Efficiency enhancement of ultrathin CIGS solar cells by optimal bandgap grading. Part III: piecewise-homogeneous grading.

In Parts I [Appl. Opt.58, 6067 (2019)APOPAI0003-693510.1364/AO.58.006067] and II [Appl. Opt.61, 10049 (2022)APOPAI0003-693510.1364/AO.474920], we used a coupled optoelectronic model to optimize a thin-film CIGS solar cell with a graded-bandgap photon-absorbing layer, periodically corrugated backreflector, and multilayered antireflection coatings. Bandgap grading of the CIGS photon-absorbing layer was continuous and either linear or nonlinear, in the thickness direction. Periodic corrugation and multilayered antireflection coatings were found to engender slight improvements in the efficiency. In contrast, bandgap grading of the CIGS photon-absorbing layer leads to significant enhancement of efficiency, especially when the grading is continuous and nonlinear. However, practical implementation of continuous nonlinear grading is challenging compared to piecewise-homogeneous grading. Hence, for this study, we investigated piecewise-homogeneous approximations of the optimal linear and nonlinear grading profiles, and found that an equivalent efficiency is achieved using piecewise-homogeneous grading. An efficiency of 30.15% is predicted with a three-layered piecewise-homogeneous CIGS photon-absorbing layer. The results will help experimentalists to implement optimal designs for highly efficient CIGS thin-film solar cells.

Transport of intensity and phase: applications to digital holography [Invited].

We first review transport of intensity and phase and show their use as a convenient tool to directly determine the unwrapped phase of an imaged object, either through conventional imaging or using digital holography. For both cases, either the traditional transport of intensity and phase, or with a modification, viz., electrically controllable transport of intensity and phase, can be used. The use of digital holography with transport of intensity for 3D topographic mapping of fingermarks coated with columnar thin films is shown as an illustrative application of this versatile technique.

Optoelectronic optimization of graded-bandgap thin-film AlGaAs solar cells. Part II: optimal antireflection front-surface texturing.

In Part I [Appl. Opt.59, 1018 (2020)APOPAI0003-693510.1364/AO.381246], we used a coupled optoelectronic model to optimize a thin-film AlGaAs solar cell with a graded-bandgap photon-absorbing layer and a periodically corrugated Ag backreflector combined with localized ohmic Pd-Ge-Au backcontacts, because both strategies help to improve the performance of AlGaAs solar cells. However, the results in Part I were affected by a normalization error, which came to light when we replaced the hybridizable discontinuous Galerkin scheme for electrical computation by the faster finite-difference scheme. Therefore, we re-optimized the solar cells containing an n-AlGaAs photon-absorbing layer with either a (i) homogeneous, (ii) linearly graded, or (iii) nonlinearly graded bandgap. Another way to improve the power conversion efficiency is by using a surface antireflection texturing on the wavelength scale, so we also optimized four different types of 1D periodic surface texturing: (i) rectangular, (ii) convex hemi-elliptical, (iii) triangular, and (iv) concave hemi-elliptical. Our new results show that the optimal nonlinear bandgap grading enhances the efficiency by as much as 3.31% when the n-AlGaAs layer is 400 nm thick and 1.14% when that layer is 2000 nm thick. A hundredfold concentration of sunlight can enhance the efficiency by a factor of 11.6%. Periodic texturing of the front surface on the scale of 0.5-2 free-space wavelengths provides a small relative enhancement in efficiency over the AlGaAs solar cells with a planar front surface; however, the enhancement is lower when the n-AlGaAs layer is thicker.

Thermal hysteresis in scattering by VO2 spheres.

Vanadium dioxide (VO2) transforms from purely monoclinic to purely tetragonal when heated from 58°C to 72°C, and the transformation is reversible but hysteretic. Electromagnetically, VO2 transforms from a dissipative dielectric to another dissipative dielectric if the free-space wavelength is λ0<1100nm; it transforms from a dissipative dielectric to a plasmonic metal (or vice versa) if λ0>1100nm. Calculating the extinction, total scattering, absorption, radiation pressure, backscattering and forward-scattering efficiencies of a VO2 sphere, we found clear signatures of thermal hysteresis in (i) the forward-scattering, backscattering, and absorption efficiencies for λ0<1100nm, and (ii) the forward-scattering, backscattering, total scattering, and absorption efficiencies for λ0>1100nm. Vacuum and null-permittivity quasistates occur between 58°C and 72°C, when tetragonal VO2 is a plasmonic metal, once each on the heating branch and once each on the cooling branch of thermal hysteresis. But none of the six efficiencies show significant differences between the two quasistates.

