High-accuracy experimental determination of photon mass attenuation coefficients of transition metals and lithium fluoride in the ultra-soft energy range.

In the field of quantitative X-ray analysis techniques, such as electron probe microanalysis, precise knowledge of fundamental parameters is crucial. Especially, the accurate determination of photon mass attenuation coefficients is essential to perform correct elemental quantification. While the widely used databases offer agreement for the hard X-ray range, significant differences arise for lower photon energies. Furthermore, addressing the uncertainties of the tabulated data, which can be of several hundreds of percent, is of urgent need. Driven by recent advances in analytical techniques in the low energy range including investigation of materials containing lithium, the interest in a reliable set of photon mass attenuation coefficients is steadily increasing. In this study, we experimentally determine photon mass attenuation coefficients for lithium fluoride, aluminium, and different transition metals in the extreme low energy range from 40 eV to a several hundreds of eV. This high-precision experimental determination allows a comparison with the existing data tables. We observe differences that turn out to be significant, especially around the absorption edges.

Towards a radon-in-water primary standard at LNHB.

Despite widespread radon-in-water measurements, no primary radon-in-water standards currently exist. This work aims to bridge this gap by developing a system to produce radon-in-water reference materials. The system relies on cryogenic, loss-free transfer of radon, which is standardized through defined solid angle measurements, to a radon standard in water. It allows for preparation of liquid scintillation and gamma-ray spectrometry samples with traceable radon-in-water concentrations. The system's design, functionality, and the results of pilot performance tests are described.

Residual radioactivity of treated green diamonds.

Treated green diamonds can show residual radioactivity, generally due to immersion in radium salts. We report various activity measurements on two radioactive diamonds. The activity was characterized by alpha and gamma ray spectrometry, and the radon emanation was measured by alpha counting of a frozen source. Even when no residual radium contamination can be identified, measurable alpha and high-energy beta emissions could be detected. The potential health impact of radioactive diamonds and their status with regard to the regulatory policy for radioactive products are discussed.

Photon emission intensities in the decay of U-235.

New measurements of photon emission intensities in the decay of U-235 were performed. Source was prepared by deposition of a U-235 solution on glass plate. Standardization was carried out by defined solid angle alpha counting, giving the reference activity with 0.7% relative combined uncertainty. Gamma spectrometry was performed with accurately calibrated high-purity germanium detectors. Corrections for source geometry and coincidence summing effects were applied. The reference line (185.72keV) intensity was obtained with 1.3% relative standard uncertainty.

Application of GUM Supplement 1 to uncertainty of Monte Carlo computed efficiency in gamma-ray spectrometry.

The uncertainty of quantities relevant in gamma-ray spectrometry (efficiency, transfer factor, self-attenuation FA and coincidence summing FC correction factors) is realistically evaluated by Monte Carlo propagation of the distributions characterizing the parameters on which these quantities depend. Probability density functions are constructed and summarized as recommended in the GUM Supplement 1 and compared with the values obtained using the traditional approach (GUM uncertainty framework). Special cases when this approach encounters difficulties (FC uncertainty due to the uncertainty of decay scheme parameters, effect of activity and matrix inhomogeneity on efficiency) are also discussed.

Determination of absolute photon emission intensities of (210)Pb.

Photon emission intensities of (210)Pb have been determined using sources prepared from a standard solution, whose activity was measured by liquid scintillation counting. The absolute γ-ray and X-ray emission intensity was measured by conventional γ-ray spectrometry. Complementary measurements of the L X-ray spectrum were performed using a cryogenic detector, characterized by very high energy resolution and constant detection efficiency. As a result, precise emission intensities of the individual X-ray lines were obtained taking into account the presence of satellite lines.

Measurement of partial L fluorescence yields of bismuth using synchrotron radiation.

Tunable monochromatic photon radiation was used to measure transmission of a bismuth target in the energy range from 7keV to 20keV. Partial L fluorescence yields of bismuth were obtained by combining measurement of the fluorescence induced by photoionization of the bismuth target and X-rays from the radioactive decay of (210)Pb. Several photon energies have been used to successively ionize the L subshells, which allowed detailed analysis of the rearrangement spectra and determination of the X-ray relative intensities of the L1, L2 and L3 series.

Determination of X- and gamma-ray emission intensities in the decay of (131)I.

The activity per unit mass of an iodine-131 solution was absolutely standardized by both the 4πß-γ coincidence method and the 4πγ counting technique. The calibrated solution was used to prepare point sources after a preliminary deposit of AgNO3 to prevent the loss of volatile iodine. Relative and absolute photon emission intensities of 15 sgamma-rays and those of the two K X-rays of xenon were determined by gamma-ray spectrometry, with relative uncertainties of 0.8% for the three main emissions.

Correction to the recommended γ-ray emission intensity of the 255.13 keV photons in the decay of (113)Sn.

The authors provide corrected measured values of the relative γ-ray emission intensity of the 255.13keV photons from the decay of (113)Sn. Consequently, new recommended values of the evaluated relative and absolute γ-ray emission intensity of the 255.13keV photons following the decay of (113)Sn are proposed.

Comparison of digital signal processing modules in gamma-ray spectrometry.

Commercial digital signal-processing modules have been tested for their applicability to gamma-ray spectrometry. The tests were based on the same n-type high purity germanium detector. The spectrum quality was studied in terms of energy resolution and peak area versus shaping parameters, using a Eu-152 point source. The stability of a reference peak count rate versus the total count rate was also examined. The reliability of the quantitative results is discussed for their use in measurement at the metrological level.

On scattering effects for volume sources in low-energy photon spectrometry.

