Different Scenarios of Autonomous Operation of an Environmental Sensor Node Using a Piezoelectric-Vibration-Based Energy Harvester.

This paper delves into the application of vibration-based energy harvesting to power environmental sensor nodes, a critical component of modern data collection systems. These sensor nodes play a crucial role in structural health monitoring, providing essential data on external conditions that can affect the health and performance of structures. We investigate the feasibility and efficiency of utilizing piezoelectric vibration energy harvesters to sustainably power environmental wireless sensor nodes on the one hand. On the other hand, we exploit different approaches to minimize the sensor node's power consumption and maximize its efficiency. The investigations consider various sensor node platforms and assess their performance under different voltage levels and broadcast frequencies. The findings reveal that optimized harvester designs enable real-time data broadcasting with short intervals, ranging from 1 to 3 s, expanding the horizons of environmental monitoring, and show that in case the system includes a battery as a backup plan, the battery's lifetime can be extended up to 9 times. This work underscores the potential of vibration energy harvesting as a viable solution for powering sensor nodes, enhancing their autonomy, and reducing maintenance costs in remote and challenging environments. It opens doors to broader applications of sustainable energy sources in environmental monitoring and data collection systems.

Fiber-based optrode with microstructured fiber tips for controlled light delivery in optogenetics.

Objective.Optogenetic modulation of neuronal activity requires precise and flexible light delivery to deep brain regions. Flat cleaved optical fibers combined with electrodes are widely used in implantable optogenetic devices for light delivery and electrical monitoring of neural activity. However, the flat fiber tip geometry induces serious tissue damage upon insertion, and makes it difficult to adjust and control the spatial extent of illumination within the brain. With their strongly increased tissue-compatibility and the possibility of spatial illumination control, tapered fibers outperform cleaved fibers in targeted neural photo-stimulation.Approach.In this work, we describe our device concept, and present a novel approach for reproducible fabrication of tapered fiber tips via grinding. Furthermore, we characterize recording electrodes by commenting data obtained from electrochemical impedance spectroscopy (EIS). We also investigate the impact of different cone angles (14°, 30°, 60°, and 90°) on the illumination profile and optical throughput.Main results. We fabricated a fiber-based optrode with cone tip and two deposited electrodes. Custom grinding setup for fabrication of tapered fiber tips with various cone angles is developed as a part of our research. Microscope images showed very good optical quality of cone tips. The results of transmitted optical power measurements performed with integrating sphere suggest that, compared to the flat cleaved optical fiber, transmitted power decreases exponentially with cone angle reduction. Obtained emission profiles (as induced fluorescence in Rhodamine 6G water solution) indicate very strong effect of cone angle on shape and size of illumination volume. Results obtained from EIS show the effect of electrode size on its recording capability.Significance. Compared to optrodes with flat cleaved optical fiber, the demonstrated fiber-based optrode with cone tip allows controlled light delivery with reduced invasiveness. The possibility to fabricate reproducible fiber tips with various cone angles enables control of light delivery in optogenetic experiment. The results presented here give neuroscientists the possibility to choose the appropriate tissue-compatible cone geometry depending on their stimulation requirements.

Analysis and Characterization of Optimized Dual-Frequency Vibration Energy Harvesters for Low-Power Industrial Applications.

We present a multiresonant vibration energy harvester designed for ultra-low-power applications in industrial environments together with an optimized harvester design. The proposed device features dual-frequency operation, enabling the harvesting of energy over a wider operational frequency range. It has been designed such that its harvesting bandwidth range is [50, 100] Hz, which is a typical frequency range for vibrations found in industrial applications. At an excitation level of 0.5 g, a maximum mean power output of 6 mW and 9 mW can be expected at the resonance frequencies of 63.3 and 76.4 Hz, respectively. The harvester delivers a power density of 492 µW/cm2. Design optimization led to improved harvester geometries yielding up to 2.6 times closer resonance frequencies, resulting in a wider harvesting bandwidth and a significantly higher power output.

System-Level Model and Simulation of a Frequency-Tunable Vibration Energy Harvester.

In this paper, we present a macroscale multiresonant vibration-based energy harvester. The device features frequency tunability through magnetostatic actuation on the resonator. The magnetic tuning scheme uses external magnets on linear stages. The system-level model demonstrates autonomous adaptation of resonance frequency to the dominant ambient frequencies. The harvester is designed such that its two fundamental modes appear in the range of (50,100) Hz which is a typical frequency range for vibrations found in industrial applications. The dual- frequency characteristics of the proposed design together with the frequency agility result in an increased operative harvesting frequency range. In order to allow a time-efficient simulation of the model, a reduced order model has been derived from a finite element model. A tuning control algorithm based on maximum-voltage tracking has been implemented in the model. The device was characterized experimentally to deliver a power output of 500 µW at an excitation level of 0.5 g at the respected frequencies of 63.3 and 76.4 Hz. In a design optimization effort, an improved geometry has been derived. It yields more close resonance frequencies and optimized performance.

