ABSTRACT
The streamlines of the energy flux (Poynting vectors) and chirality flux as well as the intensity of the electric field around various plasmonic nanostructures (nanocube, nanocuboid, nanotriangle, hexagonal nanoplate and bowtie nanoantenna) induced by a circularly polarized (CP) or linearly polarized (LP) light were studied theoretically. The boundary element method combined with the method of moment was used to solve a set of surface integral equations, based on the Stratton-Chu formulation, for analyzing the highly distorted electromagnetic (EM) field in the proximity of these nanostructures. We discovered that the winding behavior of these streamlines exhibits versatility for various modes of the surface plasmon resonance of different nanostructures. Recently, using plasmonic nanostructures to facilitate a photochemical reaction has gained significant attention, where the hot carriers (electrons) play important roles. Our findings reveal a connection between the flow pattern of energy flux and the morphology of the photochemical deposition around various plasmonic nanostructures irradiated by a CP light. For example, numerical results exhibit vertically helical streamlines of the Poynting vector around an Au nanocube and transversely twisted-roll streamlines around a nanocuboid. Additionally, the behaviors of the winding energy and chirality fluxes at the gap and corners of a plasmonic bowtie nanoantenna, implying a highly twisted EM field, depend on the polarization of the incident LP light. Our analysis of the streamlines of the Poynting vector and chirality flux offers an insight into the formation of plasmon-enhanced photocatalysis.
ABSTRACT
A water-immersion laser-scanning annealing (WILSA) method was developed for the heat treatment of a deposited polycrystalline Au film on a glass. The material characterization using X-ray diffraction, field-emission scanning electron microscopy, and electron backscatter diffraction shows improved crystallinity with a more uniform crystallographic orientation of (111) and the grain growth of the annealed Au film. Additionally, the optical constants of the Au film before and after annealing were characterized by spectroscopic ellipsometry in the visible to near-infrared (NIR) regime, and the corresponding optical densities (ODs) were measured by transmittance spectroscopy. Our results show that the extinction coefficient and the OD of the annealed film are significantly reduced, particularly in the NIR regime. This is because the grain growth caused by the annealing reduces the density of grain boundaries, leading to the decrease of the loss of free electrons' scattering at grain boundaries. Hence, the damping effect of the surface plasmon is reduced. Additionally, the integrity of the WILSA-treated thin film is kept intact without pinholes, usually produced by the conventional thermal annealing. Based on the improved optical property of the WILSA-treated Au film, two performances of an insulator-metal-insulator (IMI) layered structure of biosensors are theoretically analyzed. Numerical results show that the propagation length of a long-range surface plasmon polariton along an IMI structure with an annealed Au film is significantly increased, compared to an unannealed film, particular in the NIR region. For the other application of using an IMI sensor to detect the shift of the surface-plasmon-resonance dip in the total internal reflection spectrum for the measurement of a change of the medium's refractive index, the sensitivity is also profoundly improved by the WILSA method. It is worth mentioning that the optimal heating conditions (laser wavelength, fluence, exposure time, and scanning step) depend on the thickness of the Au film. Our study provides a postprocess of WILSA to improve the optical properties of a deposited polycrystalline Au film for raising the sensitivity of the related biosensors.
ABSTRACT
The conversion of a helical surface plasmon polariton (SPP) creeping out of a circular nanohole in a thick metal (Ag or Au) film into a spiral (Hankel type) SPP outward propagating at the film's interface is studied theoretically. The dispersion relations of SPPs of various modes in a nanohole, calculated from a transcendental equation, show that the propagation length of an SPP of mode 1 is much larger than the other modes in a specific frequency band, which is dependent on the nanohole size. In this band, the streamlines of the Poynting vector (energy flux) of mode-1 SPP in nanohole exhibit helixes; the surface component of the energy flux is perpendicular to the phase front of the SPP. Numerical results show that, after a helical SPP tunnels through a nanohole, most of the energy flux fans out at the outlet as a dipole radiation. The spatial phase distribution of E z above the interface indicates that the transmission light carries orbital angular momentum with a topological charge of 1. Additionally, a part of the helical SPP creeping along the edge of an outlet naturally converts into a spiral (Hankel type of order 1) SPP outward propagating at the film's interface; both SPPs have the same handedness. Moreover, the interferences of multi SPPs generating from two nanoholes and even from a two-dimensional nanohole array are also related to the spiral SPP.
