Creation of metasurface from vertically aligned carbon nanotubes as versatile platform for ultra-light THz components.

Here a simple and reproducible method for obtaining terahertz metasurfaces formed from multiwall carbon nanotubes (MWCNTs) is presented. The metasurfaces were obtained from a vertically aligned array of MWCNTs using a laser engraving technique followed by polymer covering. The structures under study demonstrate frequency-selective reflection in terahertz range following the Huygens-Fresnel formalism. For a normal incidence of the electromagnetic wave, the model for numerical calculation of backscattering from the metasurfaces was proposed. Lightweight and compact MWCNT-based metasurfaces are capable to replace conventional pyramidal absorbers and could serve as a versatile platform for scalable cost-efficient production of ultra-light electromagnetic components for THz applications.

Carbon nanotube sponges as tunable materials for electromagnetic applications.

The microwave conductivity and permittivity of both single-walled and multi-walled carbon nanotube (SWCNT and MWCNT) sponges were measured while compressing the samples. Compression leads to a huge variation of the absorptance, reflectance, and transmittance of the samples. The dependence of the microwave conductivity on the sponge density follows a power-law relation with exponents 1.7 ± 0.1 and 2.0 ± 0.2 for MWCNT and SWCNT sponges, respectively. These exponents can be decreased slightly by the addition of a non-conducting component which partly electrically separates adjacent tubes within the samples. The conductivity of MWCNT sponge was measured in the terahertz range while heating in air from 300 to 513 K and it increased due to an increase of a number of conducting channels in MWCNTs.

Soft cutting of single-wall carbon nanotubes by low temperature ultrasonication in a mixture of sulfuric and nitric acids.

To decrease single-wall carbon nanotube (SWCNT) lengths to a value of 100-200 nm, aggressive cutting methods, accompanied by a high loss of starting material, are frequently used. We propose a cutting approach based on low temperature intensive ultrasonication in a mixture of sulfuric and nitric acids. The method is nondestructive with a yield close to 100%. It was applied to cut nanotubes produced in three different ways: gas-phase catalysis, chemical vapor deposition, and electric-arc-discharge methods. Raman and Fourier transform infrared spectroscopy were used to demonstrate that the cut carbon nanotubes have a low extent of sidewall degradation and their electronic properties are close to those of the untreated tubes. It was proposed to use the spectral position of the far-infrared absorption peak as a simple criterion for the estimation of SWCNT length distribution in the samples.

Dipole polarizability of onion-like carbons and electromagnetic properties of their composites.

Onion-like carbons (OLC) obtained by thermal transformation of nanodiamonds are agglomerates of multi-shell fullerenes, often covered by an external graphitic mantle. For the present work, elemental OLC units were constructed on the computer by coalescence of several two-layer fullerenes, in a structure similar to carbon peapods with a corrugated external wall. The electrical polarizability of such pod-of-peas fullerenes has been computed by a classical monopole-dipole atomistic theory. The description of pod-of-peas fullerenes was further simplified by representing them as linear arrays of point-like objects, whose polarizability matches that of the starting molecules. Calculations demonstrated that the static polarizability of spherically shaped assemblies of these arrays, modeling real OLC materials, is weakly dependent on the geometry of its constituent molecules and is chiefly proportional to the volume of the whole cluster. It increases with increasing filling fraction of the pod-of-peas fullerenes in the OLC aggregate. The polarizability so obtained can be used in Maxwell-Garnett theory to predict the permittivity of OLC-based composites, at least for static excitations. Experimental results obtained at GHz frequencies reveal a weak attenuation for OLC- and nanodiamond-based polydimethylsiloxane composites. In these silicone composites, we did not find long chains of coupled OLCs. Quite separated clusters were found instead, which contribute little to the polarizability and to the dielectric properties, in good agreement with our theoretical predictions.