Waste-derived compost and biochar amendments for stormwater treatment in bioretention column: Co-transport of metals and colloids.

Bioretention systems, as one of the most practical management operations for low impact development of water recovery, utilize different soil amendments to remove contaminants from stormwater. For the sake of urban sustainability, the utilization of amendments derived from waste materials has a potential to reduce waste disposal at landfill while improving the quality of stormwater discharge. This study investigated the efficiency of food waste compost and wood waste biochar for metal removal from synthetic stormwater runoff under intermittent flow and co-presence of colloids. Throughout intermittent infiltration of 84 pore volumes of stormwater, columns amended with compost and biochar removed more than 50-70% of influent metals, whereas iron-oxide coated sand was much less effective. Only a small portion of metals adsorbed on the compost (< 0.74%) was reactivated during the drainage of urban pipelines that do not flow frequently, owing to abundant oxygen-containing functional groups in compost. In comparison, co-existing kaolinite enhanced metal removal by biochar owing to the abundance of active sites, whereas co-existing humic acid facilitated mobilization via metal-humate complexation. The results suggest that both waste-derived compost and biochar show promising potential for stormwater harvesting, while biochar is expected to be more recalcitrant and desirable in field-scale bioretention systems.

Sorption, mobility, and bioavailability of PBDEs in the agricultural soils: Roles of co-existing metals, dissolved organic matter, and fertilizers.

Polybrominated diphenyl ethers (PBDEs) are common pollutants released from electronic waste (e-waste) dismantling and recycling activities. Our city-wide survey of agricultural soils in Qingyuan (40 sampling sites), where e-waste recycling has been active, observed exceedance of PBDEs above background levels (average of 251.9ngg-1, 87 times the regional baseline concentration) together with elevated levels of metals/metalloids at the contamination hotspots, such as As (180.4mgkg-1), Cu (100.7mgkg-1), Zn (93.4mgkg-1), Pb (37.8mgkg-1), Cr (15.1mgkg-1), and Cd (0.3mgkg-1). Hence, a twenty-cycle batch sorption test on composite soil samples from the e-waste site was conducted to study the fate of BDE-28 (2,4,4'-tribromodiphenyl ether) and BDE-99 (2,2',4,4',5-pentabromodiphenyl ether) under the influence of co-existing trace elements (TEs) (Cu, Pb, Zn, and Cd, which exceeded Chinese Environmental Quality Standard for Soils), dissolved organic matter (extracted from local peat), and locally available commercial fertilizer. The results showed that the presence of TEs barely affected the sorption of BDEs, probably because the low concentration of BDEs in the environment resulted in nearly complete sorption onto the soil. In contrast, metals sorption onto soil was promoted by the presence of BDEs. The mobility of BDE-28 was higher than BDE-99 in water leaching tests, while the leaching concentration of BDE-99 was further reduced in simulated acid rain possibly due to protonation of π-accepting sites in soil organic matter. In the freshly spiked soil, BDEs of greater hydrophobicity and larger molecular size exhibited higher bioavailability (due to greater affinity to Tenax extraction), which was contrary to the field contaminated soil. Similarly, the co-occurrence of metals and fertilizer increased the bioavailability of newly sorbed BDE-99 more than BDE-28 in the soil. These results illustrate the need to holistically assess the fate and interactions of co-existing organic and inorganic pollutants in the agricultural soils.

Chelant-enhanced washing of CCA-contaminated soil: Coupled with selective dissolution or soil stabilization.

Remediation of CCA-contaminated soil (Cr, Cu, and As) by biodegradable chelant-enhanced washing (EDDS, S,S-ethylene-diamine-disuccinic-acid) needs further enhancement. This study investigated the effectiveness of coupling with pre-treatment by selective dissolution and post-treatment by soil amendments, respectively. Three groups of reagents (reductants, alkaline solvents, and organic ligands) were adopted in the pre-treatment to dissolve the oxide minerals before EDDS extraction. In the post-treatment, soil amendments (coal fly ash (CFA), acid mine drainage sludge (AMDS), green waste compost (GWC)), and their mixtures) were used for a 2-month stabilization after 2-h EDDS washing. Multi-endpoint evaluation was performed by assessing the chemical state, leachability, mobility, bioaccessibility, and plant-availability of residual metal(loid)s as well as the cytotoxicity, enzyme activities, and available nutrients of the treated soils. Pre-treatment by dithionite-citrate-bicarbonate significantly enhanced extraction efficiency, but also increased the leachability of As and Cr and bioaccessibility of Cr in the treated soils. While sodium hydroxide removed the majority of As without increasing its leachability and bioaccessibility, it increased the cytotoxicity and inhibited the acid phosphatase activity. Post-treatment with AMDS and CFA effectively controlled the mobility and leachability of residual As and Cr after EDDS washing. However, destabilized Cu was only marginally immobilized by GWC due to strong Cu-EDDS complexation. The bioaccessibility and phytoavailability of Cu was primarily reduced by EDDS washing, while those of As and Cr could be attenuated by AMDS and CFA. This study indicates that coupling chemical extraction with subsequent soil amendment plays complementary roles in mitigating effects of residual metal(loid)s and improving environmental quality.

Surface-modified biochar in a bioretention system for Escherichia coli removal from stormwater.

Bioretention systems have been recommended as one of the best management practices for low impact development for water recycling/reuse systems. Although improvement of the stormwater quality has been reported regarding pollutants eliminations such as suspended solids and heavy metals, a substantial removal of indicator bacteria is required for possible non-potable reuse. This study investigated the efficiency of wood biochar with H2SO4-, H3PO4-, KOH-, and amino-modifications for E. coli removal from synthetic stormwater under intermittent flow. The H2SO4-modified biochar showed a specific surface area of 234.7 m2 g-1 (approximately double the area of original biochar), whereas a substantial reduction in surface area was found with amino-modified biochar. The E. coli removal (initial concentration of 0.3-3.2 × 106 CFU mL-1) by modified biochars as filter media was very promising with, for example, over 98% removal efficiency in the first 20 pore volumes of stormwater infiltration and over 92% removal by the end of the second infiltration cycle. Only a small portion of E. coli attached on the modified biochars (<0.3%, except KOH- and amino-modified biochars) was remobilized during the drainage phase of intermittent flow. The high removal capacity and stability against drainage were attributed to the high surface area, porous structure, and surface characteristics (e.g. hydrophobicity and O-containing functional groups) of the biochars. Thus, the H2SO4-modified biochar appeared to give the best treatment performance.