Nanocomposites Based on Thermoplastic Acrylic Resin with the Addition of Chemically Modified Multi-Walled Carbon Nanotubes.

The main goal of this work was an improvement in the mechanical and electrical properties of acrylic resin-based nanocomposites filled with chemically modified carbon nanotubes. For this purpose, the surface functionalization of multi-walled carbon nanotubes (MWCNTs) was carried out by means of aryl groups grafting via the diazotization reaction with selected aniline derivatives, and then nanocomposites based on ELIUM® resin were fabricated. FT-IR analysis confirmed the effectiveness of the carried-out chemical surface modification of MWCNTs as new bands on FT-IR spectra appeared in the measurements. TEM observations showed that carbon nanotube fragmentation did not occur during the modifications. According to the results from Raman spectroscopy, the least defective carbon nanotube structure was obtained for aniline modification. Transmission light microscopy analysis showed that the neat MWCNTs agglomerate strongly, while the proposed modifications improved their dispersion significantly. Viscosity tests confirmed, that as the nanofiller concentration increases, the viscosity of the mixture increases. The mixture with the highest dispersion of nanoparticles exhibited the most viscous behaviour. Finally, an enhancement in impact resistance and electrical conductivity was obtained for nanocomposites containing modified MWCNTs.

Structural Health Monitoring of Chemical Storage Tanks with Application of PZT Sensors.

Chemical pressure storage tanks are containers designed to store fluids at high pressures, i.e., their internal pressure is higher than the atmospheric pressure. They can come in various shapes and sizes, and may be fabricated from a variety of materials. As aggressive chemical agents stored under elevated pressures can cause significant damage to both people and the environment, it is essential to develop systems for the early damage detection and the monitoring of structural integrity of such vessels. The development of early damage detection and condition monitoring systems could also help to reduce the maintenance costs associated with periodic inspections of the structure and unforeseen operational breaks due to unmonitored damage development. It could also reduce the related environmental burden. In this paper, we consider a hybrid material composed of glass-fiber-reinforced polymers (GFRPs) and a polyethylene (PE) layer that is suitable for pressurized chemical storage tank manufacturing. GFRPs are used for the outer layer of the tank structure and provides the dominant part of the construction stiffness, while the PE layer is used for protection against the stored chemical medium. The considered damage scenarios include simulated cracks and an erosion of the inner PE layer, as these can be early signs of structural damage leading to the leakage of hazardous liquids, which could compromise safety and, possibly, harm the environment. For damage detection, PZT sensors were selected due to their widely recognized applicability for the purpose of structural health monitoring. For sensor installation, it was assumed that only the outer GFRP layer was available as otherwise sensors could be affected by the stored chemical agent. The main focus of this paper is to verify whether elastic waves excited by PZT sensors, which are installed on the outer GFRP layer, can penetrate the GFRP and PE interface and can be used to detect damage occurring in the inner PE layer. The efficiency of different signal characteristics used for structure evaluation is compared for various frequencies and durations of the excitation signal as well as feasibility of PZT sensor application for passive acquisition of acoustic emission signals is verified.

Polyamide 11 Composites Reinforced with Diatomite Biofiller-Mechanical, Rheological and Crystallization Properties.

Amorphic diatomaceous earth is derived from natural sources, and polyamide 11 (PA11) is produced from materials of natural origin. Both of these materials show a low harmfulness to the environment and a reduced carbon footprint. This is why the combination of these two constituents is beneficial not only to improve the physicochemical and mechanical properties of polyamide 11 but also to produce a biocomposite. For the purpose of this paper, the test biocomposite was produced by combining polyamide 11, as well as basic and pre-fractionated diatomaceous earth, which had been subjected to silanization. The produced composites were used to carry out rheological (melt flow rate-MFR), mechanical (tensile strength, bending strength, impact strength), crystallographic (X-ray Diffraction-XRD), thermal and thermo-mechanical (differential scanning calorimetry-DSC, dynamic mechanical thermal analysis-DMTA) analyses, as well as a study of hydrophobic-hydrophilic properties of the material surface (wetting angle) and imaging of the surface of the composites and the fractured specimens. The tests showed that the additive 3-aminopropyltriethoxysilane (APTES) acted as an agent that improved the elasticity of composites and the melt flow rate. In addition, the produced composites showed a hydrophilic surface profile compared to pure polylactide and polyamide 11.

Beeswax as a natural alternative to synthetic waxes for fabrication of PLA/diatomaceous earth composites.

