in the range <0.01-14.2 Bq/kg (d.w.). Numerous sample cores exhibited sub-surface maxima which may be related to the historical discharges from the MCIC. Possible evidence indicating the deposition of earlier discharges at MCIC in deeper core layers was observed in the (238)Pu:(239,240)Pu activity ratio data: a Pu signal discernible from global fallout could be observed in numerous samples. Cs-137 and Pu-239,240 activity concentrations were correlated with the silt fraction (% by mass <63 microm) though no significant correlation was observed between (grain-size) normalised (137)Cs activity concentrations and distance downstream from the MCIC.

Radioactive contamination of the Balchug (Upper Yenisey) floodplain, Russia in relation to sedimentation processes and geomorphology.

The radioactive contamination of a riverine floodplain, heavily influenced by discharges from Krasnoyarsk-26, has been studied with respect to sedimentation processes and the geomorphology of the Upper Yenisey floodplain. The study was effected by implementation of a regime of in situ observations and measurements, sampling, and the interpretation of satellite images. The results of the study indicate that on the Balchug Bypass Floodplain, radionuclide contamination is primarily influenced by the thickness of the deposited sediments, and the area can be considered as two depositional environments. The Balchug floodplain area was contaminated due to sedimentation of radionuclide-contaminated alluvium, whose depositional regime significantly changed after the construction of a hydroelectric power station in 1967. Contamination levels are lower on the upstream part of the floodplain where sediment depth is less than 0.2-0.3 m, and this contamination started to accumulate in 1967, while the downstream part of the floodplain, exhibiting deeper deposits, displays higher levels of radionuclide contamination because radionuclides began to deposit here in 1958 when the Krasnoyarsk-26 Mining and Chemical Combine (KMCC) commenced operation. Radionuclide contamination of the floodplain is also related to the elevation of the floodplain, higher regions of the floodplain typically having lower contamination than low-lying areas, which tend to be frequently inundated with sediments being deposited during such inundations. Local relief, its orientation, and vegetation cover have also combined to form sediment traps with significantly higher radionuclide contamination. Lithological analysis combined with radiometric assay indicates a total 137Cs floodplain inventory of 33.7 GBq.

[Iodine concentration by the fungus Penicillium chrysogenum inhabiting soils of the nonchernozem zone]. / Kontsentrirovanie ioda gribom Penicillium chrysogenum, obitaiushchim v pochvakh Nechernozemnoi zony.

The iodine accumulation by strains of microscopic fungi Penecillium chrysogenum isolated from soddy-middle podzolic soils of Kirov region has been studied. It has been shown that fungi are able to accumulate from 5,0 X 10(-5) to 10,2% of iodine depending upon the medium iodine content and the degree of the organisms' tolerance to its high concentrations.