ABSTRACT
This paper presents the results of an analysis of the changes in the stiffness of asphalt binders modified with a bio-flux additive and subjected to the processes of foaming and short-term ageing. The purpose of the analyses was to determine changes in the rheological properties of asphalt binder as a result of technological processes characteristic of hot and warm mix asphalt technology. Three asphalt binders with similar penetration but varying degrees of polymer modification were tested: 50/70, 45/80-55 polymer-modified bitumen, and 45/80-80 highly modified bitumen. Tests were carried out on four groups of binders: original binders, foamed binders after 14 days of storage, non-foamed binders after Rolling Thin Film Oven Test (RTFOT) ageing, and foamed binders after 14 days of storage subjected to RTFOT ageing. The master curves of the complex shear modulus G* were analysed, and three indexes of binder stiffening were determined, characterising the investigated effects. The tests showed that some of the stiffening indices significantly depended on the degree of polymer modification and the content of the bio-flux additive. Moreover, it was found that the foaming process in the case of paving-grade bitumen and polymer-modified bitumen did not contribute to the additional stiffening of the binders.
ABSTRACT
The study investigated the effects of laboratory ageing on the fluxed and water-foamed asphalt binders in scope of Fourier transform infrared spectroscopic measurements of ageing indicators and changes in their chemical composition. The investigated binders included two paving grades, two polymer modified asphalt binders, and a highly modified asphalt binder. The bio-flux additive was produced from rapeseed methyl esters in an oxidation reaction in the presence of a metal catalyst and organic peroxide. The use of the bio-origin additive, in particular oil derivatives, was aimed at softening and better foaming of asphalt binders. This modification is possible due to the good mixability of vegetable oils with an asphalt binder, which gives a homogeneous product with reduced stiffness. The study involved the rolling thin film oven, short-term, and the pressure ageing vessel, long term, and ageing to induce oxidation on the evaluated asphalt binders. The addition of the bio-flux additive has significantly decreased the measured content of ketone compounds related to oxidation in both non-aged and aged asphalt binders, although this effect after ageing were far smaller in magnitude. Additionally, both ageing processes decreased significantly the absorbances in the ester spectral bands specific to the bio-flux additive. All mentioned effects were similar in magnitude in all tested asphalt binders.
ABSTRACT
The present paper investigates the effects of simultaneous mechanical foaming using water and fluxing with a bio-derived agent on the properties of three distinct asphalt binders: 50/70 paving-grade bitumen, 45/80-55 polymer-modified bitumen, and 45/80-80 highly modified asphalt binder. The testing involved classical tests for assessing binder consistency (penetration at 25 °C, ring and ball softening point, Fraass breaking point, and dynamic viscosity) as well as performance tests (high and low Superpave critical temperatures and multiple stress creep recovery). The tests included assessment directly after asphalt binder foaming and were repeated after a 14-day period. It was shown that bitumen foaming had only short-term effects on the asphalt binders, which did not persist in the repeated tests after 14 days. The fluxing agent that was utilized caused significant changes in the consistency of all asphalt binders. The changes in the performance characteristics of the 50/70 and 45/80-55 binders were severe and amounted to a significant decrease in high-temperature performance of these binders. On the other hand, an improvement in all performance characteristics in the case of the 45/80-80 asphalt binder was observed as a result of the applied processes, particularly when measured 14 days after foaming. This study shows that the simultaneous use of foaming and the fluxing additive decreased the dynamic viscosity of the 45/80-80 binder, while improving its properties relating the pavement performance.
ABSTRACT
This paper presents the results of a research study and analysis conducted to determine the degree of anisotropy of asphalt concrete in terms of its initial elastic properties. The analysis of asphalt concrete was focused on determining the effective constrained stiffness modulus in three mutually perpendicular directions based on the finite element method. The internal structure of the asphalt concrete was divided into the mortar phase and the mineral aggregate phase. Static creep tests using the Bending Beam Rheometer were conducted for the mortar phase to fit the rheological model. The aggregate arrangement and orientation were analysed using an image analytical technique for the mineral phase. The Finite Element Method (FEM) meshes were prepared based on grey images with an assumption of plane strain in 2D formulation. Using the FEM model, the tension/compression tests using selected characteristic directions were conducted, and the effective constrained stiffness moduli were estimated. This study showed a dominant horizontal direction for all coarse aggregates resulting from the normal force of the road roller and paving machines during laying and compaction on a road site. Depending on the values of the mortar's mechanical parameters and the load direction, the effective stiffness modulus might differ by ±20%. Based on the FEM analysis, this result was proven and commented on through an effective directional modulus evaluation and a presentation of internal stress distribution. Depending on the shape and orientation of the aggregates, it was possible to observe local "stress bridging" (transferring stresses from aggregate to aggregate when contacting). Moreover, the rheological properties of the mortar were considered by assuming two limiting situations (instantaneous and relaxed moduli), determining the bands of all possible solutions. In the performed FEM analysis, the influence of the Poisson ratio was also considered. The analysed asphalt concrete tends to be isotropic when the Poisson's mortar ratio is close to the value of 0.5, which agrees with the physical expectations. The obtained results are limited to particular asphalt concrete and should not be extrapolated to other asphalt mixture types without prior analysis.