In this study, injection moulding was applied to produce biocomposites consisting of polylactide (PLA) and amorphous diatomaceous earth used as a filler at different concentrations. Natural wax and synthetic wax were added to improve processing properties, comparing the resulting biocomposites. The use of natural beeswax makes the composite environmentally friendly. The prepared composites contained 2.5, 5, 10 and 15% w/w filler. The test samples have been injection moulded. Rheological, mechanical, surface and other properties were assessed for the fabricated composites. The testing has shown that the use of wax additives has a significant influence on the mechanical properties (tensile strength, flexural strength, impact strength) and the hydrophilicity/hydrophobicity of composite surfaces. The addition of natural wax, especially at lower concentration, has a positive effect on the rheological properties of composites (melt flow rate, MFR), flexural modulus and impact strength. Different composite parameters are modified by different wax types so both natural and synthetic waxes, can be used interchangeably, depending on the required final material characteristics.

Effect of Wax Additives and Silanization of Diatom Surfaces on Thermomechanical Properties of Polylactide Composites.

In the present study, tests were conducted on high-filled composite samples on a polylactide matrix, modified with diatomaceous earth, three types of silanes, and natural and synthetic wax. The obtained samples were characterized in terms of the effect of modifications on mechanical properties (tensile strength, flexural strength, and impact resistance) or processing properties, e.g., melt flow rate (MFR). The study showed that the modification had a favorable effect on the processing properties of the composites, associated with up to an eight-fold increase in flow rate index compared with the reference sample, especially for samples treated with methyltrimethoxysilane (MTMOS), and up to a ten-fold increase under low shear-rate flow conditions. The effect of the addition of waxes of different origins (synthetic and natural) was also determined, and it was shown that beeswax tended to reduce the flow rate of the composites regardless of the silane used. The addition of synthetic wax to composites increased the tendency to agglomerate diatomaceous earth, while natural wax had a positive effect on filler dispersion.

Influence of Fabrication Method and Surface Modification of Alumina Ceramic on the Microstructure and Mechanical Properties of Ceramic-Elastomer Interpenetrating Phase Composites (IPCs).

The paper presents experimental results of the work conducted to improve the adhesion between alumina ceramics and urea-urethane elastomer in the interpenetrating phase composites (IPCs), in which these two phases are interpenetrating three-dimensionally and topologically throughout the microstructure. Measurements of the contact angle, surface roughness, and shear tests were used to evaluate the effectivity and select the quantity of a silane coupling agent and the ceramic fabrication method. The tests were conducted using samples of dense alumina ceramic obtained by three- or four-step methods. In the four-step process, hot isostatic pressing (HIP) was applied additionally. As a result of the coupling agent coat and HIP application, the ceramic substrate wettability by the elastomer was improved. The water contact angle was reduced from 80 to 60%. In the next step, porous ceramic preforms were fabricated using HIP sintering and a solution of silane coupling agent treated their surface. The composites were produced using vacuum-pressure infiltration of porous alumina ceramics by urea-urethane elastomer in liquid form. The influence of the coupling agent application on the microstructure and mechanical properties of the composites was estimated. The microstructure of the composites was identified using SEM microscopy and X-ray tomography. As a result of using the coupling agent, residual porosity decreased from 7 to 2%, and compressive strength, as well as stress at a plateau, increased by more than 20%, from 25 to 33 MPa and from 15 to 24 MPa, respectively, for the composites fabricated by infiltration ceramic preforms with 40% of porosity.

Biocomposites Based on Polyamide 11/Diatoms with Different Sized Frustules.

Amorphous diatomite was used as a filler for a thermoplastic polymer of polyamide 11 obtained from natural sources. The diatomite particles of different sizes were previously fractionated by sedimentation to obtain powders with varying particle size distribution, including powders with or without frustule particles, crushed, uncrushed or agglomerated. Biocomposites containing 2.5, 5, 10 and 20% filler were tested for their mechanical properties, including tensile strength, flexural strength and impact strength. In addition, a particle size analysis (by Dynamic Light Scattering, DLS) was performed and the dispersion of the filler in the polymer matrix (Scanning Electron Microscopy, SEM), thermal parameters (Differential Scanning Calorimetry, DSC, and Dynamic Mechanical Analysis, DMA) were determined. Testing showed that biocomposites modified with diatomaceous earth have a higher mechanical strength than the reference system, especially with larger amounts of the filler (10 and 20%), e.g., the tensile strength of pure PA11 is about 46 MPa, while 20OB and 20OF 47.5 and 47 MPa, respectively, while an increase in max. flexural strength and flexural modulus is also observed compared to pure PA11 by a maximum of 63 and 54%, respectively Diatomaceous earth can be obtained in various ways-it is commercially available or it is possible to breed diatoms in laboratory conditions, while the use of commercially available diatomite, which contains diatoms of different sizes, eliminates the possibility of controlling mechanical parameters by filling biocomposites with a filler with the desired particle size distribution, and diatom breeding is not possible on an industrial scale. Our proposed biocomposite based on fractionated diatomaceous earth using a sedimentation process addresses the current need to produce biocomposite materials from natural sources, and moreover, the nature of the process, due to its simplicity, can be successfully used on an industrial scale.

