Electrochemical quantification of atrazine-fulvic acid and removal through bismuth tungstate photocatalytic hybrid membranes.

Herbicides such as atrazine and humus substances such as fulvic acid are widely used in agricultural sector. They can be traced in surface and groundwater around the agriculture field at concentrations beyond the approved limit due to their mobility and persistence. Bismuth-based photocatalysts activated by visible light are potential materials for removing various organic pollutants from water bodies. These photocatalysts can also be suitable candidates for developing a hybrid membrane with anti-fouling properties. In this study, Bi2WO6 nanoparticles were synthesized via the hydrothermal method and integrated into the cellulose acetate (CA), polyetherimide (PEI), polysulfone (PSF) and polyvinylidene fluoride (PVDF) polymers via physical blending approach. The hybrid membranes were then characterized by FTIR, XPS and FESEM to confirm the chemical bonding, chemical composition and surface morphology of Bi2WO6. Thus, the pure water flux of CA (35.6 L m-2 h-1), PEI (46.56 L m-2 h-1), PSF (6.84 L m-2 h-1), and PVDF (68.47 L m-2 h-1) hybrid membranes has significantly enhanced than the pristine CA, PEI, PSF and PVDF membranes. The significant rejection of atrazine-fulvic acid was observed with hybrid membranes in the order of CA (84.1%) > PVDF (72.7%) > PEI (47.8%) > PSF (37.2%), and these membranes have shown an excellent flux recovery ratio than pristine membranes. Further, electrochemical quantification studies were performed to analyze the removal efficiency of atrazine-fulvic acid from water. In this present work, GO-modified SPE was employed for electrochemical sensing studies. The resultant CA hybrid membrane achieved removal efficiency of 84.08% for atrazine. It was observed that the Bi2WO6 established strong bonding with CA, and PVDF membranes, thus showing a significant removal efficiency and FRR than other hybrid and pristine membranes.

Surface-initiated polymerization of PVDF membrane using amine and bismuth tungstate (BWO) modified MIL-100(Fe) nanofillers for pesticide photodegradation.

Pirimicarb as a pesticide is used to control the aphids in the agriculture field; however, it affects the groundwater ecosystem by leaching through the soil profile. The post-synthetic amine and BWO modified MIL-100 (Fe) nanofillers were synthesized. The photocatalytic property of amine-functionalized and BWO@MIL-100(Fe) nanofillers was confirmed by the lesser bandgap energy than the unmodified MIL-100 (Fe) nanofiller. Herein, we constructed a nanofillers grafted PVDF membrane via in-situ polymerization technique for the pirimicarb reduction and photodegradation. Furthermore, the nanofiller's grafted membranes were characterized by FESEM, XRD, FTIR, and contact angle analysis. The carboxylic acid peak was observed on the FTIR which demonstrated the PAA grafted on the membrane surface and similar crystalline peaks evident that the nanofillers were grafted on the membrane surface. Furthermore, surface morphology studies have exhibited the dispersion of nanofillers and enhanced microvoids in the cross-section of the membrane. The decrease in the water contact angle of the membrane depicted the improved antifouling properties and surface energy. The nanofiller's grafted membranes have shown higher hydrophilicity correlated well with the enhanced pure water flux in the order M4 > M5 > M2 > M3 > M6 > M7 compared to the neat membrane (M1). In BWO@MIL-100(Fe) membrane has shown a higher permeate flux (25.99 L m-2.h-1) than the neat PVDF membrane. The BWO@MIL-100(Fe) grafted PVDF membrane has also shown excellent pirimicarb photodegradation of 81% at pH 5. The proposed MIL-100 (Fe) and bismuth tungsten nanocomposite will pave the way for the different MOF-based photocatalytic materials for membrane-based pesticide degradation.

Surface-constructing of visible-light Bi2WO6/CeO2 nanophotocatalyst grafted PVDF membrane for degradation of tetracycline and humic acid.

The synthesis of Bi2WO6 and CeO2 photocatalytic nanomaterials exhibit a great ability to photodegrade the antibiotics and shown excellent oxidation of various organic pollutants. Heterostructure 1:1 & 2:1 Bi2WO6/CeO2 nanocomposite was successfully synthesized via the facile sono-dispersion method and exquisite photocatalytic activity. The 0.5 wt% of nanocomposites were well-grafted on PVDF membrane surface via an in-situ polymerization method using polyacrylic acid. The fourier transform infrared (FTIR) spectra demonstrated that the network formation in PVDF induced by the -COOH functional group in acrylic acid. The grafted membrane morphology and strong binding ability over the membranes were validated by scanning electron microscope with energy dispersion (SEM-EDS) and X-ray photoelectron spectroscopy (XPS), respectively. The permeate flux of 49.2 L.m-2 h-1 and 41.65 L.m-2 h were observed for tetracycline and the humic acid solution respectively for 1 wt% of PVP and 0.5 wt% of photocatalytic nanomaterials in PVDF membrane. The tetracycline and humic acid photodegradation rate of 82% and 78% and total resistance of 1.43 × 1010 m-1 and 1.64 × 1010 m-1, 83.5% and 77% flux recovery ratio were observed with N5 membrane. The 2:1 Bi2WO6/CeO2 nanocomposite grafted membrane showed a high permeate flux and better photodegradation ability of organic pollutants in the wastewater.