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Synthesis and Antioxidant Activity of Carane and Pinane Based Sulfenimines and Sulfinimines.
Sudarikov, Denis V; Krymskaya, Yulia V; Shevchenko, Oksana G; Slepukhin, Pavel A; Rubtsova, Svetlana A; Kutchin, Aleksandr V.
Chem Biodivers ; 16(11): e1900413, 2019 Nov.
Article in English | MEDLINE | ID: mdl-31503399

ABSTRACT

The synthesis of sulfenimines and sulfinimines has been carried out with 10-hydroxyisocamphylthiol. The configuration of the compounds has been deduced by methods of NMR, DFT calculations and X-ray diffraction analysis. The cytotoxic, antioxidant and membrane-protective activity of the synthesized compounds as well as of the previously obtained sulfenimines and sulfinimines based on 4-caranethiol have been determined.


Subject(s)
Antioxidants/pharmacology , Bicyclic Monoterpenes/pharmacology , Imines/pharmacology , Antioxidants/chemical synthesis , Antioxidants/chemistry , Bicyclic Monoterpenes/chemical synthesis , Bicyclic Monoterpenes/chemistry , Density Functional Theory , Dose-Response Relationship, Drug , Erythrocytes/drug effects , Humans , Imines/chemical synthesis , Imines/chemistry , Molecular Structure , Structure-Activity Relationship
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