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1.
Water Res ; 259: 121750, 2024 Aug 01.
Article in English | MEDLINE | ID: mdl-38851115

ABSTRACT

Phosphorus (P) discharge from agricultural and urban drainage is known for causing downstream eutrophication worldwide. Agricultural best management practices that are designed to reduce P load out of farms target different P species from various sources such as fertilizers leaching and farm soil and canal sediment erosion, however, few studies have assessed the impact of floating aquatic vegetation (FAV) on canal sediment and farm drainage water quality. This study evaluated the impact of FAVs on canal sediment properties and P water quality in drainage canals in the Everglades Agricultural Area in south Florida, USA. Non-parametric statistical methods, correlation analysis, trend analysis and principal component analysis (PCA) were used to determine the relationship between FAV coverage with sediment properties and P water quality parameters. Results showed that FAV coverage was correlated with the highly recalcitrant and most stable form of P in the sediment layer (Residual P Pool). FAV coverage also correlated with the dissolved organic P (DOP) which was the smallest P pool (7 %) of total P concentration in drainage water, therefore FAV coverage had no correlation with farm P load. The trend analysis showed no trend in farm P loads, despite a decline in FAV coverage at farm canals over an 8-year period. Phosphorus content in the sediment surface layer was strongly associated with farm P load and had a significant correlation with particulate P (PP) and soluble reactive P (SRP) which constituted 47 % and 46 % of the total P concentration in the drainage water, respectively. Equilibrium P concentration assays also showed the potential to release SRP from the sediment layer. The P budget established for this study reveals that sediment stores the largest P mass (333 kg P), while FAVs store the smallest P mass (8 kg P) in a farm canal, highlighting the significant contribution of canal sediment to farm P discharges. Further research is required to evaluate the impact of sediment removal and canal maintenance practices that help reduce farm P discharges.


Subject(s)
Agriculture , Geologic Sediments , Phosphorus , Phosphorus/analysis , Florida , Geologic Sediments/chemistry , Water Pollutants, Chemical/analysis , Environmental Monitoring
3.
Earth Space Sci ; 8(8): e2021EA001803, 2021 Aug.
Article in English | MEDLINE | ID: mdl-34595328

ABSTRACT

A new automated method to retrieve charge layer polarity from flashes, named Chargepol, is presented in this paper. Using data from the NASA Lightning Mapping Array (LMA) deployed during the Remote sensing of Electrification, Lightning, And Mesoscale/microscale Processes with Adaptive Ground Observations (RELAMPAGO) field campaign in Cordoba, Argentina, from November 2018 to April 2019, this method estimates the polarity of vertical charge distributions and their altitudes and thicknesses (or vertical depth) using the very-high frequency (VHF) source emissions detected by LMAs. When this method is applied to LMA data for extended periods of time, it is capable of inferring a storm's bulk electrical charge structure throughout its life cycle. This method reliably predicted the polarity of charge within which lightning flashes propagated and was validated in comparison to methods that require manual assignment of polarities via visual inspection of VHF lightning sources. Examples of normal and anomalous charge structures retrieved using Chargepol for storms in Central Argentina during RELAMPAGO are presented for the first time. Application of Chargepol to five months of LMA data in Central Argentina and several locations in the United States allowed for the characterization of the charge structure in these regions and for a reliable comparison using the same methodology. About 13.3% of Cordoba thunderstorms were defined by an anomalous charge structure, slightly higher than in Oklahoma (12.5%) and West Texas (11.1%), higher than Alabama (7.3%), and considerably lower than in Colorado (82.6%). Some of the Cordoba anomalous thunderstorms presented enhanced low-level positive charge, a feature rarely if ever observed in Colorado thunderstorms.

5.
PLoS One ; 15(1): e0227489, 2020.
Article in English | MEDLINE | ID: mdl-31929553

ABSTRACT

Particle size is one factor affecting phosphorus (P) dynamics in soils and sediments. This study investigated how flow facilitated by hydraulic pumps and aquatic vegetation species water lettuce (Pistia stratiotes) and water hyacinth (Eichhornia crassipes) affected particle size and P-dynamics in organic sediments in agricultural drainage ditches. Sediments with finer particle size (>0.002 mm) were hypothesized to contain greater total P (TP) and less labile P than sediments with coarser particle size. Particle size was determined using a LS 13 320 Laser Diffraction Particle Size Analyzer. Sediments were tested for pH, TP, and organic matter. Fractions of P were determined using a sequential fractionation experiment and 31P Nuclear Magnetic Resonance (NMR) Spectroscopy. Larger average particle size and lower average total P concentrations were found in the inflows of the field ditches compared to the outflows. Presence of flow and aquatic vegetation did not have a significant impact on particle size, TP, or labile P fractions. Median (p = 0.10) particle size was not significantly correlated to TP. Overall, there was an average trend of coarser particle size and lower P concentrations in the inflow compared to the outflow. The presence of inorganic limerock could have affected results due to increased P adsorption capacity and larger average particle size compared to the organic fraction of the sediment.