Transmissive terahertz metasurfaces with vanadium dioxide split-rings and grids for switchable asymmetric polarization manipulation.

Metasurfaces containing arrays of thermally tunable metal-free (double-)split-ring meta-atoms and metal-free grids made of vanadium dioxide (VO[Formula: see text]), a phase-change material can deliver switching between (1) polarization manipulation in transmission mode as well as related asymmetric transmission and (2) other functionalities in the terahertz regime, especially when operation in the transmission mode is needed to be conserved for both phases of VO[Formula: see text]. As the meta-atom arrays function as arrays of metallic subwavelength resonators for the metallic phase of VO[Formula: see text], but as transmissive phase screens for the insulator phase of VO[Formula: see text], numerical simulations of double- and triple-array metasurfaces strongly indicate extreme scenarios of functionality switching also when the resulting structure comprises only VO[Formula: see text] meta-atoms and VO[Formula: see text] grids. More switching scenarios are achievable when only one meta-atom array or one grid is made of VO[Formula: see text] components. They are enabled by the efficient coupling of the geometrically identical resonator arrays/grids that are made of the materials that strongly differ in terms of conductivity, i.e. Cu and VO[Formula: see text] in the metallic phase.

Efficiency enhancement of ultrathin CIGS solar cells by optimal bandgap grading. Part II: finite-difference algorithm and double-layer antireflection coatings.

In Part I [Appl. Opt.58, 6067 (2019)APOPAI003-693510.1364/AO.58.006067], we used a coupled optoelectronic model to optimize a thin-film C u I n 1-ξ G a ξ S e 2 (CIGS) solar cell with a graded-bandgap photon-absorbing layer and a periodically corrugated backreflector. The increase in efficiency due to the periodic corrugation was found to be tiny and that, too, only for very thin CIGS layers. Also, it was predicted that linear bandgap-grading enhances the efficiency of the CIGS solar cells. However, a significant improvement in solar cell efficiency was found using a nonlinearly (sinusoidally) graded-bandgap CIGS photon-absorbing layer. The optoelectronic model comprised two submodels: optical and electrical. The electrical submodel applied the hybridizable discontinuous Galerkin (HDG) scheme directly to equations for the drift and diffusion of charge carriers. As our HDG scheme sometimes fails due to negative carrier densities arising during the solution process, we devised a new, to the best of our knowledge, computational scheme using the finite-difference method, which also reduces the overall computational cost of optimization. An unfortunate normalization error in the electrical submodel in Part I came to light. This normalization error did not change the overall conclusions reported in Part I; however, some specifics did change. The new algorithm for the electrical submodel is reported here along with updated numerical results. We re-optimized the solar cells containing a CIGS photon-absorbing layer with either (i) a homogeneous bandgap, (ii) a linearly graded bandgap, or (iii) a nonlinearly graded bandgap. Considering the meager increase in efficiency with the periodic corrugation and additional complexity in the fabrication process, we opted for a flat backreflector. The new algorithm is significantly faster than the previous algorithm. Our new results confirm efficiency enhancement of 84% (resp. 63%) when the thickness of the CIGS layer is 600 nm (resp. 2200 nm), similarly to Part I. A hundredfold concentration of sunlight can increase the efficiency by an additional 27%. Finally, the currently used 110-nm-thick layer of M g F 2 performs almost as well as optimal single- and double-layer antireflection coatings.

High-throughput DNA sequencing of environmentally insulted latent fingerprints after visualization with nanoscale columnar-thin-film technique.

The goals of this study were to (a) ascertain human identity capabilities of DNA obtained from latent fingerprints that have been first environmentally insulted and then developed by the deposition of a columnar thin film (CTF), and (b) to determine if the CTF process and material are detrimental to single nucleotide polymorphism (SNP) analysis. Fingerprints were deposited on five different types of substrates and aged for one day, 7 days or 30 days while being environmentally insulted under one of the four conditions: 16.6 °C and 60% relative humidity (RH) (Condition A), 24.5 °C and 60% RH (Condition B), 35 °C and 67% RH (Condition C) and a cold condition (Condition D). Then CTF technique was then on 59% of these fingerprints. DNA samples from 805 fingerprints were extracted, quantified, subjected to manual library preparation using the Precision ID Identity Panel, and underwent high-throughput sequencing. The Ion S5™ platform was employed to sequence 124 SNP amplicons. SNPs were successfully sequenced from 802/805 samples. Total read depth was consistent across environmental conditions, and majority of samples had 100% profile completeness and 100% concordance. Anecdotally, libraries that were amplified with a higher cycle number had more 'Major Allele Frequency' flags compared to samples amplified with 23 cycle numbers, possibly due to stochastic effects. Neither the substrates nor the CTF process and materials inhibit downstream DNA analysis. DNA of low quality and quantity from the chosen samples can be sequenced using the Precision ID Identity Panel on the Ion S5™ platform which performed well, however, a different approach may be needed if spurious alleles are suspected.