ABSTRACT
The surface plasmon polaritons (SPPs) of higher-order mode propagating along a plasmonic nanowire (NW) or an elongated nanorod (NR) are studied theoretically. The dispersion relations of SPPs in NWs of different radii, obtained from a transcendental equation, show that the propagation lengths of SPPs of mode 1 and 2 at a specific frequency are longer than that of mode 0. For the higher-order mode, the spatial phase of the longitudinal component of electric field at a cross section of a NW exhibits the topological singularity, which indicates the optical vortex. Of importance, the streamlines of Poynting vector of these SPPs exhibit a helical winding along NW, and the azimuthal component of orbital momentum density exists in the nearfield of NW to produce a longitudinal orbital angular momentum (OAM). Two types of standing wave of counter-propagating SPPs of mode 1 and 2 are also studied; they perform as a string of beads or twisted donut depending on whether the handedness of two opposite-direction propagating SPPs is same or opposite. In addition, a SPP of mode 1 propagating along an elongated NR can be generated by means of an end-fire excitation of crossed electric bi-dipole with 90° phase difference. If the criterion of a resonator for a mode-1 standing wave (string of beads) is met, the configuration of a plasmonic NR associated with a pair of bi-dipoles with a phase delay (0° or 180°) at the two ends can be applied as a high-efficiency nanoantenna of transmission. Our results may pave a way to the further study of SPPs of higher-order mode carrying OAM along plasmonic waveguides.
ABSTRACT
Plasmon-enhanced photothermal and optomechanical effects on deforming and reshaping a gold nanoparticle (NP) are studied theoretically. A previous paper (Wang and Ding, ACS Nano 13, 32-37, 2019) has shown that a spherical gold nanoparticle (NP) irradiated by a tightly focused laser beam can be deformed into an elongated nanorod (NR) and even chopped in half (a dimer). The mechanism is supposed to be caused by photothermal heating for softening NP associated with optical traction for follow-up deformation. In this paper, our study focuses on deformation induced by Maxwell's stress provided by a linearly polarized Gaussian beam upon the surface of a thermal-softened NP/NR. We use an elastic model to numerically calculate deformation according to optical traction and a viscoelastic model to theoretically estimate the following creep (elongation) as temperature nears the melting point. Our results indicate that a stretching traction at the two ends of the NP/NR causes elongation and a pinching traction at the middle causes a dent. Hence, a bigger NP can be elongated and then cut into two pieces (a dimer) at the dent due to the optomechanical effect. As the continuous heating process induces premelting of NPs, a quasi-liquid layer is formed first and then an outer liquid layer is induced due to reduction of surface energy, which was predicted by previous works of molecular dynamics simulation. Subsequently, we use the Young-Laplace model to investigate the surface tension effect on the following deformation. This study may provide an insight into utilizing the photothermal effect associated with optomechanical manipulation to tailor gold nanostructures.
ABSTRACT
3D optical vortex trapping upon a polystyrene nanoparticle (NP) by a 1D gold dimer array is studied theoretically. The optical force field shows that the trapping mode can be contact or non-contact. For the former, the NP is attracted toward a corresponding dimer. For the latter, it is trapped toward a stagnation point of zero force with a 3D spiral trajectory, revealing optical vortex. Additionally the optical torque causes the NP to transversely spin, even though the system is irradiated by a linearly polarized light. The transverse spin-orbit interaction is manifested from the opposite helicities of the spin and spiral orbit. Along with the growth and decline of optical vortices the trapped NP performs a step-like motion, as the array continuously moves. Our results, in agreement with the previous experiment, identify the role of optical vortex in the near-field trapping of plasmonic nanostructure.
ABSTRACT
We generate photonic bandgaps (PBGs) in dielectric slab waveguides by exciting their acoustic plate eigenmodes of submicron wavelength. We investigate the optical forbidden bands below the light line where the slab interfaces and index of refraction are periodically modulated by the acoustic fields. Results show that multiple scattering through the enhanced periodic acousto-optic (AO) interaction opens Bragg PBGs. A tunable bandgap width and transmittance are achieved. Transmitted optical waves are found to incur strong nonlinear modulation through AO interaction by a multiphonon exchange mechanism. The applications include tunable optomechanical and AO devices.
