Miscibility and Nanoparticle Diffusion in Ionic Nanocomposites.

We investigate the effect of various spherical nanoparticles in a polymer matrix on dispersion, chain dimensions and entanglements for ionic nanocomposites at dilute and high nanoparticle loading by means of molecular dynamics simulations. The nanoparticle dispersion can be achieved in oligomer matrices due to the presence of electrostatic interactions. We show that the overall configuration of ionic oligomer chains, as characterized by their radii of gyration, can be perturbed at dilute nanoparticle loading by the presence of charged nanoparticles. In addition, the nanoparticle's diffusivity is reduced due to the electrostatic interactions, in comparison to conventional nanocomposites where the electrostatic interaction is absent. The charged nanoparticles are found to move by a hopping mechanism.

Dataset of the use of tannin of néré (parkia-biglobosa) as a solution for the sustainability of the soil constructions in West Africa.

Soil is the main material of construction in African rural areas. Sustainability of construction with soil is a thorny problem to any builder. Finding ways to improve the durability of soil is not only essential but also salutary for the African rural community that mostly lives in soil-built houses that are very often short-lived. The present data assessed the resistance to simple compression and the resistance to bad weather by simulating rainfall alternations through a test of cycles of alternate watering and drying of blocks built from four types of different soils without binder, along with blocks built from the same soils.