Effect of ajwain (Trachyspermum ammi) extract and gamma irradiation on the shelf-life extension of rohu (Labeo rohita) and seer (Scomberomorus guttatus) fish steaks during chilled storage.

Fishes are highly perishable, mainly stored and transported under frozen condition; however, they are mainly preferred as fresh or in chilled form for consumption because frozen storage compromises the texture quality and other sensory attributes. Shelf-life enhancement of rohu and seer fish steaks was studied using combination of ajwain extract (various concentrations) and γ-irradiation (various doses) under chilled storage (4 °C). These were analyzed periodically by microbiological, sensory, color and biochemical analyses during storage. Gas chromatography - mass spectrometry (GC-MS) analysis showed thymol as major component. High performance liquid chromatography (HPLC) analysis showed the presence of nine phenolic compounds including thymol in ajwain extract. The best result was achieved when samples were dipped in 10 % ajwain extract with 2 kGy gamma irradiation dose. An extended shelf-life of 5 and 10 days in case of rohu and seer fish steaks were attained respectively using this combination. These results were confirmed by microbial, biochemical and sensory analyses. The present study thus promises potential application of the above protocol in fishery industry for good quality of fish and commercial benefits.

Whole-Body Vibration Exposure vis-à-vis Musculoskeletal Health Risk of Dumper Operators Compared to a Control Group in Coal Mines.

Background: Whole-body vibration (WBV) exposure of coal mine dumper operators poses numerous health hazards. The case-control study was aimed at assessing the relative musculoskeletal health risk of dumper operators' exposure to WBV with reference to the nonexposed group. Methods: Measurements of WBV exposure were taken at the operator-seat interface using a human vibration analyzer for 110 dumper operators in three coal mines. This vibration measurement was supplemented by a questionnaire survey of 110 dumper operators exposed to WBV and an equal number of workers not exposed to WBV. The relative risk of musculoskeletal disorders (MSDs) has been assessed through the case-control study design. Results: ISO guidelines were used to compare the health risk. It was observed that the prevalence of pain in the lower back was 2.52 times more in the case group compared to the control group. The case group of Mine-2 was 2.0 times more prone to vibration hazards as compared to Mine-3. Conclusion: The case group is more vulnerable to MSDs than the control group. The on-site measurement as well as the response of the dumper operators during the questionnaire survey corroborates this finding.

Occupational exposure of dumper operators to whole-body vibration in opencast coal mines: an approach for risk assessment using a Bayesian network.

Whole-body vibration (WBV) is one of the leading risk factors for development of musculoskeletal disorders (MSDs) that develop symptoms of lower back pain, pain in the neck and shoulders, digestive problems, blood pressure and diabetes among professional dumper operators. The present study specifically aimed at assessing the WBV exposure of 79 dumper operators engaged in two Indian opencast coal mines through vibration measurements followed by questionnaire survey. From the daily frequency-weighted root mean square exposure, dumper operators have experienced vibration levels higher than the Health Guidance Caution Zone (HGCZ) of Standard No. ISO 2631-1:1997. However, on the basis of daily vibration dose values, 60.8% of operators have experienced vibration levels above the HGCZ. Finally, an attempt was also made to explore the potential of a Bayesian network to predict the risk factors for WBV of dumper operators in development of MSDs to prioritize the factors for human health risk assessment.

Whole-body vibration exposure of heavy earthmoving machinery operators in surface coal mines: a comparative assessment of transport and non-transport earthmoving equipment operators.

Purpose. Two groups of heavy earthmoving equipment operators, transport equipment (dumper) operators and non-transport equipment (drill and shovel) operators, in coal mines are assessed comparatively for their vibration magnitude and possible health consequences. Methods. Whole-body vibration exposure measurements were recorded according to Standard No. ISO 2631-1. Measurements were carried out at the operator-seat interface with a tri-axial seat pad accelerometer using a vibration analyser, followed by a questionnaire survey. The binary logistic regression model was used to comparatively assess the two groups of operators. Results. The binary logistic regression analysis revealed that the risk of lower back pain is 4.06 times greater (95% confidence interval [1.36, 12.08]) in transport equipment operators compared to non-transport operators. The daily vibration dose value of the transport equipment operators was 2.92 times greater than their counterparts (95% confidence interval [0.94, 9.09]). However, non-transport equipment operators belonging to the high driving experience category presented a value 5.26 times higher than the transport equipment operators. Conclusion. Transport equipment operators are more vulnerable to vibration hazards than their counterparts, as is evident from the vibration magnitude as well as from the symptoms of lower back pain.

Cooperative enhancement of antibacterial activity of sanguinarine drug through p-sulfonatocalix[6]arene functionalized silver nanoparticles.

The amelioration of antibacterial efficacy along with the reduced minimum inhibitory concentration (MIC) of sanguinarine (SGR) drug have been demonstrated through the uptake of SGR by p-sulfonatocalix[6]arene functionalized silver nanoparticles. The large upward pKa shift and enhanced stability of SGR resulting from the favorable supra-nanomolecular strategy are deciphered into an improved antibacterial drug against different pathogenic micro-organisms including multi drug resistant bacteria.

Photoelectrochemical activity of as-grown, α-Fe2O3 nanowire array electrodes for water splitting.

Undoped hematite nanowire arrays grown using plasma oxidation of iron foils show significant photoactivity (~0.38 mA cm(-2) at 1.5 V versus reversible hydrogen electrode in 1 M KOH). In contrast, thermally oxidized nanowire arrays grown on iron exhibit no photoactivity due to the formation of a thick (>7 µm Fe(1-x)O) interfacial layer. An atmospheric plasma oxidation process required only a few minutes to synthesize hematite nanowire arrays with a 1­5 µm interfacial layer of magnetite between the nanowire arrays and the iron substrate. An amorphous oxide surface layer on hematite nanowires, if present, is shown to decrease the resulting photoactivity of as-synthesized, plasma grown nanowire arrays. The photocurrent onset potential is improved after removing the amorphous surface on the nanowires using an acid etch. A two-step method involving high temperature nucleation followed by growth at low temperature is shown to produce a highly dense and uniform coverage of nanowire arrays.

Hybrid tin oxide nanowires as stable and high capacity anodes for Li-ion batteries.

In this report, we present a simple and generic concept involving metal nanoclusters supported on metal oxide nanowires as stable and high capacity anode materials for Li-ion batteries. Specifically, SnO(2) nanowires covered with Sn nanoclusters exhibited an exceptional capacity of >800 mAhg(-1) over hundred cycles with a low capacity fading of less than 1% per cycle. Post lithiation analyses after 100 cycles show little morphological degradation of the hybrid nanowires. The observed, enhanced stability with high capacity retention is explained with the following: (a) the spacing between Sn nanoclusters on SnO(2) nanowires allowed the volume expansion during Li alloying and dealloying; (b) high available surface area of Sn nanoclusters for Li alloying and dealloying; and (c) the presence of Sn nanoclusters on SnO(2) allowed reversible reaction between Sn and Li(2)O to produce both Sn and SnO phases.