ABSTRACT
The reaction of alkali-metal (Na, Cs) clusters with water clusters embedded in helium nanodroplets is studied using femtosecond photoionization as well as electron-impact ionization. Unlike Na clusters, Cs clusters are found to completely react with water in spite of the ultracold helium droplet environment. Mass spectra of the Csn+(H2O)m reaction products are interpreted in terms of stability with respect to fragmentation using high-level molecular structure calculations.
ABSTRACT
We consider the dynamics of Vicsek fractals of arbitrary connectivity, models for hyperbranched polymers. Their basic dynamical properties depend on their eigenvalue spectra, which can be determined iteratively. This paves the way for theoretical studies to very high precision for regular, finite, arbitrarily large hyperbranched structures.