Anthropogenic interventions on land neutrality in a critically vulnerable estuarine island ecosystem: a case of Munro Island (India).

All landscapes, including estuarine islands, normally try to restore their geomorphic isostasy in all anthropogenic interventions on land dynamics. Munroe Island has been experiencing drastic environmental degradation, such as land subsidence, severe tidal/monsoon flooding, subsidence of build-ups and a drastic decay in agricultural productivity. This paper examines the role of anthropo-geomorphic interventions causing for the land degradation in Munroe Island through a multidisciplinary approach. Multidated, multiresolution satellite products and published maps, spanning a period of about six decades from 1960 to 2021, were used to understand the different geomorphic and geographical processes in the study area. Evaluation of the temporal bathymetric datasets, salinity measurements of the river and estuary, borehole data logs of the area and electrical resistivity surveys of the island were analyzed to find out the causative factors for the disturbances in the land neutrality, along with the tidal hydrodynamic changes in the region. The study shows about 14% of the total land area was vanished during the study period, and more than 25% of the area is under stress, leading to further land degradation. More than 500 households are forced to vacate their residence due to land subsidence/flooding. Lack of required freshwater and sediment supply from the Kallada river after the construction of the Thenmala reservoir in the Kallada river as well as the uncontrolled sand mining prevailed are the key factors for the environmental degradation of Munroe Island. The paper describes the role and colinkages of human-induced hydrogeomorphic interventions on a geomorphic system, in charge of the environmental degradation and land subsidence crisis of an estuarine island ecosystem and discusses the concerns related to the management strategies of such region.

Geochemical aspects and contamination evaluation of major and trace elements in the sediments of Kallada river, southern Western Ghats, India.

The metal concentrations within the sediments of Kallada River Basin (KRB) draining the south-western flanks of Western Ghats in Kerala, India were examined using pollution indices and statistical analysis in order to inspect the level of contamination. This study includes a systematic analysis of sediment contamination by heavy metals and major oxides of the river Kallada draining the south-western flanks of Western Ghats in Kerala, India during pre-monsoon (May 2019), monsoon (September 2019) and post-monsoon (February 2020) seasons. Sediment samples were taken from 20 locations and the major investigations carried out in the sediment samples include geochemical analysis for the determination of major oxides and minor (trace) elements by using X-ray Fluorescence spectrometer (XRF) and textural analysis for the classification of sediment samples into different categories. To understand the pollution loads in the sediments of the area under study, the heavy metal and major element contamination of the samples were assessed based on crustal enrichment factor (EFc), geo accumulation index (Igeo), contamination factor (CF), degree of contamination (Cdeg) and pollution load index (PLI). From the analysis, it is seen that the coastal sediments of KRB were polluted mainly by Zirconium which exhibits high values in the pre-monsoon season. Among the major elements, Titanium is the only one which manifests slightly higher values in the pre-monsoon period. Based on the textural analysis, it is observed that these sediments predominantly come under sandy loam and loamy silt classifications during the three seasons of study. The concentrations of heavy metals and major ions in the surface sediments of Kallada river were studied to determine the extent of anthropogenic inputs in this tropical river system.

Nail-Patella Syndrome: A Rare Cause of Nephrotic Syndrome in Pregnancy.

Nail-Patella syndrome (NPS) is an inherited disease with characteristic nail, limb, and renal anomalies. While almost all patients manifest classical skeletal and nail abnormalities, renal involvement is seen in only 40% of patients. Asymptomatic proteinuria is the most common renal presentation. Although a substantial number of patients can progress to nephrotic range proteinuria, development of end-stage kidney disease is rare. Pathological abnormalities are appreciable only by electron microscopy. Our patient who had not been diagnosed with NPS previously presented with new-onset proteinuria during the second trimester of her first pregnancy. The characteristic physical and radiological features confirmed the diagnosis of NPS. Her clinical course was complicated by nephrotic syndrome with fetal loss at 22 weeks and postpartum renal vein thrombosis. Nephrotic state improved after termination of pregnancy. She was managed with angiotensin receptor blocker and anticoagulation. At the end of 2 years of follow-up, she has normal glomerular filtration rate with minimal proteinuria.

