Modification of Fibers and Matrices in Natural Fiber Reinforced Polymer Composites: A Comprehensive Review.

Application of natural fiber-polymer composites (NFPCs) in different industrial applications provides competitive edge due to their lightweight, higher specific mechanical properties than glass fibers, sustainability, and lower cost involved in production. There are certain challenges associated with natural fibers and their reinforcement in composites such as poor bonding between the fibers and matrix due to their contradictory nature of characteristics, moisture absorption, lower thermal properties, and poor interfacial adhesion between the natural fiber and polymer matrix. The challenges involved in NFPCs need to be overcome to produce materials with relatively equivalent properties to those of conventional composites and other metallic structures. Several researchers around the globe have conducted investigations with the primary attention being paid to the modification of natural fibers and matrix by employing surface treatments and other chemical treatment methods. In order to address the need for eco-friendly and sustainable materials in different domains, a comprehensive review on natural fibers and their sources, available matrix materials, modification techniques, mechanical and thermal properties of NFPCs, is needed for better understanding of the behavior of NFPCs. This work provides the information and holistic view of natural fiber-reinforced composites based on the results obtained from modification techniques, with the view of focusing the review in terms of different chemical and physical treatment techniques, modification of fibers and matrix, and enhanced mechanical and thermal properties in the composites.

Modelling contaminant transport in fly ash-bentonite composite landfill liner: mechanism of different types of ions.

Generated hazardous or toxic waste posses a serious threat if dumped into ponds or low lying areas which leads to contamination, this necessitates the effective landfill liner system. Mainly compacted clayey soils are used as an engineered barrier. Recently, composite materials have gained popularity as landfill liner materials, including the use of waste materials amended with low permeable soils. Though, studies on the composite optimum mix and its corresponding thickness are very scarce. Here, we evaluated the unconfined compressive strength and hydraulic conductivity of fly ash-bentonite composites. Efforts were also made to determine the thickness of landfill liner composite using a finite difference method (i.e. MATLAB). The results reveal that composite consists of 30% bentonite and 70% fly ash is suitable for landfill liner, which meets strength and permeability criteria. Numerical simulation for five major contaminants shows that the composite plays a crucial role in reducing the leaching of heavy metals and suggests an optimum thickness in the range of 126-154 cm. Overall, the findings of the study indicate that fly ash-bentonite composite can be used to solve real-life challenges in a sustainable way.

QCT/FEA predictions of femoral stiffness are strongly affected by boundary condition modeling.

Quantitative computed tomography-based finite element models of proximal femora must be validated with cadaveric experiments before using them to assess fracture risk in osteoporotic patients. During validation, it is essential to carefully assess whether the boundary condition (BC) modeling matches the experimental conditions. This study evaluated proximal femur stiffness results predicted by six different BC methods on a sample of 30 cadaveric femora and compared the predictions with experimental data. The average stiffness varied by 280% among the six BCs. Compared with experimental data, the predictions ranged from overestimating the average stiffness by 65% to underestimating it by 41%. In addition, we found that the BC that distributed the load to the contact surfaces similar to the expected contact mechanics predictions had the best agreement with experimental stiffness. We concluded that BC modeling introduced large variations in proximal femora stiffness predictions.

Poptube approach for ultrafast carbon nanotube growth.

Microwave irradiation can be used to heat conductive materials and metallocene precursors to initiate ultrafast CNT growth. It takes only 15-30 seconds to grow CNTs at room temperature in air, without the need for any inert gas protection and additional feed stock gases.