Subject(s)
Agriculture , Geologic Sediments/chemistry , Phosphorus/chemistry , Hyacinthus/growth & development , Hydrogen-Ion Concentration , Lactuca/growth & development , Magnetic Resonance Spectroscopy , Organic Chemicals/chemistry , Particle Size , Soil/chemistry , Water Movements
6.
Sci Rep ; 8(1): 8782, 2018 Jun 08.
Article in English | MEDLINE | ID: mdl-29884899

ABSTRACT

A constellation of small, low-cost satellites is able to make scientifically valuable measurements of the Earth which can be used for weather forecasting, disaster monitoring, and climate studies. Eight CYGNSS satellites were launched into low Earth orbit on December 15, 2016. Each satellite carries a science radar receiver which measures GPS signals reflected from the Earth surface. The signals contain information about the surface, including wind speed over ocean, and soil moisture and flooding over land. The satellites are distributed around their orbit plane so that measurements can be made more often to capture extreme weather events. Innovative engineering approaches are used to reduce per satellite cost, increase the number in the constellation, and improve temporal sampling. These include the use of differential drag rather than propulsion to adjust the spacing between satellites and the use of existing GPS signals as the science radars' transmitter. Initial on-orbit results demonstrate the scientific utility of the CYGNSS observations, and suggest that a new paradigm in spaceborne Earth environmental monitoring is possible.

7.
J Geophys Res Atmos ; 123(4): 2347-2367, 2018 Feb 27.
Article in English | MEDLINE | ID: mdl-29910996

ABSTRACT

This study examined 34 lightning flashes within four separate thundersnow events derived from lightning mapping arrays (LMAs) in northern Alabama, central Oklahoma, and Washington DC. The goals were to characterize the in-cloud component of each lightning flash, as well as the correspondence between the LMA observations and lightning data taken from national lightning networks like the National Lightning Detection Network (NLDN). Individual flashes were examined in detail to highlight several observations within the dataset. The study results demonstrated that the structures of these flashes were primarily normal polarity. The mean area encompassed by this set of flashes is 375 km2, with a maximum flash extent of 2300 km2, a minimum of 3 km2, and a median of 128 km2. An average of 2.29 NLDN flashes were recorded per LMA-derived lightning flash. A maximum of 11 NLDN flashes were recorded in association with a single LMA-derived flash on 10 January 2011. Additionally, seven of the 34 flashes in the study contain zero NLDN identified flashes. Eleven of the 34 flashes initiated from tall human-made objects (e.g., communication towers). In at least six lightning flashes, the NLDN detected a return stroke from the cloud back to the tower and not the initial upward leader. This study also discusses lightning's interaction with the human built environment and provides an example of lightning within heavy snowfall observed by GOES-16's Geostationary Lightning Mapper.

8.
J Atmos Ocean Technol ; 35(No 1): 35-55, 2018 Jan.
Article in English | MEDLINE | ID: mdl-29805195

ABSTRACT

Tropical convection during the onset of two Madden-Julian oscillation (MJO) events, in October and December of 2011, was simulated using the Weather Research and Forecasting (WRF) Model. Observations from the Dynamics of the MJO (DYNAMO) field campaign were assimilated into the WRF Model for an improved simulation of the mesoscale features of tropical convection. The WRF simulations with the assimilation of DYNAMO data produced realistic representations of mesoscale convection related to westerly wind bursts (WWBs) as well as downdraft-induced gust fronts. An end-to-end simulator (E2ES) for the Cyclone Global Navigation Satellite System (CYGNSS) mission was then applied to the WRF dataset, producing simulated CYGNSS near-surface wind speed data. The results indicated that CYGNSS could detect mesoscale wind features such as WWBs and gust fronts even in the presence of simulated heavy precipitation. This study has two primary conclusions as a consequence: 1) satellite simulators could be used to examine a mission's capabilities for accomplishing secondary tasks and 2) CYGNSS likely will provide benefits to future tropical oceanic field campaigns that should be considered during their planning processes.

