Luminescence chronology of cave sediments at the Atapuerca paleoanthropological site, Spain.

Ascertaining the timing of the peopling of Europe, after the first out-of-Africa demographic expansion at the end of the Pliocene, is of great interest to paleoanthropologists. One of the earliest direct evidences for fossil hominins in western Europe comes from an infilled karstic cave site called Gran Dolina at Atapuerca, in a stratum approximately 1.5m below the Brunhes-Matuyama (B-M) geomagnetic boundary (780ka) within lithostratigraphic unit TD6. However, most of the meters of fossil- and tool-bearing strata at Gran Dolina have been difficult to date. Therefore, we applied both thermoluminescence (TL) and infrared-stimulated-luminescence (IRSL) multi-aliquot dating methods to fine-silt fractions from sediment samples within Gran Dolina and the nearby Galería cave site. We also applied these methods to samples from the present-day surface soils on the surrounding limestone hill slopes to test the luminescence-clock-zeroing-by-daylight assumption. Within the uppermost 4m of the cave deposits at Gran Dolina, TL and paired TL and IRSL ages range stratigraphically from 198+/-19ka to 244+/-26ka. Throughout Gran Dolina, all luminescence results are stratigraphically self-consistent and, excepting results from two stratigraphic units, are consistent with prior ESR-U-series ages from progressively deeper strata. Thermoluminescence ages culminate at 960+/-120ka approximately 1m below the 780ka B-M boundary. At Galería, with one exception, TL and IRSL ages range stratigraphically downward from 185+/-26ka to 503+/-95ka at the base of the lowermost surface-inwash facies. These results indicate that TL and (sometimes) IRSL are useful dating tools for karstic inwash sediments older than ca. 100ka, and that a more accurate chronostratigraphic correlation is now possible among the main Atapuerca sites (Gran Dolina, Galería, Sima de los Huesos). Furthermore, the oldest TL age of ca. 960ka from Gran Dolina, consistent with biostratigraphic and paleomagnetic evidence, implies a probable numeric age of 900-950ka for the oldest hominin remains ( approximately 0.8m below the TL sample). This age window suggests a correspondence to Marine Isotope Stage (MIS) 25, a relatively warm and humid interglaciation.

High-precision U-series dating of Locality 1 at Zhoukoudian, China.

Thermal ionization mass spectrometric(230)Th/(234)U dating has been carried out on intercalated speleothem samples from the limestone cave occupied by Homo erectus at Zhoukoudian, China. The samples were recently collected in proper stratigraphic context after detailed field examinations. The results show that the age of the No. 5 Skull from Layer 3 is >400 ka, possibly in the range of about 400-500 ka, and that the hominid fossils from the lower strata are at least 600 ka and possibly >800 ka, much older than previously thought. The near-equilibrium(230)Th/(234)U ratios and internal consistency of the dates and stratigraphy lend credence to the results and allow us to comment on their important implications for human evolution.

Lavage administration of dilute surfactants after acute lung injury in neonatal piglets.

Exogenous surfactant therapy is not standard in the acute respiratory distress syndrome (ARDS) because of a lack of proven benefit. Nonuniform surfactant distribution after either bolus or aerosol administration may be an important factor limiting response. In a previous study of acute lung injury, we demonstrated that lavage administration of Exosurf (13.5 mg phospholipid/ml) was both effective and distributed uniformly in the lungs. Since the endogenous surfactant pool is much smaller than the typical dose of exogenous surfactant administered, we hypothesized that dilute surfactant preparations (4-4.5 mg phospholipid/ml) administered by lung lavage would be equally effective in reversing pulmonary dysfunction in a piglet model of acute lung injury. We compared three dilute surfactants: Infasurf (n = 5), KL4-Surfactant (n = 6), and Exosurf (n = 5) with controls (n = 6) and undiluted Exosurf (13. 5 mg phospholipid/ml; n = 6). All dilute surfactant preparations were effective in improving oxygenation and other parameters of pulmonary function. Surfactant administered by lavage resulted in uniform lung distribution. We conclude that dilute surfactants administered by lung lavage are effective in reversing pulmonary dysfunction after acute lung injury. We speculate that doses in the range of 20-40 mg phospholipid/kg may be adequate to improve lung function in ARDS when exogenously administered surfactant is uniformly distributed in the lung.

Precise timing of the last interglacial period from mass spectrometric determination of thorium-230 in corals.