In this study, different aspects of the Compton scattering inside volume sources are illustrated using experimental approach and Monte Carlo simulation. For the low-energy range (below 100 keV) scattered events represents around 30% of the whole spectrum. Influence of the source-detector geometry is discussed. The scattering effects induce strong differences in spectrum shape for different geometrical conditions. This should influence efficiency transfer factors. A new approach is proposed, including the scattered events, to avoid complex peak area determination.

Validation of efficiency transfer for Marinelli geometries.

In the framework of environmental measurements by gamma-ray spectrometry, some laboratories need to characterize samples in geometries for which a calibration is not directly available. A possibility is to use an efficiency transfer code, e.g., ETNA. However, validation for large volume sources, such as Marinelli geometries, is needed. With this aim in mind, ETNA is compared, initially to a Monte Carlo simulation (PENELOPE) and subsequently to experimental data obtained with a high-purity germanium detector (HPGe).

Characterization of a cosmic suppression spectrometer.

In this work, PENELOPE2008 and MCNP5 software packages were used to investigate the effect of simulation parameters such as cut-off energy of photons and electrons on the detector response function and peak escape intensity to assess their influence on the efficiency determination. The results showed a general agreement between the two codes, however both the intensity of escape peaks and total efficiency computed with PENELOPE2008 are higher than those obtained with MCNP5. Moreover, the calculated efficiencies are typically 8% higher than what is experimentally found in the low energy range. Further investigation was required to obtain better agreement and lead to better estimate of the real germanium crystal dimensions and dead layer.

Measurements of relative photon emission intensities and nuclear decay data evaluation of 113Sn.

In the frame of a co-operation between CEA-LIST/LNE-LNHB (France) and IFIN-HH (Romania), the relative intensities of the photon emissions following the (113)Sn decay were accurately determined at the LNHB using high resolution X- and γ-ray spectrometers, characterized by excellent quality efficiency calibrations. Two series of measurements were carried out. The intensity of the 255 keV γ-ray relative to that of the 392 keV γ-ray was determined with an uncertainty lower than 1%. A new (113)Sn nuclear decay data evaluation was accomplished. The main results obtained are presented.

Coincidence summing corrections applied to volume sources.

The numerical calculation of coincidence summing corrections requires both the total and full-energy peak efficiencies to be included in the corrective factors. Moreover, in the case of volume sources, the coincidence probability depends on the position of the photon emission inside the radioactive sample, thus it is necessary to calculate the coincidence summing corrective factors by integrating the elemental contributions for the entire volume. The software ETNA calculates coincidence summing corrective factors according to a deterministic method, for volume sources, two approaches are included in the software: the "simplified" calculation uses directly the efficiency of the volume source like in the case of point source, and the "complete" calculation performs the volume integration. To assess the difference between these, different geometrical cases are tested for several radionuclides using both methods.

Measurement of beta-plus emitters by gamma-ray spectrometry.

The activity measurement of beta-plus emitters by gamma-ray spectrometry is studied. Experimental measurements are performed with (22)Na, (65)Zn and (64)Cu with sources included in a lead container. For these nuclides, the activity can be derived both from one photon emission peak and from the 511 keV annihilation peak, including annihilation in-flight correction and geometry correction computed by Monte Carlo simulation. The activity values obtained using the two types of peaks show satisfying agreement. The extension of the method to volume sources is discussed.

A new determination of 79Se half-life.

A new value of (79)Se half-life was determined by the means of inductively coupled plasma mass spectrometry (ICP-MS) and liquid scintillation counting (LSC) on a sample source isolated from a nuclear reprocessing solution. The procedure used to extract Se from the complex sample solution consisted in liquid-liquid extraction and ion exchange chromatographic methods. The concentration of (79)Se was measured using ICP-MS coupled with electro-thermal vaporisation to eliminate potential isobaric interferences. The activity was measured using LSC after gamma-ray spectrometry to check the contribution of residual radioactive contaminants. From these results, the half-life of (79)Se was found to be 3.77 (19) x 10(5) a.

Experimental validation of coincidence summing corrections computed by the ETNA software.

The ETNA software has been developed to compute efficiency transfer and coincidence summing corrections. Different experiments are combined to test the validity of this last facility. Point sources with multi-gamma emitters are measured at several source-to-detector distances. Experimental correction factors are determined from the variation in the peaks' relative intensities versus the geometrical conditions. The ETNA code is used to compute the corrections due to coincidence summing for the same geometries. The calculated values are compared to the experimental ones.

Determination of the intensity of X- and gamma-ray emissions in the decay of 153Sm.

The activity of a 153Sm solution was determined by means of liquid scintillation counting and an ionization chamber. Several accurately calibrated X- and gamma-ray spectrometers were used to measure point sources. The use of different detectors results in improvements to the accuracy of the data around 100 keV where the efficiency curve changes significantly. Photon emission intensities have been derived for the main X- and gamma-rays, and the 103-keV emission has a measured intensity of (29.07 (20)) per 100 disintegrations.

A tunable monochromatic X-ray source for metrological studies in the 1-20 keV energy range: application to the measurement of attenuation coefficients.

A tunable monochromatic X-ray source operating in the 1-20 keV energy range is described. An X-ray tube provides initial photons. A dispersive crystal performs the energy selection, according to Bragg's law. An X-ray detector is connected to the monochromator fixed exit. This setup can be used for metrological studies. A first application consists in measuring attenuation coefficients in the 4-10 keV energy range. Results for aluminum and copper are given, with average relative uncertainties (1sigma) of 1% and 3% respectively.