9.
J Vis Exp ; (129)2017 11 07.
Article in English | MEDLINE | ID: mdl-29155744

ABSTRACT

The purpose of this study is to describe the methods used to capture flow-weighted water and suspended particulates from farm canals during drainage discharge events. Farm canals can be enriched by nutrients such as phosphorus (P) that are susceptible to transport. Phosphorus in the form of suspended particulates can significantly contribute to the overall P loads in drainage water. A settling tank experiment was conducted to capture suspended particulates during discrete drainage events. Farm canal discharge water was collected in a series of two 200 L settling tanks over the entire duration of the drainage event, so as to represent a composite subsample of the water being discharged. Imhoff settling cones are ultimately used to settle out the suspended particulates. This is achieved by siphoning water from the settling tanks via the cones. The particulates are then collected for physico-chemical analyses.


Subject(s)
Agriculture/methods , Drainage/methods , Environmental Monitoring/methods , Particulate Matter/chemistry , Water Pollutants, Chemical/chemistry , Phosphorus/chemistry , Suspensions/chemistry , Water Movements
10.
Bull Am Meteorol Soc ; 98(6): 1153-1168, 2017 Jun.
Article in English | MEDLINE | ID: mdl-28111477

ABSTRACT

A World Meteorological Organization weather and climate extremes committee has judged that the world's longest reported distance for a single lightning flash occurred with a horizontal distance of 321 km (199.5 mi) over Oklahoma in 2007, while the world's longest reported duration for a single lightning flash is an event that lasted continuously for 7.74 seconds over southern France in 2012. In addition, the committee has unanimously recommended amendment of the AMS Glossary of Meteorology definition of lightning discharge as a "series of electrical processes taking place within 1 second" by removing the phrase "within one second" and replacing with "continuously." Validation of these new world extremes (a) demonstrates the recent and on-going dramatic augmentations and improvements to regional lightning detection and measurement networks, (b) provides reinforcement regarding the dangers of lightning, and

11.
J Geophys Res Atmos ; 122(18): 9668-9684, 2017 Sep 27.
Article in English | MEDLINE | ID: mdl-29333358

ABSTRACT

The seasonal and diurnal cycles of ocean vector winds in the domain of the South China Sea are characterized and compared using RapidScat and the Cross-Calibrated Multi-Platform (CCMP) data sets. Broad agreement in seasonal flow patterns exists between these data sets during the year 2015. Both observe the dramatic reversal from wintertime trade winds (November-April) to westerly flow associated with the summer monsoon (May-October). These seasonal changes have strong but not equivalent effects on mean wind divergence patterns in both data sets. Specifically near the Philippines, the data sets agree on several aspects of the seasonal mean and diurnal cycle of near-surface vector winds and divergence. In particular, RapidScat and CCMP agree that daytime onshore and nocturnal offshore flow patterns affect the diurnal cycle of winds up to ~200 km west of Luzon, Philippines. Observed disagreements over the diurnal cycle are explainable by measurement uncertainty, as well as shortcomings in both data sets.

12.
Adv Clin Chem ; 63: 211-45, 2014.
Article in English | MEDLINE | ID: mdl-24783355

ABSTRACT

Hypoglycemia in the pediatric population is a common finding important to recognize and manage to prevent brain injury. Recent advances in molecular genetics have provided new insight into its biochemical and physiologic basis and have led to more appropriate and specific treatment. Although a major cause of brain injury in pediatrics, the ability to predict the long-term outcome in these patients remains difficult. Identification of these at-risk individuals is important. The physiologic adaptations associated with transition from fetal to neonatal life are now better understood thus allowing for improved surveillance and management. Despite these advances, analytical limitations of point-of-care testing instruments at low glucose concentration continue to persist, This review aims to address these questions and provide an overview of pediatric hypoglycemia and the molecular pathways involved.


Subject(s)
Hypoglycemia/diagnosis , Child , Homeostasis , Humans , Hypoglycemia/genetics , Hypoglycemia/metabolism , Infant, Newborn , Point-of-Care Systems
13.
Ann Clin Biochem ; 48(Pt 3): 200-11, 2011 May.
Article in English | MEDLINE | ID: mdl-21478208

ABSTRACT

Identification and investigation of hypoglycaemia in childhood remains an important clinical emergency. Rapid recognition and appropriate management of this clinical state continues to be important in order to prevent neurological damage or even death. The purpose of this review is to provide an update on the advances made in this area since the review by Bonham in this journal in 1993. Advances in molecular science and diagnostic techniques have assisted in understanding the mechanisms involved in the homeostasis of glucose metabolism at rest and when stressed. New disorders causing hypoglycaemia are described using the classification based upon aetiologies, which was used in Bonham's original paper. The development and use of guidelines and pre-assembled packs for investigating hypoglycaemia is also discussed.