Enhanced efficiency of graded-bandgap thin-film solar cells due to concentrated sunlight.

A systematic study was performed with a coupled optoelectronic model to examine the effect of the concentration of sunlight on the efficiencies of CIGS, CZTSSe and AlGaAs thin-film solar cells with a graded-bandgap absorber layer. Efficiencies of 34.6% for CIGS thin-film solar cells and 29.9% for CZTSSe thin-film solar cells are predicted with a concentration of 100 suns, the respective one-sun efficiencies being 27.7% and 21.7%. An efficiency of 36.7% is predicted for AlGaAs thin-film solar cells with a concentration of 60 suns, in comparison to 34.5% one-sun efficiency. Sunlight concentration does not affect the per-sun electron-hole-pair (EHP) generation rate but reduces the per-sun EHP recombination rate either near the front and back faces or in the graded-bandgap regions of the absorber layer, depending upon the semiconductor used for that layer, and this is the primary reason for the improvement in efficiency. Other effects include the enhancement of open-circuit voltage, which can be positively correlated to the higher short-circuit current density. Sunlight concentration can therefore play a significant role in enhancing the efficiency of thin-film solar cells.

Magnetically tunable metasurface comprising InAs and InSb pixels for absorbing terahertz radiation.

A magnetically tunable metasurface comprising meta-atoms with InSb-patched, InAs-patched, and unpatched pixels was simulated using commercial software to maximize the absorption of normally incident radiation in the terahertz spectral regime, with the patches decorating the illuminated face of a gold-backed polyimide substrate. Maximum absorptance of 0.99 and minimum absorptance of 0.95 can be obtained in 0.14-0.23-THz-wide bands in the 2-4-THz spectral regime, with an average tuning rate of 0.3THzT-1 and 0.24-THz dynamic range when the controlling magnetostatic field is aligned parallel to the incident electric field. The use of both InSb and InAs patches is much superior to the use of patches of only one of those materials. The design can be adapted for neighboring spectral regimes by exploiting the scale invariance of the Maxwell equations.

Massively parallel sequencing and STR analysis from partial bloody fingerprints enhanced with columnar thin films.

Fingerprint enhancement often includes either physical or chemical approaches, such as fingerprint powder or cyanoacrylate fuming, to improve the quality of a fingerprint for visualization and analysis. However, these methods become more complex when fingerprints are partial bloody, and these procedures may interfere with downstream DNA analysis. Columnar thin film (CTF) deposition is a type of nanotechnology that utilizes an evaporant material to enhance a fingerprint under low-pressure conditions. Short tandem repeat (STR) analysis is the traditional method employed in crime laboratories. When DNA is of poor quality and quantity, like that often obtained from fingerprints, little to no genetic information may be obtained. Single nucleotide polymorphisms (SNPs) may be used to glean additional information when STR analysis fails. In this pilot study, 100 partial bloody fingerprints were collected from two donors and deposited on five different crime scene substrates, in which half were enhanced with CTFs and were graded for quality by an IAI-certified latent fingerprint examiner. CTF-developed fingerprints, on average, had higher grades compared to non-developed partial bloody fingerprints. STR analysis using Fusion 6C was performed to assess inhibition from the evaporant materials, in which no inhibition was observed. Sequencing of SNPs using the Precision ID Identity Panel was also employed, in which genetic information that could not be obtained from STRs was acquired with SNPs. Various sample types (i.e. pristine, low quality, and contaminated) utilized in this project demonstrated the acceptable performance of the Precision ID Identity Panel.

Multiple Rayleigh waves guided by the planar surface of a continuously twisted structurally chiral material.

The Stroh formalism was adapted for Rayleigh-wave propagation guided by the planar traction-free surface of a continuously twisted structurally chiral material (CTSCM), which is an anisotropic solid that is periodically non-homogeneous in the direction normal to the planar surface. Numerical studies reveal that this surface can support either one or two Rayleigh waves at a fixed frequency, depending on the structural period and orientation of the CTSCM. In the case of two Rayleigh waves, each wave possesses a different wavenumber. The Rayleigh wave with the larger wavenumber is more localized to the surface and has a phase speed that changes less as the angular frequency varies in comparison with the Rayleigh wave with the smaller wavenumber.

