Stream flow composition and sediment yield comparison between partially urbanized and undisturbed coastal watersheds-case study: St. John, US Virgin Islands.

In steep dry-tropical islands, rural and urban development can lead to accelerated soil erosion and the delivery of land-based materials into marine ecosystems. The objective of this paper was to compare stream water composition, clay minerology, and sediment yield between a partially urbanized (Coral Bay) and an undisturbed (Lameshur) coastal watersheds in St. John, US Virgin Islands (USVI). The saturation index of streamflow water samples was calculated using "The Geochemist's Workbench" software and most likely precipitated minerals from observed storm events was then compared with X-ray diffraction on soil clay mineralogy. The spatial distribution on both annual mean (2010) erosion rates and storm event-wise (Hurricane Otto) sediment yield among the two study watersheds were modeled using the revised and modified universal soil loss equations (RUSLE; MUSLE), respectively. Cations concentration in stream flow water samples and sediment yield were higher for the partially urbanized (Coral Bay) compared to the undisturbed (Lameshur) watershed. Our findings suggest that rural/urban development may increase stream water cations concentration and inputs of sediment to downstream ecosystems. Future studies evaluating the effect of management practices such as pavement or other stabilization of dirt roads and their impact on stream water quality and quantity and sediment yield are crucial for the proper sediment management in the study watersheds and potentially in other rural-urbanizing tropical watersheds.

Modelling Runoff and Sediment Loads in a Developing Coastal Watershed of the US-Mexico Border.

Urbanization can increase sheet, rill, gully, and channel erosion. We quantified the sediment budget of the Los Laureles Canyon watershed (LLCW), which is a mixed rural-urbanizing catchment in Northwestern Mexico, using the AnnAGNPS model and field measurements of channel geometry. The model was calibrated with five years of observed runoff and sediment loads and used to evaluate sediment reduction under a mitigation scenario involving paving roads in hotspots of erosion. Calibrated runoff and sediment load had a mean-percent-bias of 28.4 and - 8.1, and root-mean-square errors of 85% and 41% of the mean, respectively. Suspended sediment concentration (SSC) collected at different locations during one storm-event correlated with modeled SSC at those locations, which suggests that the model represented spatial variation in sediment production. Simulated gully erosion represents 16%-37% of hillslope sediment production, and 50% of the hillslope sediment load is produced by only 23% of the watershed area. The model identifies priority locations for sediment control measures, and can be used to identify tradeoffs between sediment control and runoff production. Paving roads in priority areas would reduce total sediment yield by 30%, but may increase peak discharge moderately (1.6%-21%) at the outlet.

Precipitation and topography modulate vegetation greenness in the mountains of Baja California, México.

Vegetation greenness (normalized difference vegetation index, NDVI) showed significant temporal and spatial correlations with precipitation and topography-derived features within the context of slope aspect (South- (SFS) and North-facing slopes (NFS) and an intermountain valley (IMV)) in a semi-arid Mediterranean-climate watershed in northwestern Baja California, México. Rank correlation with annual precipitation (1986-2016) showed a strong positive relationship with wet season NDVI at SFS (Rs = 0.82), IMV (Rs = 0.79), and NFS (Rs = 0.65) but moderate relation and only on hillslopes in the dry season (SFS, Rs = 0.47; NFS, Rs = 0.39). Thus, the vegetation on the more xeric SFS sites was more responsive to intra-annual and inter-annual precipitation than on either IMV or NFS. The correlation of NDVI with six topography-derived environmental attributes (elevation, slope gradient, curvature, drainage density, topographic wetness index, solar radiation) was weak to moderate, varied in degree and significance between years with exceptionally high or low NDVI, and often differed in sign between SFS, NFS, and IMV. Results showed that precipitation controlled vegetation greenness, under the three aspect conditions, more closely than did the other topography-derived features, and the sparse deciduous vegetation of SFS showed stronger associations with precipitation than IMV or NFS. The measurement of these relationships should be continued and complemented by other studies to improve the overall model, because they are important to modeling ecohydrology and productivity, and may be of use for projecting and hindcasting vegetation dynamics.

Measuring ephemeral gully erosion rates and topographical thresholds in an urban watershed using unmanned aerial systems and structure from motion photogrammetric techniques.

