Energetic, economic and environmental assessment for the anaerobic digestion of pretreated and codigested press mud.

This study investigates the feasibility of anaerobic digestion (AD) of press mud previously pretreated, using two methods: Liquid Hot Water (LHW) and Thermo-Alkaline (TA), from an economic, energetic and environmental point of view. Two scenarios, a sugar mill with and without distillery were studied, considering monodigestion and vinasse codigestion. The results have shown that the LHW and TA pretreatments are self-sufficient in terms of thermal requirements since they can recover heat from the biogas engine, but the maximum electric and thermal net energy (64 MWh d-1 and 95 MWh d-1, respectively) was obtained during co-digestion with vinasse. The results of the environmental Life Cycle Analysis (LCA) show that the alternatives improve the environmental profiles, in both scenarios. The endpoint impact category "Human health" had the highest contribution because of both: the burning of fossil fuel at refinery to supply the required electricity; and the production of Ca(OH)2 when vinasse was fed. The AD of pretreated press mud by LHW in CSTR reactors was the most viable for the scenario of a sugar mill without distillery, while the alternative co-digestion with the vinasse of the press mud without pretreatment was the most viable for the scenario of a sugar mill with distillery. This research shows that both the environmental and energetic profiles and the profitability of methane production can improve when the pretreatment and co-digestion of these wastes from the sugar - alcohol production process are considered.

Anaerobic co-digestion of sugarcane press mud with vinasse on methane yield.

The conversion efficiency of high solids waste digestion as sugarcane press mud (P) may be limited due to hydrolysis step. The option of co-digestion with vinasse, main liquid waste generated from ethanol production, was investigated under batch regime at mesophilic conditions (37.5±1°C) and the best mixture was evaluated under semicontinuous regime in stirred-tank reactors. The maximum values for methane yield in batch tests were for V75/P25 and V50/P50 mixtures (on basis of the chemical oxygen demand (COD) percentage added in the mixture), with an average value of 246NmL CH4g-1 CODfed, which was 13% higher than that of press mud alone. A highest methane production rate of 69.6NmL CH4g-1 CODfed-1d-1 was obtained for the mixtureV75/P25. During the experiment carried out in CSTR reactors, the organic loading rate (OLR) was increased from 0.5 up to 2.2gVSL-1d-1. Methane yields of 365L CH4 kg-1VS and biogas productivities of 1.6LL-1 were obtained in co-digestion, which was 64% higher in comparison to mono-digestion. The performance of the process in mono-digestion was less stable than in co-digestion, with a significant fall of methane yield to 1.8kgVSm-3d-1, and a partial inhibition of the methanogenic archaeas when the OLR was increased up to 2.2kgVSm-3d-1. The co-digestion of vinasse with press mud is a good option for the treatment of streams at the alcohol-sugar industry.

Effect of liquid hot water pre-treatment on sugarcane press mud methane yield.

Sugarcane press mud was pretreated by liquid hot water (LHW) at different temperatures (140-210 °C) and pre-treatment times (5-20 min) in order to assess the effects on the chemical oxygen demand (COD) solubilisation, inhibitors formation and methane yield. The experimental results showed that a high degree of biomass solubilisation was possible using LHW. Higher methane yields were obtained at lower severities (log(Ro) = 2.17-2.77) with (i) mild temperatures (140-150 °C) and long contact times (12.5 min, 20 min) or (ii) mild temperatures (175 °C) with short contact time (2 min). The highest increase in methane yield (up to 63%) compared to the untreated press mud was found at 150 °C for 20 min. At temperatures of 200 °C and 210 °C, low methane efficiency was attributed to the possible formation of refractory compounds through the Maillard reaction.

Thermo-chemical pre-treatment to solubilize and improve anaerobic biodegradability of press mud.

Different pre-treatment severities by thermo-alkaline conditions (100°C, Ca(OH)2) on press mud were evaluated for different pre-treatment time and lime loading. COD solubilization and the methane yield enhancement were assessed. The biochemical methane potential was determined in batch assays under mesophilic conditions (37±1°C). The best pre-treatment resulted in a surplus of 72% of methane yield, adding 10g Ca(OH)2 100g(-1)TS(-1) for 1h. Pre-treatment also increased the COD solubilization, but the optimal severity for COD solubilization as determined by response surface methodology did not ensure the highest methane production. Inhibitory effects on anaerobic digestion were noticed when the severity was increased. These results demonstrate the relevance of thermo-alkaline pre-treatment severity in terms of both lime loading and pre-treatment time to obtain optimal anaerobic biodegradability of lignocellulosic biomass from press mud.