Two Dyakonov-Voigt surface waves guided by a biaxial-isotropic dielectric interface.

Electromagnetic surface waves guided by the planar interface of an orthorhombic dielectric material and an isotropic dielectric material were analyzed theoretically and numerically. Both naturally occurring minerals (crocoite, tellurite, and cerussite) and engineered materials were considered as the orthorhombic partnering material. In addition to conventional Dyakonov surface waves, the analysis revealed that as many as two Dyakonov-Voigt surface waves can propagate in each quadrant of the interface plane, depending upon the birefringence of the orthorhombic partnering material. The coexistence of two Dyakonov-Voigt surface waves marks a fundamental departure from the corresponding case involving the planar interface of a uniaxial dielectric material and an isotropic dielectric material for which only one Dyakonov-Voigt surface wave is possible. The two Dyakonov-Voigt surface waves propagate in different directions in each quadrant of the interface plane, with different relative phase speeds and different penetration depths. Furthermore, the localization characteristics of the two Dyakonov-Voigt surface waves at the planar interface are quite different: the Dyakonov-Voigt surface wave with the higher relative phase speed is much less tightly localized at the interface in the isotropic dielectric partnering material.

Left/right asymmetry of the dipole field due to reflection from a periodic multilayer of a topological insulator and a columnar thin film.

The problem of a vertical electric dipole radiating above a periodic multilayer whose unit cell comprises a layer of a topological insulator (TI) and a columnar thin film (CTF) was solved in order to investigate the left/right asymmetry of the total electric field in the far zone in the half-space containing the dipole. Occurring in a wide range of the polar observation angle, the left/right asymmetry of Eϕ is due to both the CTFs and the TI layers. Occurring in a narrow range of the polar observation angle, the left/right asymmetry of Eθ is entirely due to the TI layers. For presently available values of the magnitude of the surface admittance γTI of TIs, significant left/right asymmetry occurs if the number of unit cells in the periodic TI/CTF multilayer is high enough.

Optoelectronic optimization of graded-bandgap thin-film AlGaAs solar cells.

An optoelectronic optimization was carried out for an $ {{\rm Al}_\xi }{{\rm Ga}_{1 - \xi }}{\rm As} $AlξGa1-ξAs (AlGaAs) solar cell containing (i) an $ n $n-AlGaAs absorber layer with a graded bandgap and (ii) a periodically corrugated Ag backreflector combined with localized ohmic Pd-Ge-Au backcontacts. The bandgap of the absorber layer was varied either sinusoidally or linearly. An efficiency of 33.1% with the 2000-nm-thick $ n $n-AlGaAs absorber layer is predicted with linearly graded bandgap along with silver backreflector and localized ohmic backcontacts, in comparison to 27.4% efficiency obtained with homogeneous bandgap and a continuous ohmic backcontact. Sinusoidal grading of the bandgap is predicted to enhance the maximum efficiency to 34.5%. Thus, grading the bandgap of the absorber layer, along with a periodically corrugated Ag backreflector and localized ohmic Pd-Ge-Au backcontacts, can help realize ultrathin and high-efficient AlGaAs solar cells for terrestrial applications.

Efficiency enhancement of ultrathin CIGS solar cells by optimal bandgap grading: erratum.

Typographical errors in a few equations in [Appl. Opt.58, 6067 (2019)APOPAI0003-693510.1364/AO.58.006067] are corrected.

Tricontrollable pixelated metasurface for absorbing terahertz radiation.

The incorporation of materials with controllable electromagnetic constitutive parameters allows the conceptualization and realization of controllable metasurfaces. With the aim of formulating and investigating a tricontrollable metasurface for efficiently absorbing terahertz radiation, we adopted a pixel-based approach in which the meta-atoms are biperiodic assemblies of discrete pixels. We patched some pixels with indium antimonide (InSb) and some with graphene, leaving the others unpatched. The bottom of each meta-atom was taken to comprise a metal-backed substrate of silicon nitride. The InSb-patched pixels facilitate the thermal and magnetic control modalities, whereas the graphene-patched pixels facilitate the electrical control modality. With proper configuration of patched and unpatched pixels, and with proper selection of the patching material for each patched pixel, the absorptance spectra of the pixelated metasurface were found to contain peak-shaped features with maximum absorptance exceeding 0.95, full-width-at-half-maximum bandwidth of less than 0.7 THz, and maximum-absorptance frequency lying between 2 THz and 4 THz. The location of the maximum-absorptance frequency can be thermally, magnetically, and electrically controllable. The lack of rotational invariance of the optimal meta-atom adds mechanical rotation as the fourth control modality.