Both rural and urban development can lead to accelerated gully erosion. Quantifying gully erosion is challenging in environments where gullies are rapidly repaired, and in urban areas where microtopographic complexity complicates the delineation of contributing areas. This study used unmanned aerial vehicles (UAVs) and Structure-from-Motion (SfM) photogrammetric techniques to quantify gully erosion in the Los Laureles Canyon watershed, a rapidly urbanizing watershed in Tijuana, Mexico. Following a storm event, the gully network extent was mapped using an orthomosaic (0.038 m pixel size); the local slope and watershed area contributing to each gully head were mapped with a Digital Surface Model (0.3 m pixel size). Gullies formed almost exclusively on unpaved roads which had erodible soils and concentrated flow. Management practices (e.g. road maintenance that fill gullies after large storms) contributed to total sediment production at the watershed scale. Sediment production from gully erosion was higher and threshold values of slope and drainage area for gully incision were lower than ephemeral gullies reported for agricultural settings. This indicates high vulnerability of unpaved roads to gully erosion which is consistent with high soil erodibility and low critical shear stress measured in the laboratory with a mini jet-erosion-test device. Future studies that evaluate effects of different soil types on gully erosion rates for unpaved roads, as well as those that model effects of management practices such as road paving and their impact on runoff, soil erosion, and sediment loads are needed to advance sediment management and planning in urban watersheds.

Modelling Ephemeral Gully Erosion from Unpaved Urban Roads: Equifinality and Implications for Scenario Analysis.

Modelling gully erosion in urban areas is challenging due to difficulties with equifinality and parameter identification, which complicates quantification of management impacts on runoff and sediment production. We calibrated a model (AnnAGNPS) of an ephemeral gully network that formed on unpaved roads following a storm event in an urban watershed (0.2 km2) in Tijuana, Mexico. Latin hypercube sampling was used to create 500 parameter ensembles. Modelled sediment load was most sensitive to the Soil Conservation Service (SCS) curve number, tillage depth (Td), and critical shear stress (τc). Twenty-one parameter ensembles gave acceptable error (behavioural models), though changes in parameters governing runoff generation (SCS curve number, Manning's n) were compensated by changes in parameters describing soil properties (TD, τc, resulting in uncertainty in the optimal parameter values. The most suitable parameter combinations or "behavioural models" were used to evaluate uncertainty under management scenarios. Paving the roads increased runoff by 146-227%, increased peak discharge by 178-575%, and decreased sediment load by 90-94% depending on the ensemble. The method can be used in other watersheds to simulate runoff and gully erosion, to quantify the uncertainty of model-estimated impacts of management activities on runoff and erosion, and to suggest critical field measurements to reduce uncertainties in complex urban environments.

Inter-laboratory test for oxygen and hydrogen stable isotope analyses of geothermal fluids: Assessment of reservoir fluid compositions.

RATIONALE: Knowledge of the accuracy and precision for oxygen (δ18 O values) and hydrogen (δ2 H values) stable isotope analyses of geothermal fluid samples is important to understand geothermal reservoir processes, such as partial boiling-condensation and encroachment of cold and reinjected waters. The challenging aspects of the analytical techniques for this specific matrix include memory effects and higher scatter of delta values with increasing total dissolved solids (TDS) concentrations, deterioration of Pt-catalysts by dissolved/gaseous H2 S for hydrogen isotope equilibration measurements and isotope salt effects that offset isotope ratios determined by gas equilibration techniques. METHODS: An inter-laboratory comparison exercise for the determination of the δ18 O and δ2 H values of nine geothermal fluid samples was conducted among eleven laboratories from eight countries (CeMIEGeo2017). The delta values were measured by dual inlet isotope ratio mass spectrometry (DI-IRMS), continuous flow IRMS (CF-IRMS) and/or laser absorption spectroscopy (LAS). Moreover, five of these laboratories analyzed an additional sample set at least one month after the analysis period of the first set. Statistical evaluation of all the results was performed to obtain the expected isotope ratios of each sample, which were then subsequently used in deep reservoir fluid composition calculations. RESULTS: The overall analytical precisions of the measurements were ± 0.2‰ for δ18 O values and ± 2.0‰ for δ2 H values within the 95% confidence interval. CONCLUSIONS: The measured and calculated δ18 O and δ2 H values of water sampled at the weir box, separator and wellhead of geothermal wells suggest the existence of hydrogen and oxygen isotope-exchange equilibrium between the liquid and vapor phases at all sampling points in the well. Thus, both procedures for calculating the isotopic compositions of the deep geothermal reservoir fluid - using either the analytical data of the liquid phase at the weir box together with those of vapor at the separator or the analytical data of liquid and vapor phases at the separator -are equally valid.

Functionalized rare earth-doped nanoparticles for breast cancer nanodiagnostic using fluorescence and CT imaging.

