Assessment of hair metal levels in aluminium plant workers using scalp hair ICP-DRC-MS analysis.

The objective of the present study was to assess the level of aluminium and toxic metals in hair of workers occupationally exposed to aluminium. 124 employees of the aluminium plant working in the hydrometallurgical (n = 43) and sintering units (n = 41), as well as 40 occupationally nonexposed controls were examined. Hair aluminium (Al), arsenic (As), beryllium (Be), cadmium (Cd), mercury (Hg), nickel (Ni), lead (Pb), and tin (Sn) content was assessed using inductively-coupled plasma mass spectrometry. The obtained data demonstrate that aluminium plant workers had significantly higher levels of hair Al (28.8 (15.4-58.6) vs 7.8 (4.3-14.2) µg/g, p < 0.001), Cd (0.053 (0.032 - 0.095) vs 0.025 (0.014 - 0.043) µg/g, p < 0.001) and Pb (0.672 (0.299-1.310) vs 0.322 (0.170 - 0.609) µg/g, p = 0.012) than the controls, respectively. Further analysis demonstrated that persons involved in different technological processes were characterized by distinct hair metal profiles. Hair Al, Be, Cd, Ni, Pb, and Sn levels in men working in the sintering unit of the aluminium plant exceeded the respective control values. In turn, workers of the hydrometallurgical unit were characterized by more than 2-fold higher levels of Al and Cd in hair as compared to the controls. The results of the present study demonstrate that workers of the aluminium plant are characterized by increased risk of Al as well as As, Cd, Pb, and Sn exposure.

The level of toxic and essential trace elements in hair of petrochemical workers involved in different technological processes.

The objective of the investigation is comparative analysis of hair trace element content in workers of different departments of petrochemical plant. A total of 75 men working in office (engineers), and departments 1 (D1), 3 (D3), and 4 (D4) of the petrochemical plant, as well as occupationally non-exposed persons, were examined. Hair trace element levels were analyzed using inductively coupled plasma mass spectrometry. The office workers were characterized by the highest hair As, Hg, Sn, I, and Si content as compared to the workers of other departments, whereas the level of those elements did not differ significantly from the control values. It is notable that hair Be levels in all employees of petrochemical plant were significantly lower, whereas Se content was significantly higher than that in unexposed controls. Hair toxic trace element content in workers directly involved in industrial processes did not differ significantly or was lower than that in the control group. At the same time, the highest levels of essential trace elements (Cr, Fe, and I) were observed in employees working in primary oil refining (D1). Hair levels of Co, I, and Li were maximal in persons of sulfur and bitumen-producing division (D4). The lowest levels of both essential and toxic trace elements in hair were detected in employees involved in production of liquefied gas, kerosene, and diesel fuel (D3). The obtained data demonstrate that involvement in different technological processes in petrochemical complex differentially affect hair trace element content in workers.