Dyakonov-Voigt surface waves.

Electromagnetic surface waves guided by the planar interface of an isotropic dielectric medium and a uniaxial dielectric medium, both non-dissipative, were considered, the optic axis of the uniaxial medium lying in the interface plane. Whereas this interface is known to support the propagation of Dyakonov surface waves when certain constraints are satisfied by the constitutive parameters of the two partnering mediums, we identified a different set of constraints that allow the propagation of surface waves of a new type. The fields of the new surface waves, named Dyakonov-Voigt (DV) surface waves, decay as the product of a linear and an exponential function of the distance from the interface in the anisotropic medium, whereas the fields of the Dyakonov surface waves decay only exponentially in the anisotropic medium. In contrast to Dyakonov surface waves, the wavenumber of a DV surface wave can be found analytically. Also, unlike Dyakonov surface waves, DV surface waves propagate only in one direction in each quadrant of the interface plane.

Efficiency enhancement of ultrathin CIGS solar cells by optimal bandgap grading.

The power conversion efficiency of an ultrathin CuIn1-ξGaξSe2 (CIGS) solar cell was maximized using a coupled optoelectronic model to determine the optimal bandgap grading of the nonhomogeneous CIGS layer in the thickness direction. The bandgap of the CIGS layer was either sinusoidally or linearly graded, and the solar cell was modeled to have a metallic backreflector corrugated periodically along a fixed direction in the plane. The model predicts that specially tailored bandgap grading can significantly improve the efficiency, with much smaller improvements due to the periodic corrugations. An efficiency of 27.7% with the conventional 2200-nm-thick CIGS layer is predicted with sinusoidal bandgap grading, in comparison to 22% efficiency obtained experimentally with homogeneous bandgap. Furthermore, the inclusion of sinusoidal grading increases the predicted efficiency to 22.89% with just a 600-nm-thick CIGS layer. These high efficiencies arise due to a large electron-hole pair generation rate in the narrow-bandgap regions and the elevation of the open-circuit voltage due to a wider bandgap in the region toward the front surface of the CIGS layer. Thus, bandgap nonhomogeneity, in conjunction with periodic corrugation of the backreflector, can be effective in realizing ultrathin CIGS solar cells that can help overcome the scarcity of indium.

Information Transfer by Near-Infrared Surface-Plasmon-Polariton Waves on Silver/Silicon Interfaces.

Electronic interconnections restrict the operating speed of microelectronic chips as semiconductor devices shrink. As surface-plasmon-polariton (SPP) waves are localized, signal delay and crosstalk may be reduced by the use of optical interconnections based on SPP waves. With this motivation, time-domain Maxwell equations were numerically solved to investigate the transport of information by an amplitude-modulated carrier SPP wave guided by a planar silicon/silver interface in the near-infrared spectral regime. The critical-point model was used for the permittivity of silicon and the Drude model for that of silver. The signal can travel long distances without significant loss of fidelity, as quantified by the Pearson and concordance correlation coefficients. The signal is partially reflected and partially transmitted without significant loss of fidelity, when silicon is terminated by air; however, no transmission occurs when silicon is terminated by silver. The fidelity of the transmitted signal in the forward direction rises when both silicon and silver are terminated by air. Thus, signals can possibly be transferred by SPP waves over several tens of micrometers in microelectronic chips.

Hybrid Nanostructured Porous Silicon-Silver Layers for Wideband Optical Absorption.

As subwavelength nanostructures are receiving increasing attention for photonic and plasmonic applications, we grew nanostructured porous silicon (n-PS) and hybrid n-PS/Ag layers onto silicon substrates and measured their reflection and absorption characteristics as functions of the wavelength, angle of incidence, and polarization state of incident light. The experimental results show that the absorption characteristics of the hybrid n-PS/Ag layer can be controlled by selecting the appropriate combination of its thickness and porosity, together with the density of infiltrant silver nanoparticles. The observed wideband optical absorption characteristics of the hybrid n-PS/Ag layers might be useful in light-harvesting devices and photodetectors, since the overall efficiency will be increased as a result of increased field-of-view for both s- and p-polarization states of incident light.