Tertiary treatment of a mixture of composting and landfill leachates using electrochemical processes.

The study investigated the treatment efficiency of coupled electrocoagulation (EC) and electrooxidation (EO) processes for landfill leachate treatment in batch and continuous mode. The EC process (iron anode and graphite cathode) at 18.2 mA/cm2 for 2.5 min resulted in COD, turbidity, total phosphorus, total coliforms and fecal coliforms removal of 58.1, 72.9, 98.5, 97.9, and 97.2% respectively. Under the same operating conditions, the coupled EC/EO (Ti-Pt anode, bipolar iron electrode, and graphite cathode) processes showed that the COD, turbidity, total phosphorus, total coliforms, and fecal coliforms removal of 56.5%, 78.3%, 96.3%, 97.2% and fecal coliforms 72.7%, respectively. The energy costs associated with the EC and EC/EO were 0.11 and 0.25 $/m3, respectively. Compared to the batch configuration, the continuous configuration of EC resulted in similar processing performance. However, the EC/EO process resulted in the production of chlorates, perchlorates, and trihalomethanes as by-products. Moreover, the continuous process slightly increases the pH and ammonia concentration of the leachate and also resulted in the metallic sludge production with an average dryness of 4.2%. The toxicity tests determined that the treated effluent was not toxic to Rainbow trout and Daphnia.

Effect of cathode material and charge loading on the nitrification performance and bacterial community in leachate treating Electro-MBRs.

Electro-MBR technology, which combines an electrocoagulation process inside the mixed liquor of a membrane bioreactor, was studied for the treatment of a high-strength ammonia leachate (124 ± 4 mg NH4-N L-1). A lab-scale aerobic Electro-MBR was operated with a solid retention time of 45 days, hydraulic retention times of 24h and 12h, and charge loading ranging from 100 to 400 mAh L-1. At 400 mAh L-1, with a combination of a Ti/Pt cathode and a sacrificial iron anode, removal percentages for ammonia nitrogen, total organic carbon, and total phosphorus were 99.8%, 38%, and 99.0%, respectively. At 400 mAh L-1, the estimated ferric ion dosage was 325 mg Fe3+ L-1. Experiments conducted with different cathode materials showed that previously reported inhibition phenomena may result from a cathodic nitrate reduction into ammonia nitrogen. Conventional cathode materials, such as graphite, have electrochemical nitrate reduction rates of -0.03 mg NO3-N mAh-1. By comparison, when using Ti/Pt, the rate was -0.0045 mg NO3-N mAh-1(85% lower than graphite due to its low hydrogen overpotential). Charge loading tested in this study had no significant impact on both nitrification performance and microbial population diversity. However, the relative abundance of the mixed liquor's Nitrosomonas increased from 4.8% to 8.2% when the charge loading increased from 0 to 400 mAh L-1. Results from this study are promising for future applications of the Ti/Pt - Iron Electro-MBR in various high-strength ammonia wastewater treatment applications.

Identifying the link between MBRs' key operating parameters and bacterial community: A step towards optimized leachate treatment.

A MBR treating compost leachate was studied in order to link the operating parameters (solid and hydraulic retention time) to contaminant's specific bacterial catabolic activity. In this context, a lab-scale aerobic membrane bioreactor was operated for 200 days, at solid retention times (SRT) of 30 and 45 days and four different contaminant load rates. Results showed that increasing the food to microorganism ratio (F/M) by increasing the contaminant load rates lessened the selectivity pressure, which allowed the proliferation of subdominant operational taxonomic units (OTU) (relative abundance >3%) that were otherwise inhibited by highly adapted dominant OTUs (relative abundance >10%). Subsequently, increasing the SRT resulted in a lower species richness and the selection of two dominant types of bacteria: 1) genera with low growth rates that feed on non-limiting substrates or substrates with few competitors, and 2) genera with metabolisms that are highly specific to the available substrates and that can outcompete the other genera by using the substrate more efficiently. The bacterial population evolution observed during this study suggests that the mixed liquor population diversity and structure can be modulated with the operating conditions for the bioenhancement of contaminant specific catabolic activity. Identified dominant and subdominant genera were linked to the MBR's NH4+ and COD removal performances. Interestingly, nitrification performances were unaffected by the organic load rate and the Nitrosomonas relative abundance.

MBR treatment of leachates originating from waste management facilities: A reference study of the design parameters for efficient treatment.

The main objective of the study was to define the interaction between the solid retention time (SRT) and the contaminant loading rate on a membrane bioreactor's efficacy in removing contaminants frequently detected (chemical oxygen demand (COD), NH4+, total phosphorus and metals) above the discharge criteria in waste-originating leachates. The rates and coefficient calculated from this study's experimental data can be used for the design of membrane bioreactor treating wastewaters, even beyond the scope of this experiment. Over a period of 152 days, SRTs of 28 and 47 days and HRTs of 13, 25, 36 and 52 h were studied using a real leachate with a constant composition. Results showed that membrane bioreactors can efficiently treat >1850 mg COD L-1 d-1 of highly to moderately biodegradable COD, with the SRT having no significant impact on the removal of recalcitrant COD. Overall ammonium removal rates of >740 mg NH4-N L-1 d-1 can be achieved as long as a residual alkalinity of 200 mg CaCO3 L-1 and an adequate dissolved oxygen concentration (6-7 mg L-1) are both maintained. Overall phosphorus removal rates are independent of the phosphorus loading rate. However, the highest overall phosphorus removal rate (39 ± 2 mg P per g of total suspended solids) was obtained at the lowest SRT (28 days) due to an increased extracellular polymeric substance production. Finally, membrane bioreactor's metal removal capacity is mostly dependent on the metals' affinity to both the leachate's recalcitrant COD as well as sludge concentrations.