Ultrasound-assisted preparation and characterization of crystalline cellulose-ionic liquid blend polymeric material: a prelude to the study of its application toward the effective adsorption of chromium.

The molecular interaction of biopolymers with an array of substrates offers interesting insight into the adsorption phenomenon. The present work proposes the preparation and characterization of cellulose-methyltrioctylammonium chloride (MeTOACl)-a room temperature ionic liquid (IL) blend polymeric sorbent and its application for the adsorption of carcinogenic chromium(VI). The blend adsorbent material was synthesized in a relatively green solvent (methylisobutylketone) medium by ultrasonication. The mechanism of interaction of biopolymer with the ionic liquid could be conceptualized as electrostatic attraction, hydrogen bonding, and Van der Waals force of attraction with the hydroxyl groups of cellulose as a bilayer assembly. The composition, crystallinity, and the surface area of the prepared material were comprehensively characterized using FT-IR, solid-state (13)C NMR, TGA, XRD, SEM, EDX, XPS, and BET isotherm study. The adsorption capacity of chromium(VI) calculated from Langmuir isotherm model was found to be 38.94 mg g(-1) with adherence to the second-order kinetics. The study of thermodynamic parameters that affect the sorption process indicated the spontaneity and exothermic nature of adsorption. The green aspect in the methodology is brought out in the regeneration of the adsorbent, where Cr(VI) could be effectively reduced to the less toxic Cr(III) using ascorbic acid.

A preliminary spectroscopic investigation on the molecular interaction of metal-diphenylthiocarbazone complex with cellulose biopolymer and its application.

Biopolymer adsorbents are versatile in their application for removal of heavy metals. The present work is focused towards the preliminary study of the interaction of diphenylthiocarbazone (DTZ) complex of chromium(VI) in acidic medium with cellulose biopolymer. Chromium-DTZ complex could be quantitatively adsorbed on a cellulose column in the pH range 1.0-2.5 and the effect of various experimental parameters such as stability of the column and the complex, column breakthrough volume, and interfering ions have been studied in detail. The probable mechanism of adsorption of complex on the cellulose biopolymer was corroborated using Fourier transform infra-red spectroscopy (FT-IR), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) and solid state 13C nuclear magnetic resonance techniques (CP-MAS). The pores formed due to the hydrogen bond between the cellulose layers and then the ensuing occupation of the complex between these layers and on the surface of the biopolymer layer through electrostatic attractive force and Π interaction of aromatic ring with cellulose are expected to play a vital role in the interaction. The cellulose column could be regenerated using environmentally benign polyethylene glycol-400 (PEG-400) in acidic medium. The cellulose biosorbent has been successfully tested to study the removal of chromium as its dithizone complex from synthetic and real waste water samples.

MR and CT Evaluation of Dysembryoplastic Neuroepithelial Tumor. A Case Report.

A 33-year-old man presented with a long history of intractable partial seizures with the first episode at the age of 18 years. The seizure frequency had increased in the recent past. CT imaging revealed a low attenuation lesion in the left frontal cortex with calvarial scalloping. MR imaging revealed a heterogeneous signal intensity lesion with involvement of the cortex and the subcortical white matter. In dysembryoplastic neuroepithelial tumor the neoplastic elements adjacent to the cortex might cause disorganization of cortical layers in the developmental stage leading to cortical dysplasia. Architectural dysplasia is characterized by cortical thickening and ectopic neurons in the white matter. MR imaging features reflect the characteristics of cortical dysplasia and ectopic neurons in the sub-cortical white matter.

Pachymeningeal metastasis from squamous cell carcinoma of the uterine cervix with involvement of the optic nerve: case report and review of the literature.

This report describes the case of a 50-year-old woman with carcinomatous meningitis from squamous cell carcinoma of the uterine cervix. Ultrasound showed an irregular hypoechoic mass in the cervix. Contrast enhanced computed tomography imaging revealed intense linear enhancement along the falx cerebri suggestive of pachymeningeal metastasis with involvement of the optic nerve. To our knowledge this is the first reported case of imaging features of isolated metastatic dural involvement from cervical carcinoma. Moreover, this is the first case of its kind in which dural involvement was diagnosed at presentation in a locally confined tumour.

CT and MR Imaging in Choroid Plexus Carcinoma. Report of Two Cases.

