A novel hybrid ferrous sulfide impregnated anion exchanger for trace removal of hexavalent chromium from contaminated water.

To effectively remove trace concentration of potential cancer-causing Cr(VI) from impaired drinking water, a novel hybrid material was synthesized through an in-situ synthesis process by dispersing ferrous sulfide nanoparticles within an anion exchanger. Characterization studies revealed that the hybrid material, named hybrid ferrous sulfide impregnated anion exchanger (HISIIX), contained uniformly distributed ferrous sulfide nanoparticles of size 10-40 nm within the anion exchanger host. Apart from FeS2 nanoparticles, it also included nanoparticles of FeO and FeOOH. The incorporation of ferrous sulfide nanoparticles within the anion exchanger contributed to the significant differences in the Cr(VI) uptake capacity of HISIIX. Validation studies using fixed-bed column proved that HISIIX had significantly high Cr(VI) uptake capacity and was able to run for 4200 bed volumes (BVs) before a breakthrough of 50 µg L-1 when subjected to a synthetic aqueous solution containing 200 µg L-1 Cr(VI). Cr(VI) uptake capacity of the parent anion exchanger and HISIIX were determined to be 1.39 mg g-1 and 3.44 mg g-1, respectively, when the columns were allowed to run until exhaustion. Ferrous sulfide nanoparticles acted as a reducing agent transforming Cr(VI) anions into Cr(III) precipitates. It also produced sites for further removal of Cr(VI) anions through ligand sorption upon oxidation. The anion exchanger substrate attracted anions selectively via the Donnan membrane principle, resulting in a synergy of three different processes - ion exchange, redox reaction, and ligand sorption that gave the HISIIX a high capacity for the selective Cr(VI) removal from contaminated water.

Effective degradation of azo dye from textile wastewater by electro-peroxone process.

Color-producing chemicals emitted from many sources, such as textile or dye manufacturing industries, are a significant concern worldwide. The present study focuses on the electro-peroxone (EP) process for decolorizing a synthetic azo dye, C.I. Reactive Black 5 (RB5). Findings suggest that the EP process is more effective for dye degradation than ozonation and electrolysis. The EP process resulted in 100% decolorization after 60 min of contact time under optimum testing conditions such as pH 7, applied current 300 mA, and sulfate concentration 3.55 g L-1. Based on the findings of the primary investigation, EP treatment of real textile effluent was carried out and 2 h of EP treatment resulted in 99% decolorization and 74%total organic carbon (TOC) removal. As an outcome, the EP process can treat textile wastewater in a cost-effective and environmentally friendly manner.

Conversion of sewage sludge into biochar: A potential resource in water and wastewater treatment.

Production of biochar from sewage sludge (SS) is consistent with the goal of sustainable resource recovery and promotes a wastewater-based circular economy. Thermochemical conversion of SS to biochar resolves two major issues simultaneously as it minimizes the cost of disposal and acts as a resource to eliminate the toxic contaminants from water and wastewater. The reusability and ready availability of the biochar, irrespective of the season, makes it an economically viable material for wastewater treatment. In this review, explicit insights into the production, modification and usage of SS derived biochar are provided including (i) the production yield, (ii) characteristic features such as physical, chemical, electrochemical and morphological aspects, and (iii) impact on contaminant removal through adsorption, catalytic and electrochemical processes. Particular attention is given to the use of SS derived biochar as an adsorbent for contaminants present in wastewaters, the potential use of biochar as a catalyst and support material in advanced oxidation processes and the use of biochars as an electrode material. The effect of pyrolysis conditions and co-pyrolysis with other materials on biochar properties is explored and insight is provided into the toxicity of biochar components present at different process conditions.

Iron impregnated biochars as heterogeneous Fenton catalyst for the degradation of acid red 1 dye.

In the present work, Acid Red 1 (AR1) dye degradation by two heterogeneous Fenton catalysts, namely iron loaded rice husk biochar (Fe-RHB) and coir pith biochar (Fe-CPB) are studied. Biochar prepared from RHB and CPB were sonicated in the presence of ferric nitrate for the synthesis of Fe-RHB and Fe-CPB by incipient impregnation method. Effect of operational parameters such as pH, the dosage of catalyst, H2O2 concentration and temperature were examined. Characterization of the synthesized Fenton catalyst, Fe-RHB and Fe-CPB were analysed by SEM, EDS, XRD and XPS techniques. In Fe-RHB Fenton system, maximum dye removal efficiency of 97.6% and TOC removal efficiency of 84.2% were obtained at pH 3 for 50 mg L-1 of AR1 concentration, with 16 mM of H2O2 and 5 g L-1 of catalyst dosage within 120 min reaction time. Similarly, for Fe-CPB, maximum dye removal efficiency of 99.1% and TOC removal efficiency of 86.7% were obtained with 16 mM of H2O2 and 4 g L-1 of dosage for 50 mg L-1 of initial dye concentration at pH 3. The prepared catalysts can be reused for successive cycles as the catalyst materials are highly stable and have very less iron leaching property.

Iron-loaded mangosteen as a heterogeneous Fenton catalyst for the treatment of landfill leachate.

Iron-loaded mangosteen shell powder (Fe-MSP) was found as an effective heterogeneous Fenton catalyst for the treatment of stabilized landfill leachate. Sonolytically produced catalyst has higher efficiency than other catalysts. At the optimal conditions (pH 3, catalyst concentration of 1,750 mg/L and hydrogen peroxide concentration of 0.26 M), 81 % of the chemical oxygen demand (COD) was removed effectively from the landfill leachate. But, the efficiency of Fe-MSP was reduced in the first recycling due to the poisoning of active sites. A metal leaching study indicated that the degradation of the pollutant is mainly due to solid Fe ions present in Fe-MSP rather than the leached ferrous and ferric ions. Hydroxyl radical production in the system was confirmed by the Fenton oxidation of benzoic acid. Compared to the homogeneous Fenton process, the heterogeneous Fenton process using Fe-MSP had higher COD removal efficiency, indicating the practical applicability of the prepared catalyst.