The development of mass spectrometric techniques for determination of (230)Th abundance has made it possible to reduce analytical errors in (238)U-(234)U-(230)Th dating of corals even with very small samples. Samples of 6 x 10(8) atoms of (230)Th can be measured to an accuracy of +/-3 percent (2sigma) and 3 x 10(10) atoms of (230)Th can be measured to an accuracy of +/-0.2 percent. The time range over which useful age data on corals can be obtained now ranges from about 50 to about 500,000 years. For young corals, this approach may be preferable to (14)C dating. The precision with which the age of a coral can now be determined should make it possible to critically test the Milankovitch hypothesis concerning Pleistocene climate fluctuations. Analyses of a number of corals that grew during the last interglacial period yield ages of 122,000 to 130,000 years. The ages coincide with, or slightly postdate, the summer solar insolation high at 65 degrees N latitude which occurred 128,000 years ago. This supports the idea that changes in Pleistocene climate can be the result of variations in the distribution of solar insolation caused by changes in the geometry of the earth's orbit and rotation axis.

Radionuclides in mono lake, california.

Several radioisotopes of the naturally occurring uranium and thorium decay series, in addition to fallout plutonium, have unusually high concentrations in the water column of Mono Lake, a natural alkaline, saline lake. Complexing by carbonate ions appears to be responsible for the enhanced solubility of actinide elements with oxidation states of IV to VI. In contrast, fallout strontium-90 has been largely removed from the water, probably as a result of coprecipitation with calcium carbonate. The daughter/parent activity ratios of thorium, radium, and uranium isotopes suggest that thorium is removed from the water column to the sediments on time scales substantially longer than a month and that the desorption of thorium from the sediments to the water column requires less than a few years.

Eustatic sea level 120,000 years ago on oahu, hawaii.

Extensive dating of the fossil corals associated with the Waimanalo shoreline on Oahu has shown that 120,000 years ago the ocean was approximately 7.6 meters above its present level. Corals grown during that time constitute a major portion of the subaerial reef-derived material on the island, with exposures ranging from about 10 meters to near sea level. This evidence corroborates the notion that 120,000 years before the present was the last time during which the sea stood significantly higher than it does today. The reported benches at 3.7, 1.5, and 0.6 meters, if not of Recent origin, could be features created by brief halts of the sea during rapid regression shortly after the Waimanalo high stand.

Milankovitch hypothesis supported by precise dating of coral reefs and deep-sea sediments.

Barbados provides a possibly unique opportunity for reconstruction of the times and elevations of late-Pleistocene high stands of the sea. The island appears to be rising from the sea at a uniform rate that is fast enough to separate in elevation coral-reef tracts formed at successive high stands of the sea. Unaltered coral found in the lower terraces enables high-precision Th(230): U(234) and Pa(231): U(235) dating. Three distinct high stands of the sea are found about 122,000, 103,000, and 82,000 years ago. New Pa(231) and Th(230) dates from a deep-sea core also indicate that Ericson's W-X cold-to-warm climatic change occurred close to 126,000 years ago. These data show a parallelism over the last 150,000 years between changes in Earth's climate and changes in the summer insolation predicted from cycles in the tilt and precession of Earth's axis.

Atlantic deep-sea stratigraphy: extension of absolute chronology to 320,000 years.

Thorium-230 measurements on a core of globigerina ooze from the Caribbean Sea substantiate the prediction of Ericson et al. that the paleontological boundary U-V (Sangamon-Illinoian boundary in their scheme) in the Atlantic sediments has an age of close to 320,000 years. As the ages derived by Ericson et al. were based on extrapolations of mean sedimentation rates established by carbon-14 and protactinium-231 dating of the upper sections of this and other cores, this result confirms the assumption that sedimentation rates in the Caribbean Sea have not changed significantly during the past several hundred thousand years. The uranium content of the ocean as indicated by the deposition rate of thorium-230 was no more than 30 percent higher during glacial than during interglacial periods.

Manganese nodules: their evolution.

That manganese nodules and adjacent deep-sea sediments are accumulating manganese at almost the same rate has been established by thorium-230 dating of both sediments and nodules of known manganese content. The rate of manganese deposition is nearly constant over the world oceans. A relatively simple model of nodule evolution explains the distribution of manganese nodules between sediment column and sediment-water interface; the model appears to apply to other trace elements such as copper, nickel, and cobalt.