This case report describes the CT and MR appearances of choroid plexus carcinomas in children less than two years of age. MR and CT imaging of this rare tumor revealed intensely enhancing mass lesions in an intraventricular location, the atrium of the lateral ventricle being the preferred site in children. The tumors were associated with hydrocephalus and cerebral parenchymal invasion.

Is environmental degradation the root cause for communicable diseases in kerala? A case study.

In Kerala (India), environmental degradation, consequent to urbanization, industrialization and skewed agricultural practices, is on the rise. The urban area has acute land and water pollution due to these activities. In Thiruvananthapuram district, especially in certain pockets of squalor and poor environmental quality, communicable diseases are being reported frequently. The present study aims to highlight the causes of environmental degradation which are directly related to the health issues of Thiruvananthapuram district. Based on this study some recommendations are also made for enhancing the environmental quality of the region.

Failure-to-thrive, maltreatment and the behavior and development of 6-year-old children from low-income, urban families: a cumulative risk model.

OBJECTIVE: A cumulative risk model was used to examine the relationship among failure-to-thrive (FTT), maltreatment, and four aspects of children's development: cognitive performance (standardized testing), adaptive functioning at school, and classroom behavior (teacher report), and behavior at home (maternal report). METHOD: The sample included 193 6-year-old children and their families, recruited from pediatric clinics serving inner-city, low-income, primarily African-American families, who were part of a longitudinal investigation of child development and maltreatment. Four risk groups were formed based on their growth and maltreatment history: neither FTT nor Maltreatment, FTT Only, Maltreatment Only, and both FTT and Maltreatment. FTT was defined as a deceleration in weight gain (weight-for-age below the 5th percentile) prior to 25 months of age among children born at term with birth weight appropriate for gestational age. Maltreatment was defined as having at least one report to CPS for neglect, physical abuse and/or sexual abuse. RESULTS: Risk status was negatively associated with each of the four developmental outcomes. Children with a history of both FTT and maltreatment had more behavior problems and worse cognitive performance and school functioning than children with neither risk factor. Children with only one risk factor (either FTT or maltreatment) achieved intermediate scores. CONCLUSIONS: Findings support a cumulative risk model as being more detrimental to children's development than the presence of a single risk factor alone, consistent with theories linking the accumulation of environmental risks to negative consequences. These results underscore the importance of interventions to prevent both FTT and maltreatment during children's early years.

Predicting longitudinal growth curves of height and weight using ecological factors for children with and without early growth deficiency.

Growth curve models were used to examine the effect of genetic and ecological factors on changes in height and weight of 225 children from low income, urban families who were assessed up to eight times in the first 6 y of life. Children with early growth deficiency [failure to thrive (FTT)] (n = 127) and a community sample of children without growth deficiency (n = 98) were examined to evaluate how genetic, child and family characteristics influenced growth. Children of taller and heavier parents, who were recruited at younger ages and did not have a history of growth deficiency, had accelerated growth from recruitment through age 6 y. In addition, increases in height were associated with better health, less difficult temperament, nurturant mothers and female gender; increases in weight were associated with better health. Children with a history of growth deficiency demonstrated slower rates of growth than children in the community group without a history of growth deficiency. In the community group, changes in children's height and weight were related to maternal perceptions of health and temperament and maternal nurturance during feeding, whereas in the FTT group, maternal perceptions and behavior were not in synchrony with children's growth. These findings suggest that, in addition to genetic factors, growth is dependent on a nurturant and sensitive caregiving system. Interventions to promote growth should consider child and family characteristics, including maternal perceptions of children's health and temperament and maternal mealtime behavior.

Children in low-income, urban settings. Interventions to promote mental health and well-being.

Urbanization provides unique political, cultural, economic, and educational opportunities for children and families. However, it may also have a negative impact on the mental health and well-being of children and adolescents, particularly when they are exposed to settings with high rates of crime, violence, delinquency, substance use, abuse, and poverty. Psychologists are well suited to intervene in problems associated with urbanization. However, most psychological services have been directed toward children who are experiencing problems, and there has been less focus on population-based or preemptive interventions that prevent problems before they occur. This review presents 11 recommendations for urban interventions that build on individual, family, and community strengths to promote the mental health and well-being of urban children and adolescents.