Photo-polymerization properties of type-II photoinitiator systems based on 2-chlorohexaaryl biimidazole (o-Cl-HABI) and various N-phenylglycine (NPG) derivatives.

A series of p-substituted NPG derivatives (Cl-NPG, OMe-NPG and NO2-NPG) comprising different push-pull characteristics have been synthesized and characterized. The NPG derivatives have good thermal stability and red shifted absorption when compared with the original N-phenyl glycine (NPG) compound. These NPGs were selected in combination with 2-chlorohexaaryl biimidazole (o-Cl-HABI) for Type II free radical polymerization (FRP). Commercial NPG was also mixed with o-Cl-HABI for comparison. Their photo-polymerization properties were investigated by the gel fraction method in a nitrogen atmosphere. Electron transfer efficiencies for those Type II packages were studied by cyclic voltammetry (CV) and free energy change ΔG results.

Numbers of cyanovinyl substitutes and their effect on phenothiazine based organic dyes for dye-sensitized solar cells.

A series of phenothiazine based dyes (OMS1-3), comprising different conjugation lengths and numbers of electron deficient (cyanovinyl) moieties with cyanoacrylic acid as an anchor, have been synthesized. The dyes display broad UV-visible absorption, from 389 nm to 484 nm. The higher molar extinction coefficient and longer absorption peak are achieved as the conjugation length and numbers of electron deficient units increase. The cell performance based on these dyes exhibits efficiencies ranging from 0.68-4.00%, compared to a standard N719-based device (PCE = 7.49%) fabricated under similar conditions. Although the OMS3 dye has two electron deficient units between phenothiazine units, an insignificant electron trapping effect is observed. From the results, the OMS3 based cell exhibits the highest short circuit current (J SC) at 8.72 mA cm-2 and the highest open-circuit voltage (V OC) at 0.66 V, together with the best cell performance at 4.00%.