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1.
Phys Rev Lett ; 116(11): 110601, 2016 Mar 18.
Article in English | MEDLINE | ID: mdl-27035293

ABSTRACT

We analyze both the attractive and repulsive Casimir-Lifshitz forces recently reported in experimental investigations. By using a kinetic approach, we obtain the Casimir forces from the power absorbed by the materials. We consider collective material excitations through a set of relaxation times distributed in frequency according to a log-normal function. A generalized expression for these forces for arbitrary values of temperature is obtained. We compare our results with experimental measurements and conclude that the model goes beyond the proximity-force approximation.

2.
J Chem Phys ; 142(10): 104106, 2015 Mar 14.
Article in English | MEDLINE | ID: mdl-25770525

ABSTRACT

We analyze the temperature relaxation phenomena of systems in contact with a thermal reservoir that undergoes a non-Markovian diffusion process. From a generalized Langevin equation, we show that the temperature is governed by a law of cooling of the Newton's law type in which the relaxation time depends on the velocity autocorrelation and is then characterized by the memory function. The analysis of the temperature decay reveals the existence of an anomalous cooling in which the temperature may oscillate. Despite this anomalous behavior, we show that the variation of entropy remains always positive in accordance with the second law of thermodynamics.

3.
PLoS One ; 8(3): e58770, 2013.
Article in English | MEDLINE | ID: mdl-23527019

ABSTRACT

Radiative heat exchange at the nanoscale presents a challenge for several areas due to its scope and nature. Here, we provide a thermokinetic description of microscale radiative energy transfer including phonon-photon coupling manifested through a non-Debye relaxation behavior. We show that a lognormal-like distribution of modes of relaxation accounts for this non-Debye relaxation behavior leading to the thermal conductance. We also discuss the validity of the fluctuation-dissipation theorem. The general expression for the thermal conductance we obtain fits existing experimental results with remarkable accuracy. Accordingly, our approach offers an overall explanation of radiative energy transfer through micrometric gaps regardless of geometrical configurations and distances.


Subject(s)
Nanostructures/chemistry , Nanostructures/radiation effects , Thermal Conductivity , Energy Transfer , Kinetics , Models, Theoretical , Photons , Quantum Theory
4.
Phys Rev Lett ; 101(23): 230602, 2008 Dec 05.
Article in English | MEDLINE | ID: mdl-19113535

ABSTRACT

A recent Letter [M. H. Lee, Phys. Rev. Lett. 98, 190601 (2007)] has called attention to the fact that irreversibility is a broader concept than ergodicity, and that therefore the Khinchin theorem [A. I. Khinchin, (Dover, New York, 1949)] may fail in some systems. In this Letter we show that for all ranges of normal and anomalous diffusion described by a generalized Langevin equation the Khinchin theorem holds.

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