PCDD/Fs, PAHs and HCl emissions from co-combustion of lignite and chicken manure in a circulating fluidized bed boiler with compact refractory casting.

Chicken manure (CM) should be used in energy production due to its high production potential for the waste-to-energy approach. Co-combustion of CM with lignites may be a good practice in terms of reducing its environmental impact and the need for fossil fuels. However, the level of organic pollutants originated from CM combustion is not clear. This study investigated the potential of CM to be combusted in a circulating fluidized bed boiler (CFBB) with a local lignite. Combustion and co-combustion tests of CM and Kale Lignite (L) were performed in the CFBB to measure PCDD/Fs, PAHs and HCl emissions. CM burned in the upper parts of the boiler due to its high volatile matter content and low density compared to coal. This caused the bed temperature to decrease with the increase in the amount of CM in the fuel mixture. It was also observed that the combustion efficiency increased as the share of CM in the fuel mixture increased. Total PCDD/F emissions increased with CM share in the fuel mixture. However, all are less than emission limit value (100 pg I-TEQ/m3). Co-combustion of CM with lignite at different ratios did not have a significant effect on HCl emissions. PAH emissions were found to increase with the increase of the CM share when the CM share was more than 50% by weight.

Investigation on thermal degradation kinetics and mechanisms of chicken manure, lignite, and their blends by TGA.

In this study, thermogravimetric analysis (TGA) was performed under the air environment for four different heating rates (10, 20, 30, and 40 °C min-1) in order to find out thermal degradation and mechanisms of the chicken manure, a Turkish lignite, and their blends (25 lignite + 75 manure, 50 lignite + 50 manure, and 75 lignite + 25 manure). To calculate thermal kinetics and responsible solid-state mechanisms of the samples, the Flynn-Wall-Ozawa and Coats-Redfern methods were applied. Significant differences between Turkish lignite and chicken manure samples were observed in terms of thermal kinetics and mechanisms. D1 and D4 mechanisms were found to be the responsible mechanisms for the main oxidation region of the lignite and chicken manure/blends, respectively. A similar decreasing trend for the calculated activation energies and pre-exponential constants was observed with increasing biomass content in the manure blends from 25 to 75% by both Flynn-Wall-Ozawa and Coats-Redfern methods. Furthermore, biomass content has an effect on the mechanisms of chicken manure blends during the combustion. D3 was found to be the responsible solid-state mechanism for the third regions (pre-combustion of the manure) of the chicken manure samples. However, D1 and D2 mechanisms were found to be responsible mechanisms for the blends.

Empirical study of alginate impression materials by customized proportioning system.

PURPOSE: Alginate mixers available in the market do not have the automatic proportioning unit. In this study, an automatic proportioning unit for the alginate mixer and controller software were designed and produced for a new automatic proportioning unit. With this device, it was ensured that proportioning operation could arrange weight-based alginate impression materials. MATERIALS AND METHODS: The variation of coefficient in the tested groups was compared with the manual proportioning. Compression tension and tear tests were conducted to determine the mechanical properties of alginate impression materials. The experimental data were statistically analyzed using one way ANOVA and Tukey test at the 0.05 level of significance. RESULTS: No statistically significant differences in modulus of elastisity (P>0.3), tensional/compresional strength (P>0.3), resilience (P>0.2), strain in failure (P>0.4), and tear energy (P>0.7) of alginate impression materials were seen. However, a decrease in the standard deviation of tested groups was observed when the customized machine was used. To verify the efficiency of the system, powder and powder/water mixing were weighed and significant decrease was observed. CONCLUSION: It was possible to obtain more mechanically stable alginate impression materials by using the custom-made proportioning unit.