ABSTRACT
An interactive multimedia tool, Nuclides.net, has been developed at the Institute for Transuranium Elements. The Nuclides.net "integrated environment" is a suite of computer programs ranging from a powerful user-friendly interface, which allows the user to navigate the nuclides chart and explore the properties of nuclides, to various computational modules for decay calculations, dosimetry and shielding calculations, etc. The product is particularly suitable for environmental radioprotection and radioecology. Detailed descriptions of Nuclides.net and some potential applications in radioprotection and radioecology are presented.
Subject(s)
Environmental Monitoring/methods , Radiation Protection/instrumentation , Conservation of Natural Resources , Databases, Factual , Ecology , Internet , Models, Theoretical , Programming Languages , Radiation Dosage , Radiometry , Software , Software Design , Time Factors , User-Computer Interface , WaterABSTRACT
Structural properties of uranyl cations in acidic aqueous perchlorate and triflate solutions were investigated using uranium LIII -edge extended X-ray absorption fine-structure spectroscopy (EXAFS) in conjunction with quantum mechanical calculations of gas-phase model complexes. EXAFS spectra were measured in aqueous solutions of up to 10 M triflic and 11.5 M perchloric acid, as well as mixtures of perchloric acid and sodium perchlorate. In no case is the perchlorate anion coordinated to UO2(2+). The number of equatorial water molecules bound to UO2(2+) is always about five. In the case of the 10 M CF3SO3H solution, an inner-sphere complexation of the triflate is observed with a U-S radial distance of 3.62 Å. These results are in qualitative agreement with quantum mechanical calculations of model uranyl complexes, according to which the interaction energies of anions follow the order perchlorate
