Characterization of Electrochemical Processes in Metal-Organic Batteries by X-ray Raman Spectroscopy.

X-ray Raman spectroscopy (XRS) is an emerging spectroscopic technique that utilizes inelastic scattering of hard X-rays to study X-ray absorption edges of low Z elements in bulk material. It was used to identify and quantify the amount of carbonyl bonds in a cathode sample, in order to track the redox reaction inside metal-organic batteries during the charge/discharge cycle. XRS was used to record the oxygen K-edge absorption spectra of organic polymer cathodes from different multivalent metal-organic batteries. The amount of carbonyl bond in each sample was determined by modeling the oxygen K-edge XRS spectra with the linear combination of two reference compounds that mimicked the fully charged and the fully discharged phases of the battery. To interpret experimental XRS spectra, theoretical calculations of oxygen K-edge absorption spectra based on density functional theory were performed. Overall, a good agreement between the amount of carbonyl bond present during different stages of battery cycle, calculated from linear combination of standards, and the amount obtained from electrochemical characterization based on measured capacity was achieved. The electrochemical mechanism in all studied batteries was confirmed to be a reduction of double carbonyl bond and the intermediate anion was identified with the help of theoretical calculations. X-ray Raman spectroscopy of the oxygen K-edge was shown to be a viable characterization technique for accurate tracking of the redox reaction inside metal-organic batteries.

Quinone Based Materials as Renewable High Energy Density Cathode Materials for Rechargeable Magnesium Batteries.

Organic cathode materials are promising cathode materials for multivalent batteries. Among organic cathodes, anthraquinone (AQ) has already been applied to various metal‒organic systems. In this work, we compare electrochemical performance and redox potential of AQ with 1,4-naphthoquinone (NQ) and 1,4-benzoquinone (BQ), both of which offer significantly higher theoretical energy density than AQ and are tested in two different Mg electrolytes. In Mg(TFSI)2-2MgCl2 electrolyte, NQ and BQ exhibit 0.2 and 0.5 V higher potential than AQ, respectively. Furthermore, an upshift of potential for 200 mV in MgCl2-AlCl3 electrolyte versus Mg(TFSI)2-2MgCl2 was confirmed for all used organic compounds. While lower molecular weights of NQ and BQ increase their specific capacity, they also affect the solubility in used electrolytes. Increased solubility lowers long-term capacity retention, confirming the need for the synthesis of NQ and BQ based polymers. Finally, we examine the electrochemical mechanism through ex situ attenuated total reflectance infrared spectroscopy (ATR-IR) and comparison of ex situ cathode spectra with spectra of individual electrode components. For the first time, magnesium anthracene-9,10-bis(olate), a discharged form of AQ moiety, is synthesized, which allows us to confirm the electrochemical mechanism of AQ cathode in Mg battery system.