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J Air Waste Manag Assoc ; 70(5): 504-521, 2020 05.
Article in English | MEDLINE | ID: mdl-32186474

ABSTRACT

On January 22, 2010, the U.S. Environmental Protection Agency (EPA) established a new one-hour probabilistic National Ambient Air Quality Standard (NAAQS) for nitrogen dioxide (NO2) at 100 parts per billion (ppb) or approximately 188 micrograms per cubic meter (µg/m3). The 1-hr NO2 NAAQS is considerably more stringent than the longstanding annual standard of 53 ppb or approximately 100 µg/m3. AERMOD is the EPA recommended dispersion modeling tool for predicting impacts from emission sources, including compressor station reciprocating engines. Existing datasets were previously reviewed to evaluate and improve AERMOD 1-hr NO2 model performance. However, these datasets were not representative due to either an absence of accurate concurrent hourly emission inventories, being associated with larger electric generating units, shorter duration tracer studies, or were too site-specific (e.g., external influences such as terrain). To address this data gap, an intensive 13-month field data program was undertaken by Pipeline Research Council International (PRCI) to collect a comprehensive dataset including concurrent emissions, meteorological, and ambient ozone and nitrogen oxide measurements. This paper describes the Balko, OK natural gas compressor station host site and the design of the meteorological, ambient NOx and O3 monitors and continuous Parametric Emissions Monitoring System (PEMS). Two comparisons are made between the monitored data and AERMOD results. First, the measured onsite data (ambient air, meteorological, and emissions) were used as input to AERMOD to make comparisons between measured and modeled NOx and NO2. These comparisons showed that NOx was both over and under predicted, sometimes beyond a factor-of-two. The second comparison uses the typical permitting approach where onsite data are not available to contrast how conservative input assumptions for emissions, background O3, NO2, and offsite meteorology cause significant over predictions especially for this site where engines have a low annual utilization rate and operate infrequently throughout the year.Implications: This project resulted following the promulgation of the new 1-hr NO2 NAAQS and the challenges that natural gas pipeline compressor stations have in modeling intermittent emissions using AERMOD to demonstrate compliance with this standard. AERMOD was developed and validated with a primary focus on large sources with tall stacks, such as electric utility boilers. A recently collected dataset at a gas compressor station in Balko, Oklahoma shows that the use of permitted allowable emission values compared to actual hourly emission values causes over predictions using typical regulatory methods. Comparison of model results using actual hourly emission values to coincident ambient air monitoring values at the site shows that AERMOD over predicts near-field impacts due to simplifying assumptions including building downwash, plume dispersion, chemistry, and 1-hr invariant meteorological conditions.


Subject(s)
Air Pollutants/analysis , Environmental Monitoring/methods , Models, Theoretical , Nitrogen Oxides/analysis , Ozone/analysis , Natural Gas , United States , United States Environmental Protection Agency
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