Biochar and surfactant synergistically enhanced PFAS destruction in UV/sulfite system at neutral pH.

The UV/sulfite-based advanced reduction process (ARP) emerges as an effective strategy to combat per- and polyfluoroalkyl substances (PFAS) pollution in water. Yet, the UV/sulfite-ARP typically operates at highly alkaline conditions (e.g., pH > 9 or even higher) since the generated reductive radicals for PFAS degradation can be quickly sequestered by protons (H+). To overcome the associated challenges, we prototyped a biochar-surfactant-system (BSS) to synergistically enhance PFAS sorption and degradation by UV/sulfite-ARP. The degradation and defluorination efficiencies of perfluorooctanoic acid (PFOA) depended on solution pH, and concentrations of surfactant (cetyltrimethylammonium bromide; CTAB), sulfite, and biochar. At high pH (8-10), adding biochar and BSS showed no or even small inhibitory effect on PFOA degradation, since the degradation efficiencies were already high enough that cannot be differentiated. However, at acidic and neutral pH (6-7), an evident enhancement of PFOA degradation and defluorination efficiencies occurred. This is due to the synergies between biochar and CTAB that create favorable microenvironments for enhanced PFOA sorption and deeper destruction by prolonging the longevity of reductive radicals (e.g., SO3•-), which is less affected by ambient pH conditions. The performance of UV/sulfite/BSS was further optimized and used for the degradation of four PFAS. At the optimal experimental condition, the UV/sulfite/BSS system can completely degrade PFOA with >30% defluorination efficiency for up to five continuous cycles (n = 5). Overall, our BSS provides a cost-effective and sustainable technique to effectively degrade PFAS in water under environmentally relevant pH conditions. The BSS-enabled ARP technique can be easily tied into PFAS treatment train technology (e.g., advanced oxidation process) for more efficient and deeper defluorination of various PFAS in water.

Mechanistic understanding of perfluorooctane sulfonate (PFOS) sorption by biochars.

Biochar has recently emerged as a cost-effective solution to combat per- and polyfluoroalkyl substances (PFAS) pollution in water, but mechanistic understanding of which physicochemical properties of biochars dictate PFAS sorptive removal from water remains elusive. Herein, 15 biochars were pyrolyzed from five feedstocks (corn, Douglas fir, eucalyptus, poplar, and switchgrass) at three pyrolysis temperatures (500, 700, and 900 °C) to investigate their removal efficiencies and mechanisms of perfluorooctane sulfonate (PFOS) from water. A commercial biochar was also included for comparison. Biochar physiochemical properties, including elemental composition, pH, specific surface area (SSA), pore structure, hydrophobicity, surface charge, surface functional groups, and crystalline structure were systematically characterized. Batch sorption data showed that the Douglas fir 900 biochar (Douglas fir and 900 are the feedstock type and pyrolysis temperature, respectively; this naming rule applies to other biochars), poplar 900 biochar, and commercial biochar can remove over 95% of PFOS from water. Structural equation model (SEM) was used to elucidate which biochar properties affect PFOS sorption. Interestingly, biochar pore diameter was identified as the most critical factor controlling PFOS removal, but pore diameter/pore volume ratio, SSA, pyrolysis temperature, hydrophobicity, and elemental composition all played variable roles. Hypothetically, biochars with small pore diameters and large pore volumes had a narrow yet deep pore structure that traps PFOS molecules inside once already sorbed, resulting in an enhanced PFOS sorption. Biochars with small pore diameter, low nitrogen content, and high pyrolysis temperature were also favorable for enhanced PFOS sorption. Our findings advance the knowledge of using biochars with optimized properties to remove PFOS and possibly other similar PFAS compounds from water.

Critical review of microplastics removal from the environment.

Globally, microplastics pollution has become a serious environmental threat due to their multitude sources, widespread occurrence, persistence, and adverse effects to ecosystem and the human health. Addressing this multifaceted threat requires innovative technologies that can efficiently remove microplastics from the environment. In this review, we first overviewed the source, occurrence, and potential adverse impacts of microplastics to human health. We then identified promising technologies for microplastics removal, including physical, chemical, and biological approaches. A detailed analysis of the advantages and limitations of different techniques was provided. We concluded this review with the current challenges and future research priorities, which will guide us through the path addressing microplastics contamination.