Subject(s)
Hypoglycemia , Child , Clinical Laboratory Techniques , Glucose/biosynthesis , Glucose/metabolism , Glycogen/metabolism , Homeostasis , Humans , Hypoglycemia/chemically induced , Hypoglycemia/metabolism , Ketone Bodies/metabolism
14.
J Environ Qual ; 39(5): 1751-61, 2010.
Article in English | MEDLINE | ID: mdl-21043280

ABSTRACT

Water flow and P dynamics in a low-relief landscape manipulated by extensive canal and ditch drainage systems were modeled utilizing an ontology-based simulation model. In the model, soil water flux and processes between three soil inorganic P pools (labile, active, and stable) and organic P are represented as database objects. And user-defined relationships among objects are used to automatically generate computer code (Java) for running the simulation of discharge and P loads. Our objectives were to develop ontology-based descriptions of soil P dynamics within sugarcane- (Saccharum officinarum L.) grown farm basins of the Everglades Agricultural Area (EAA) and to calibrate and validate such processes with water quality monitoring data collected at one farm basin (1244 ha). In the calibration phase (water year [WY] 99-00), observed discharge totaled 11,114 m3 ha(-1) and dissolved P 0.23 kg P ha(-1); and in the validation phase (WY 02-03), discharge was 10,397 m3 ha(-1) and dissolved P 0.11 kg P ha(-). During WY 99-00 the root mean square error (RMSE) for monthly discharge was 188 m3 ha(-1) and for monthly dissolved P 0.0077 kg P ha(-1); whereas during WY 02-03 the RMSE for monthly discharge was 195 m3 ha(-1) and monthly dissolved P 0.0022 kg P ha(-1). These results were confirmed by Nash-Sutcliffe Coefficient of 0.69 (calibration) and 0.81 (validation) comparing measured and simulated P loads. The good model performance suggests that our model has promise to simulate P dynamics, which may be useful as a management tool to reduce P loads in other similar low-relief areas.


Subject(s)
Phosphorus/analysis , Saccharum/chemistry , Florida
15.
J Rural Health ; 25(3): 309-13, 2009.
Article in English | MEDLINE | ID: mdl-19566618

ABSTRACT

CONTEXT: Access to psychiatric services, particularly inpatient psychiatric care, is limited and lacks comprehensiveness in rural areas. PURPOSE: The purpose of this study was to evaluate the impact on readmission rates of a multifaceted inpatient psychiatry approach (MIPA) offered in a rural hospital. METHODS: Readmissions within 30 days of patients who were admitted to an inpatient psychiatric unit using a MIPA model of care (N = 147) were compared to readmissions of a comparison group of patients who were admitted prior to the adoption of the MIPA (N = 37). Case mix differences were adjusted using multiple logistic regression analysis (N = 184). FINDINGS: Patients treated in the MIPA model of care had lower odds of readmission within 30 days (odds ratio 0.14, 95% CI 0.02-0.87, P < .03). CONCLUSIONS: Effective inpatient psychiatric care can be provided in rural hospitals.


Subject(s)
Mental Health Services , Patient Readmission/trends , Patients/psychology , Adult , Female , Health Services Accessibility , Hospitals, Rural , Humans , Male , Medical Audit , Mental Health Services/statistics & numerical data , Odds Ratio , Retrospective Studies
16.
J Environ Qual ; 38(4): 1683-93, 2009.
Article in English | MEDLINE | ID: mdl-19549945