Influence of Diatomaceous Earth Particle Size on Mechanical Properties of PLA/Diatomaceous Earth Composites.

The fractionation of diatomaceous earth (DE) using sedimentation made it possible to obtain separate unbroken diatom fractions from broken or agglomerated bodies with a range of particle sizes. The produced filler was used to prepare polylactide (PLA)/diatomaceous earth biocomposite samples containing different particle sizes, which were subjected to mechanical testing (tensile strength, flexural strength, impact strength), colloidal testing (contact angle, color change test, SEM/EDS), and thermal testing (TGA, DSC, DMA). Modification of the PLA containing the smallest particle size with diatomaceous earth (Fraction 5) resulted in a higher impact strength compared to both the pure PLA and the PLA/DE composite that contained base diatomaceous earth. Furthermore, the melt flow rate was improved by more than 80 and 60% for the composite modified with fractionated diatomaceous earth (Fraction 4) compared to pure PLA and base diatomaceous earth, respectively. The elasticity of the composite was also improved from 3.3 GPa for pure polylactide to 4.4 GPa for the system containing the smallest diatomaceous earth particles (Fraction 5).

The Influence of the Microstructure of Ceramic-Elastomer Composites on Their Energy Absorption Capability.

The paper presents the experimental results of static and dynamic compressive tests conducted on ceramic-elastomer composites. The alumina ceramic preforms were fabricated by the four-step method: ceramic mixture preparation, consolidation under pressure, presintering, and sintering under pressure, respectively. To obtain ceramic preforms with a similar volume fraction of open pores, but with different pore sizes, alumina powder with different particle size and a ceramic binder were used, as well as pore-forming agents that were evenly distributed throughout the volume of the molding mass. The composites were obtained using vacuum pressure infiltration of porous alumina ceramic by urea-urethane elastomer in liquid form. As a result, the obtained composites were characterized by two phases that interpenetrated three-dimensionally and topologically throughout the microstructure. The microstructure of the ceramic preforms was revealed by X-ray tomography, which indicated that the alumina preforms had similar porosity of approximately 40% vol. but different pore diameter in the range of 6 to 34 µm. After composite fabrication, image analysis was carried out. Due to the microstructure of the ceramic preforms, the composites differed in the specific surface fraction of the interphase boundaries (Sv). The highest value of the Sv parameter was achieved for composite fabricated by infiltration method of using ceramic preform with the smallest pore size. Static and dynamic tests were carried out using different strain rate: 1.4·10-3, 7·10-2, 1.4·10-1, and 3·103 s-1. Compressive strength, stress at plateau zone, and absorbed energy were determined. It was found that the ceramic-elastomer composites' ability to absorb energy depended on the specific surface fraction of the interphase boundaries and achieved a value between 15.3 MJ/m3 in static test and 51.1 MJ/m3 for dynamic strain rate.

Effect of Processing Temperature and the Content of Carbon Nanotubes on the Properties of Nanocomposites Based on Polyphenylene Sulfide.

The study aimed to investigate the effect of processing temperature and the content of multi-wall carbon nanotubes (MWCNTs) on the rheological, thermal, and electrical properties of polyphenylene sulfide (PPS)/MWCNT nanocomposites. It was observed that the increase in MWCNT content influenced the increase of the complex viscosity, storage modulus, and loss modulus. The microscopic observations showed that with an increase in the amount of MWCNTs, the areal ratio of their agglomerates decreases. Thermogravimetric analysis showed no effect of processing temperature and MWCNT content on thermal stability; however, an increase in stability was observed as compared to neat PPS. The differential scanning calorimetry was used to assess the influence of MWCNT addition on the crystallization phenomenon of PPS. The calorimetry showed that with increasing MWCNT content, the degree of crystallinity and crystallization temperature rises. Thermal diffusivity tests proved that with an increase in the processing temperature and the content of MWCNTs, the diffusivity also increases and declines at higher testing temperatures. The resistivity measurements showed that the conductivity of the PPS/MWCNT nanocomposite increases with the increase in MWCNT content. The processing temperature did not affect resistivity.

Push-Out Method for Micro Measurements of Interfacial Strength in Aluminium Alloy Matrix Composites.

The main goal of this work was the evaluation of the interfacial strength of the carbon fibres/aluminium matrix interface dependently on the utilised composite fabrication method, namely high pressure die casting and gas pressure infiltration. In addition, the influence of a Ni-P coating on the C-fibres was investigated. The proposed measurements of the interfacial strength were carried out by means of the "push-out" method. The interfacial strength of the samples fabricated using the high-pressure infiltration method average between 19.03 MPa and 45.34 MPa.