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Molecules ; 24(9)2019 May 05.
Article in English | MEDLINE | ID: mdl-31060299

ABSTRACT

A series of pyrimidine derivatives bearing one, two or three triphenylamine/9-ethylcarbazole substituents has been synthesized by Suzuki cross-coupling reaction. All compounds showed absorption bands in the UV region and the emission of violet-blue light upon irradiation. Protonation led to quenching of the fluorescence, although some derivatives remained luminescent with the appearance of a new red-shifted band in the spectra. Accurate control of the amount of acid enabled white photoluminescence to be obtained both in solution and in solid state.


Subject(s)
Carbazoles/chemistry , Fluorescent Dyes/chemical synthesis , Pyrimidines/chemical synthesis , Fluorescence , Fluorescent Dyes/chemistry , Fluorescent Dyes/pharmacology , Molecular Structure , Pyrimidines/chemistry , Pyrimidines/pharmacology
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