ABSTRACT

A mandatory best management practices (BMP) program was implemented in the Everglades Agricultural Area (EAA) farms basin-wide in 1995 as required by the Everglades Forever Act to reduce P loads in drainage water reaching the Everglades ecosystem. All farms in the EAA basin implement similar BMPs, and basin wide P load reductions have exceeded the 25% reduction required by law; however, differences remain in water quality between subbasins. Our objective was to determine long-term trends in P loads in discharge water in the EAA after implementing BMPs for 7 to10 yr and to explore reasons for differences in the performance of the subbasins. Two monitoring datasets were used, one from 10 research farms and the second from the EAA basin inflow and outflow locations. Mann-Kendall trend analysis was used to determine the degree of change in water quality trends. A decreasing trend in P loads was observed in general on sugarcane (Saccharum officinarum L.) farms, while mixed crop farms showed either decreasing or insignificant trends. The insignificant trends are probably related to management practices of mixed crop systems. Decreasing trends in P loads were observed in the outflow of the EAA basin, S5A, and S8 subbasins from 1992 to 2002. Inflow water from Lake Okeechobee had increasing P concentration from 1992 to 2006 with the highest trend in the east side of the lake. This analysis indicated there may be other factors impacting the success of BMPs in individual farms including cropping rotations and flooding of organic soils. Elevated P concentrations in Lake Okeechobee water used for irrigation may pose a future risk to degrade water quality on farms in the EAA, especially in the S5A subbasin.


Subject(s)
Conservation of Natural Resources , Water , Crops, Agricultural , Florida
17.
Ann Clin Biochem ; 45(Pt 5): 486-8, 2008 Sep.
Article in English | MEDLINE | ID: mdl-18753421

ABSTRACT

BACKGROUND: A protocol exists for the collection of samples to investigate unexplained hypoglycaemia, termed the 'hypopack'. These packs are kept in Accident and Emergency departments and neonatal special care baby units throughout Northern Ireland and most wards of the Regional Children's Hospital. A retrospective audit of 107 hypopacks received between July 2001 and December 2003 highlighted a number of problems: samples collected when the patient was receiving dextrose, incomplete clinical history provided, insufficient and haemolysed samples received and poor filing of reports in charts. These were addressed by re-designing the request form, updating the protocol and introducing a summative report. The new protocol was introduced in April 2006. METHODS: The aim of this study is to assess whether the revised protocol improved utility of the hypopack. A retrospective re-audit of 100 hypopacks received between April 2006 and May 2007 was performed. RESULTS: Forty-nine percent of patients were hypoglycaemic (<2.6 mmol/L) compared with 35% in the original audit. In both audits, 33% of laboratory reports were missing from patients' charts. One case of medium-chain acyl-CoA dehydrogenase deficiency, three cases of hyperinsulinism and two endocrine-related cases were identified. CONCLUSIONS: The new hypopack protocol has increased the number of appropriately performed investigations. Provision of information concerning dextrose infusion has assisted the interpretation of the hypopack results.


Subject(s)
Chemistry, Clinical/methods , Hypoglycemia/blood , Hypoglycemia/diagnosis , Acute Disease , Blood Glucose/metabolism , Clinical Protocols , Female , Humans , Hyperinsulinism/diagnosis , Infant , Infant, Newborn , Male , Northern Ireland , Quality Indicators, Health Care , Quality of Health Care , Retrospective Studies
18.
J Environ Qual ; 35(1): 141-50, 2006.
Article in English | MEDLINE | ID: mdl-16391285

ABSTRACT

Specific conductance in farm canals of the Everglades Agricultural Area (EAA) in south Florida is an important water quality parameter that was categorized as a parameter of concern according to an observed frequency of >5% excursions over the Class III water quality criterion and needed to be addressed as a part of the Everglades Regulatory Program. This study was conducted to evaluate specific conductance in farm canals of the EAA. Specific conductance was monitored at 10 representative farms (a total of 12 pump stations) in the EAA using multi-parameter water quality data loggers, for periods ranging from 24 to 83 mo. Cation and anion concentrations were also determined. Nonparametric Mann-Kendall trend analyses and Sen's slope analysis of specific conductance were conducted to determine specific conductance trends. Mean specific conductance ranged from 0.74 to 1.68 dS m(-1) and only 2 of the 10 farms were above the State Class III water quality criterion of 1.275 dS m(-1). Statistically significant downward trends were observed at 3 of the 10 farms. Determination of ion compositions in grab samples at 8 of the 10 farms indicated that the major ions contributing to the increase in specific conductance in the EAA were Cl-, HCO3-, and Na+. Mean Na/Cl ratios in most of the EAA canals ranged from 0.57 to 0.78, whereas those of SO4/Cl ranged from 0.46 to 0.98. Investigation of historical data and literature indicates that elevated specific conductance in parts of the EAA is a natural phenomenon due to entrapment of connate seawater in the Everglades formation. Sulfur contributes minor increases in specific conductance in the EAA with probable sources from organic soil mineralization, ground water, Lake Okeechobee, and S fertilizers.


Subject(s)
Agriculture , Electric Conductivity , Water/chemistry , Florida , Ions
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