ABSTRACT
This article discusses the phenomenon of fresh and RAP binders miscibility and presents test results of bitumen film properties from specially prepared asphalt mixtures. The miscibility of a fresh binder and a RAP binder still has not been fully recognised. The aim of this study was to determine the homogeneity level of the bitumen film based on viscoelastic assessment. In addition, an attempt was made to assess the impact of fresh binder on the binders blending degree. The study included assessment of homogeneity of bitumen film comprising various types of bituminous binders. The assessment was conducted on the basis of tests in the dynamic shear rheometer regarding rheological properties of the binders recovered from specific layers of the bitumen film using a staged extraction method. A complex shear modulus as a function of temperature, an elastic recovery R and a non-recoverable creep compliance modulus JNR from MSCR test were determined. The conducted statistical analyses confirmed the significant impact of the type of fresh binder on the blending degree. Regressive dependencies have been set between the differences of the complex shear modulus of the binders subject to mixing and differences of the complex shear modulus of binders from the internal and external layer of the bitumen film comprised of those binders. It was found that there is no full blending of fresh hard bitumen-simulated binder from RAP, which results in non-homogeneity of the bitumen film.
ABSTRACT
The benefits of the use of cold recycling mixtures (CRMs) in pavement rehabilitation are associated with both the reduction of natural resource consumption by replacing them with recycled materials and the reduction of energy consumption during their production and paving. The evolution of the stiffness of CRMs in road construction and the fatigue life of pavements with CRM base layers are still being investigated. In this paper, CRMs with 1% cement content, called bitumen-stabilized materials with bitumen emulsion (BSM-Es), were examined. Mixtures that were differentiated in terms of Reclaimed Asphalt Pavement (RAP) content, as well as the amount and type of bitumen emulsions, were subjected to indirect tensile stiffness modulus (ITSM) tests at 5 °C, 13 °C, and 20 °C. The thermal sensitivities of the BSM-E mixtures were analyzed. BSM-E mixture stiffness modulus levels at various temperatures were determined using a statistical approach. On the basis of the results obtained, a discussion on the mechanistic-empirical design of flexible pavements with BSM-E base layers is presented. The potential benefits of using BSM-E materials in road construction in certain aspects of pavement life are indicated.
ABSTRACT
In the course of manufacturing, transport and installation, road bitumens and asphalt mixtures can be exposed to the impact of elevated process temperatures exceeding 240 °C. This mainly applies to the mixtures used for road pavements and bridge deck insulation during adverse weather conditions. The heating process should not change the basic and rheological properties of binders and the asphalt mixtures that to a degree cause the degradation of asphalt pavement durability. The work involved analyzing the properties of non-modified bitumens and SBS polymer modified bitumens, heated at temperatures of 200 °C, 250 °C and 300 °C for 1 h. Next, the asphalt mixtures were heated in the same temperatures. Based on the developed Overheating Degradation Index (ODI) it was demonstrated that polymer-modified bitumens were characterized by higher overheating sensitivity A(ODI) than non-modified bitumens, which was confirmed by mixture test results. Overheating limit temperatures T(ODI) were determined, which in the case of polymer-modified bitumens are up to 20 °C lower than for non-modified bitumens. When the temperature increases above T(ODI), loss of viscoelastic properties occurs in the material which causes, among other effects, a loss of resistance to fatigue cracking.
ABSTRACT
Bitumen is a commonly used material for road construction. According to environmental regulations, vegetable-based materials are applied for binder modification. Fluxed road bitumen containing a bio-flux oxidation product increases the consistency over time. The efficiency of crosslinking depends on the number of double bonds and their position in the aliphatic chain of fatty acid. The main goal of this paper was to examine the structural changes taking place during hardening bitumen with bio-flux additives. Two types of road bitumens fluxed with two different oxidized methyl esters of rapeseed oil were used in this study. Various chemical and rheological tests were applied for the fluxed-bitumen at different stages of oxygen exposure. The oxidation of rapeseed oil methyl ester reduced the iodine amount by about 10%-30%. Hardening of the fluxed bitumen generally results in an increase of the resins content and a reduction of the aromatics and asphaltenes. In the temperature range of 0 °C to 40 °C, bio-flux results with a much higher increase in the phase angle than in temperatures above 40 °C in the bitumen binder. The increase in the proportion of the viscous component in the low and medium binder temperature is favorable due to the potential improvement of the fatigue resistance of the asphalt mixture with such binders.