Facile Fabrication of Bio- and Dual-Functional Poly(2-oxazoline) Bottle-Brush Brush Surfaces.

Poly(2-oxazoline)s (POx) bottle-brush brushes have excellent biocompatible and lubricious properties, which are promising for the functionalization of surfaces for biomedical devices. Herein, a facile synthesis of POx is reported which is based bottle-brush brushes (BBBs) on solid substrates. Initially, backbone brushes of poly(2-isopropenyl-2-oxazoline) (PIPOx) were fabricated via surface initiated Cu0 plate-mediated controlled radical polymerization (SI-Cu0 CRP). Poly(2-methyl-2-oxazoline) (PMeOx) side chains were subsequently grafted from the PIPOx backbone via living cationic ring opening polymerization (LCROP), which result in ≈100 % increase in brush thickness (from 58 to 110 nm). The resultant BBBs shows tunable thickness up to 300 nm and high grafting density (σ) with 0.42 chains nm-2 . The synthetic procedure of POx BBBs can be further simplified by using SI-Cu0 CRP with POx molecular brush as macromonomer (Mn =536 g mol-1 , PDI=1.10), which results in BBBs surface up to 60 nm with well-defined molecular structure. Both procedures are significantly superior to the state-of-art approaches for the synthesis of POx BBBs, which are promising to design bio-functional surfaces.

Magnetic Frequency Tuning of a Multimodal Vibration Energy Harvester.

In this paper, we present a novel vibration-based piezoelectric energy harvester, capable of collecting power at multiple operating frequencies and autonomously adapting itself to the dominant ambient frequencies. It consists of a compact dual-frequency resonator designed such that the first two fundamental natural frequencies are in the range of [50, 100] Hz, which is a typical frequency range for ambient vibrations in industrial environments. A magnetic frequency-tuning scheme is incorporated into the structure, which enables the frequency agility of the system. In contrast to single frequency harvesters, the presented approach combines multi-resonance and frequency tunability of both modes enabling a larger operative bandwidth. We experimentally demonstrate independent bi-directional tunability of our dual-frequency design. Furthermore, a control algorithm based on maximum amplitude tracking has been implemented for self-adaption of the system. The latter has been demonstrated in a system-level simulation model, which integrates the dual-frequency resonator, the magnetic tuning, and the control algorithm.

Pressure induced transition between superhydrophobic states: configuration diagrams and effect of surface feature size.

The stability of wetting states, namely the Cassie state (partial wetting) and the Wenzel state (complete wetting) of surfaces with protrusions, is determined by comparing the total free energy of a liquid drop in terms of their apparent contact angles for different protrusion features. It is found that when the area fraction of the topographical features and the intrinsic contact angle for a flat surface are large, the Cassie state is favored, but it can be either the metastable or stable state. It is shown that the transition from the Cassie state to the Wenzel state requires the application of a pressure to the meniscus between the surface protrusions. The critical transition pressure increases not only with increasing area fraction and intrinsic contact angle, but also with decreasing protrusion size. During the transition, a high-pressure gas can be trapped around the protrusions that can cause the Cassie state to be recovered after the release of the applied pressure. The analysis shows that a droplet can 'hang' upside-down when the protrusion size is very small; namely, the protrusions can pin the meniscus. These results are discussed relative to the advancing and receding contact angle.

Synthesis of spherical polymer and titania photonic crystallites.

The fabrication of small structured spherical particles that are essentially small photonic crystals is described. The particles are 1-50 microm in diameter and are porous with nearly close-packed monodisperse pores whose size is comparable to the wavelength of light. The solid matrix of the particles is titania, which provides a large refractive index contrast between the particle matrix and pores. The particles are made by encapsulating polymer colloidal particles in emulsion droplets of hexanes in which a titanium alkoxide precursor is dissolved. Subsequent osmotic removal of the hexanes from the droplets and condensation of the alkoxide precursor leads to spherical aggregates of polymer spheres with titania filling the spaces between the polymer spheres. The polymer particles are then burned out leaving behind the desired porous titania particles. The size and structure of the pores and high refractive index of the titania matrix are expected to produce particles that are very efficient scatterers of light, making them useful as pigments.