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Nanomaterials (Basel) ; 13(14)2023 Jul 10.
Article in English | MEDLINE | ID: mdl-37513051

ABSTRACT

Percolative memristive networks based on self-organized ensembles of silver and gold nanoparticles are synthesized and investigated. Using cyclic voltammetry, pulse and step voltage excitations, we study switching between memristive and capacitive states below the percolation threshold. The resulting systems demonstrate scale-free (self-similar) temporal dynamics, long-term correlations, and synaptic plasticity. The observed plasticity can be manipulated in a controlled manner. The simplified stochastic model of resistance dynamics in memristive networks is testified. A phase field model based on the Cahn-Hilliard and Ginzburg-Landau equations is proposed to describe the dynamics of a self-organized network during the dissolution of filaments.

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