BACKGROUND: Breast cancer is the second leading cause of cancer death among women and represents 14% of death in women around the world. The standard diagnosis method for breast tumor is mammography, which is often related with false-negative results leading to therapeutic delays and contributing indirectly to the development of metastasis. Therefore, the development of new tools that can detect breast cancer is an urgent need to reduce mortality in women. Here, we have developed Gd2O3:Eu3+ nanoparticles functionalized with folic acid (FA), for breast cancer detection. RESULTS: Gd2O3:Eu3+ nanoparticles were synthesized by sucrose assisted combustion synthesis and functionalized with FA using EDC-NHS coupling. The FA-conjugated Gd2O3:Eu3+ nanoparticles exhibit strong red emission at 613 nm with a quantum yield of ~ 35%. In vitro cytotoxicity studies demonstrated that the nanoparticles had a negligible cytotoxic effect on normal 293T and T-47D breast cancer cells. Cellular uptake analysis showed significantly higher internalization of FA-conjugated RE nanoparticles into T-47D cells (Folr hi ) compared to MDA-MB-231 breast cancer cells (Folr lo ). In vivo confocal and CT imaging studies indicated that FA-conjugated Gd2O3:Eu3+ nanoparticles accumulated more efficiently in T-47D tumor xenograft compared to the MDA-MB-231 tumor. Moreover, we found that FA-conjugated Gd2O3:Eu3+ nanoparticles were well tolerated at high doses (300 mg/kg) in CD1 mice after an intravenous injection. Thus, FA-conjugated Gd2O3:Eu3+ nanoparticles have great potential to detect breast cancer. CONCLUSIONS: Our findings provide significant evidence that could permit the future clinical application of FA-conjugated Gd2O3:Eu3+ nanoparticles alone or in combination with the current detection methods to increase its sensitivity and precision.

The geospatial relationship of geologic strata, geological fractures, and land use attained by a time-series aridity index in a semiarid region.

In a vast semiarid region of the Baja California Peninsula, remote sensing and GIS techniques were applied to moderate resolution images of Landsat 5 TM to explore the geospatial correlation among the grid aridity index (AI), shapefiles of geologic strata, land use, and geological fractures. A dataset of randomized sample points in a time-series of one hydrologic year along with vector file GIS delineated geologic fractures-including the area between their left/right parallel buffer lines-was used as mask analysis. MANOVA results were significant (p < 0.05) for geologic strata, land use, and basin. Overall results reveal the effects of soil texture on water retention on deeper soil horizons and the rate of vertical motion of rainwater. Despite the fact that geologic fractures underlie a large number of biotic communities, in both latitude and longitude gradients of the peninsula, no statistical significance was observed among the fractures themselves or the areas between their parallel buffer lines. One pulse rainfall event was documented by the AI grid maps enabling a robust vegetative response in early summer to an abnormal amount of rain provided by tropical storm Julio. AI grids appear to be useful for characterizing an ecosystem's dynamism. New options are suggested for this research strategy by expanding the number of datasets and incorporating geographic exclusion areas.

Future groundwater extraction scenarios for an aquifer in a semiarid environment: case study of Guadalupe Valley Aquifer, Baja California, Northwest Mexico.

Semiarid northwestern Mexico presents a growing water demand produced by agricultural and domestic requirements during the last two decades. The community of Guadalupe Valley and the city of Ensenada rely on groundwater pumping from the local aquifer as its sole source of water supply. This dependency has resulted in an imbalance between groundwater pumpage and natural recharge. A two-dimensional groundwater flow model was applied to the Guadalupe Valley Aquifer, which was calibrated and validated for the period 1984-2005. The model analysis verified that groundwater levels in the region are subject to steep declines due to decades of intensive groundwater exploitation for agricultural and domestic purposes. The calibrated model was used to assess the effects of different water management scenarios for the period 2007-2025. If the base case (status quo) scenario continues, groundwater levels are in a continuous drawdown trend. Some wells would run dry by August 2017, and water demand may not be met without incurring in an overdraft. The optimistic scenario implies the achievement of the mean groundwater recharge and discharge. Groundwater level depletion could be stopped and restored. The sustainable scenario implies the reduction of current extraction (up to about 50 %), when groundwater level depletion could be stopped. A reduction in current extraction mitigates water stress in the aquifer but cannot solely reverse declining water tables across the region. The combination of reduced current extraction and an implemented alternative solution (such as groundwater artificial recharge), provides the most effective measure to stabilize and reverse declining groundwater levels while meeting water demands in the region.